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1. Sr(Ag 1−x Li x ) 2 Se 2 and [Sr 3 Se 2 ][(Ag 1−x Li x ) 2 Se 2 ] Tunable Direct Band Gap Semiconductors

   https://doi.org/10.1002/ange.202301191  

   Zhou, Xiuquan ; Wilfong, Brandon ; Chen, Xinglong ; Laing, Craig ; Pandey, Indra R. ; Chen, Ying‐Pin ; Chen, Yu‐Sheng ; Chung, Duck‐Young ; Kanatzidis, Mercouri G. ( February 2023 , Angewandte Chemie)

   Synthesizing solids in molten fluxes enables the rapid diffusion of soluble species at temperatures lower than in solid‐state reactions, leading to crystal formation of kinetically stable compounds. In this study, we demonstrate the effectiveness of mixed hydroxide and halide fluxes in synthesizing complex Sr/Ag/Se in mixed LiOH/LiCl. We have accessed a series of two‐dimensional Sr(Ag_1−xLi_x)₂Se₂layered phases. With increased LiOH/LiCl ratio or reaction temperature, Li partially substituted Ag to form solid solutions of Sr(Ag_1−xLi_x)₂Se₂withxup to 0.45. In addition, a new type of intergrowth compound [Sr₃Se₂][(Ag_1−xLi_x)₂Se₂] was synthesized upon further reaction of Sr(Ag_1−xLi_x)₂Se₂with SrSe. Both Sr(Ag_1−xLi_x)₂Se₂and [Sr₃Se₂][(Ag_1−xLi_x)₂Se₂] exhibit a direct band gap, which increases with increasing Li substitution (x). Therefore, the band gap of Sr(Ag_1−xLi_x)₂Se₂can be precisely tuned via fine‐tuningxthat is controlled by only the flux ratio and temperature.

    

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2. Sr(Ag 1−x Li x ) 2 Se 2 and [Sr 3 Se 2 ][(Ag 1−x Li x ) 2 Se 2 ] Tunable Direct Band Gap Semiconductors

   https://doi.org/10.1002/anie.202301191  

   Zhou, Xiuquan ; Wilfong, Brandon ; Chen, Xinglong ; Laing, Craig ; Pandey, Indra R. ; Chen, Ying‐Pin ; Chen, Yu‐Sheng ; Chung, Duck‐Young ; Kanatzidis, Mercouri G. ( February 2023 , Angewandte Chemie International Edition)

   Synthesizing solids in molten fluxes enables the rapid diffusion of soluble species at temperatures lower than in solid‐state reactions, leading to crystal formation of kinetically stable compounds. In this study, we demonstrate the effectiveness of mixed hydroxide and halide fluxes in synthesizing complex Sr/Ag/Se in mixed LiOH/LiCl. We have accessed a series of two‐dimensional Sr(Ag_1−xLi_x)₂Se₂layered phases. With increased LiOH/LiCl ratio or reaction temperature, Li partially substituted Ag to form solid solutions of Sr(Ag_1−xLi_x)₂Se₂withxup to 0.45. In addition, a new type of intergrowth compound [Sr₃Se₂][(Ag_1−xLi_x)₂Se₂] was synthesized upon further reaction of Sr(Ag_1−xLi_x)₂Se₂with SrSe. Both Sr(Ag_1−xLi_x)₂Se₂and [Sr₃Se₂][(Ag_1−xLi_x)₂Se₂] exhibit a direct band gap, which increases with increasing Li substitution (x). Therefore, the band gap of Sr(Ag_1−xLi_x)₂Se₂can be precisely tuned via fine‐tuningxthat is controlled by only the flux ratio and temperature.

    

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3. Kinetics of the Topochemical Transformation of (PbSe) m (TiSe 2 ) n (SnSe 2 ) m (TiSe 2 ) n to (Pb 0.5 Sn 0.5 Se) m (TiSe 2 ) n

   https://doi.org/10.1021/jacs.8b10681  

   Sutherland, Duncan R. ; Merrill, Devin R. ; Ditto, Jeffrey ; Moore, Daniel B. ; Medlin, Douglas ; Johnson, David C. ( January 2019 , Journal of the American Chemical Society)
4. Characterization of Tetracyanopyridine (TCNPy)-Based Magnets: V[TCNPy] 2 ⋅ z  (CH 2 Cl 2 ) ( T c =111 K) and V[TCNPy] 3 ⋅ z  (CH 2 Cl 2 ) ( T c =90 K)

   https://doi.org/10.1002/chem.201602385  

   Hao, Jingjun ; Davidson, Royce A. ; Kareis, Christopher M. ; Kavand, Marzieh ; van Schooten, Kipp J. ; Boehme, Christoph ; Wöß, Eva ; Knör, Günther ; Miller, Joel S. ( September 2016 , Chemistry - A European Journal)
5. Synthesis and crystallographic characterization of diphenylamide rare-earth metal complexes Ln (NPh 2 ) 3 (THF) 2 and [(Ph 2 N) 2 Ln (μ-NPh 2 )] 2

   https://doi.org/10.1107/S2056989020009998  

   Palumbo, Chad T. ; Kotyk, Christopher M. ; Ziller, Joseph W. ; Evans, William J. ( September 2020 , Acta Crystallographica Section E Crystallographic Communications)

   null (Ed.)

   Studies of the coordination chemistry between the diphenylamide ligand, NPh 2 , and the smaller rare-earth Ln III ions, Ln = Y, Dy, and Er, led to the structural characterization by single-crystal X-ray diffraction crystallography of both solvated and unsolvated complexes, namely, tris(diphenylamido-κ N )bis(tetrahydrofuran-κ O )yttrium(III), Y(NPh 2 ) 3 (THF) 2 or [Y(C 12 H 10 N) 3 (C 4 H 8 O) 2 ], 1-Y , and the erbium(III) (Er), 1-Er , analogue, and bis[μ-1κ N :2(η 6 )-diphenylamido]bis[bis(diphenylamido-κ N )yttrium(III)], [(Ph 2 N) 2 Y(μ-NPh 2 )] 2 or [Y 2 (C 12 H 10 N) 6 ], 2-Y , and the dysprosium(III) (Dy), 2-Dy , analogue. The THF ligands of 1-Er are modeled with disorder across two positions with occupancies of 0.627 (12):0.323 (12) and 0.633 (7):0.367 (7). Also structurally characterized was the tetrametallic Er III bridging oxide hydrolysis product, bis(μ-diphenylamido-κ 2 N : N )bis[μ-1κ N :2(η 6 )-diphenylamido]tetrakis(diphenylamido-κ N )di-μ 3 -oxido-tetraerbium(III) benzene disolvate, {[(Ph 2 N)Er(μ-NPh 2 )] 4 (μ-O) 2 }·(C 6 H 6 ) 2 or [Er 4 (C 12 H 10 N) 8 O 2 ]·2C 6 H 6 , 3-Er . The 3-Er structure was refined as a three-component twin with occupancies 0.7375:0.2010:0.0615. 

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