Abstract Photochemical hazes are suspected to obscure molecular features, such as water, from detection in the transmission spectra of exoplanets with atmospheric temperatures <800 K. The opacities of laboratory produced organic compounds (tholins) from Khare et al. have become a standard for modeling haze in exoplanet atmospheres. However, these tholins were grown in an oxygen-free, Titan-like environment that is very different from typical assumptions for exoplanets, where C/O ∼ 0.5. This work presents the 0.13–10 μ m complex refractive indices derived from laboratory transmission measurements of tholins grown in environments with different oxygen abundances. With the increasing uptake of oxygen, absorption increases across the entire wavelength range, and a scattering feature around 6 μ m shifts toward shorter wavelengths and becomes more peaked around 5.8 μ m, due to a C = O stretch resonance. Using GJ 1214 b as a test case, we examine the transmission spectra of a sub-Neptune planet with C/O ratios of solar, 1, and 1000 to evaluate the effective differences between our opacities and those of Khare. For an atmosphere with solar hydrogen and helium abundances, we find a difference of 200–1500 ppm, but for high-metallicity ( Z = 1000) environments, the difference may only be 20 ppm. The 1–2 μ m transmission data for GJ 1214 b rule out the Titan-like haze model, and are more consistent with C/O = 1 and C/O = solar haze models. This work demonstrates that using haze opacities that are more consistent with underlying assumptions about bulk atmospheric composition are important for building self-consistent models that appropriately constrain the atmospheric C/O ratio, even when molecular features are obscured.
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The Hazy and Metal-rich Atmosphere of GJ 1214 b Constrained by Near- and Mid-infrared Transmission Spectroscopy
Abstract The near-infrared transmission spectrum of the warm sub-Neptune exoplanet GJ 1214 b has been observed to be flat and featureless, implying a high metallicity atmosphere with abundant aerosols. Recent JWST MIRI Low Resolution Spectrometer observations of a phase curve of GJ 1214 b showed that its transmission spectrum is flat out into the mid-infrared. In this paper, we use the combined near- and mid-infrared transmission spectrum of GJ 1214 b to constrain its atmospheric composition and aerosol properties. We generate a grid of photochemical haze models using an aerosol microphysics code for a number of background atmospheres spanning metallicities from 100 to 1000× solar, as well as a steam atmosphere scenario. The flatness of the combined data set largely rules out atmospheric metallicities ≤300× solar due to their large corresponding molecular feature amplitudes, preferring values ≥1000× solar and column haze production rates ≥10 −10 g cm −2 s −1 . The steam atmosphere scenario with similarly high haze production rates also exhibits sufficiently small molecular features to be consistent with the transmission spectrum. These compositions imply that atmospheric mean molecular weights ≥15 g mol −1 are needed to fit the data. Our results suggest that haze production is highly efficient on GJ 1214 b and could involve non-hydrocarbon, non-nitrogen haze precursors. Further characterization of GJ 1214 b’s atmosphere would likely require multiple transits and eclipses using JWST across the near- and mid-infrared, potentially complemented by ground-based high-resolution transmission spectroscopy.
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- Award ID(s):
- 1931736
- PAR ID:
- 10436109
- Date Published:
- Journal Name:
- The Astrophysical Journal
- Volume:
- 951
- Issue:
- 2
- ISSN:
- 0004-637X
- Page Range / eLocation ID:
- 96
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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