More Like this

1. On the Effect of Biochar Application on the Hydraulic Properties of Salt-affected Green Stormwater Infrastructure

   Finnegan, Maxwell; Khatei, Ganesh; Rinaldo, Tobia; Caplan, Joshua; Van_Pelt, Scott; D'Odorico, Paolo; Ravi, Sujith (December 2024, American Geophysical Union)

   Soil salinization is an increasing global problem, especially in agricultural, coastal, and roadside environments. The increasing intensity of precipitation events due to climate change may be exacerbating these effects, such as through larger pulses of deicing salts entering roadside green stormwater infrastructure (GSI) and stronger coastal storms bringing seawater further inland. Although soils are often amended with biochar to remove pollutants and improve hydraulic properties, it may also mitigate the impact of salinity. Here, we compared the water retention properties and unsaturated hydraulic conductivities of both biochar-amended and unamended GSI soil media with varying salinity levels (1-25 dS m-1, using Na+ salts). The effects of salinity on both matric and osmotic potential included shifts in the plant-available water range, with the magnitude depending on the salt concentration and biochar content. Overall, biochar addition decreased the salinity and improved plant water availability in salt-affected soils. There was an increase in the integral water capacity (which describes the total amount of water the soil media can hold and release to a plant) for biochar-amended saline soils, demonstrating that biochar can reduce the total osmo-matric stress. On a macro scale, the high density of pores in biochar appears to increase soil hydraulic conductivity while reducing osmotic potential by adsorbing salt ions. On a micro scale, the negative surface charge of biochar likely counteracts the impact of the electric double layer of saline soils, reducing the total osmo-matric force on water molecules in soil solution. In effect, this helps the plant's osmotic potential to overcome the forces holding water molecules to soil grains. As soils become more saline due to ongoing climate-related snow events, biochar application might be an effective management technique for roadside and other saline soils. 

   more » « less
2. Freshwater Salinization Syndrome Alters Retention and Release of ‘Chemical Cocktails’ along Flowpaths:  from Stormwater Management to Urban Streams

   https://doi.org/10.1086/721469  

   Kaushal, Sujay; Reimer, Jenna E.; Mayer, Paul M.; Shatkay, Ruth R.; Maas, Carly; Nguyen, William D.; Boger, Walter L.; Yaculak, Alexis M.; Doody, Thomas R.; Pennino, Michael; et al (June 2022, Freshwater Science)

   Freshwater salinization syndrome (FSS) refers to the suite of interactive effects of salt ions on degradation of physical, biological,and social systems. Best management practices (BMPs), which are methods to effectively reduce runoff and nonpoint source pollution (stormwater, nutrients, sediments), do not typically consider management of salt pollution. We investigate impacts of FSS on mobilization of salts, nutrients, and metals in urban streams and storm water BMPs by analyzing original data on concentrations and fluxes of salts, nutrients, and metals from 7 urban watersheds in the Mid-Atlantic USA and synthesizing literature data. We also explore future critical research needs through a survey of practitioners and scientists. Our original data show 1) sharp pulses in concentrations of salt ions and metals in urban streams directly following both road salt events and stream restoration construction (e.g.,similar to the way concentrations increase during other soil disturbance activities); 2) sharp declines in pH (acidification) in response to road salt applications because of mobilization of H+ from soil exchange sites by Na+; 3) sharp increases inorganic matter from microbial and algal sources (based on fluorescence spectroscopy) in response to road salt applications, likely because of lysing cells and changes insolubility; 4) substantial retention (~30–40%) of Na+ in stormwater BMP sediments and floodplains in response to salinization; 5) increased ion exchange and mobilization of diverse salt ions (Na+, Ca2+, K+, Mg2+), nutrients(N, P), and trace metals(Cu, Sr) from stormwater BMPs and restored streams in response to FSS; 6) downstream increasing loads ofCl–, SO42–, Br–, F–,andI–along flowpaths through urbanstreams and P release from urban stormwater BMPs in response to salinization; and 7)a substantial annual reduction (>50%) in Na+concentrations in an urban stream when road salt applications were dramatically reduced, which suggests potential for ecosystem recovery. We compare our original results with published metrics of contaminant retention and release across a broad range of stormwater BMPs from North America and Europe.Overall, urban streams and stormwater BMPs consistently retain Na+ and Cl–but mobilize multiple contaminants based on salt types and salinity levels. Finally, we present our top 10 research questions regarding FSS impacts on urban streams and stormwater BMPs. Reducing diverse chemical cocktails of contaminants mobilized by freshwater salinization is a priority for effectively and holistically restoring urban waters. 

   more » « less
3. Wind Erodibility and Particulate Matter Emissions of Salt‐Affected Soils: The Case of Dry Soils in a Low Humidity Atmosphere

   https://doi.org/10.1029/2023JD039576  

   Khatei, Ganesh; Rinaldo, Tobia; Van_Pelt, R Scott; D’Odorico, Paolo; Ravi, Sujith (January 2024, Journal of Geophysical Research: Atmospheres)

   Abstract Arid and semiarid ecosystems around the world are often prone to both soil salinization and accelerated soil erosion by wind. Soil salinization, the accumulation of salts in the shallow portions of the soil profile, is known for its ability to decreases soil fertility and inhibit plant growth. However, the effect of salts on soil erodibility by wind and the associated dust emissions in the early stages of soil salinization (low salinity conditions) remains poorly understood. Here we use wind tunnel tests to detect the effects of soil salinity on the threshold velocity for wind erosion and dust production in dry soils with different textures treated with salt‐enriched water at different concentrations. We find that the threshold velocity for wind erosion increases with soil salinity. We explain this finding as the result of salt‐induced (physical) aggregation and soil crust formation, and the increasing strength of surface soil crust with increasing soil salinity, depending on soil texture. Even though saline soils showed resistance to wind erosion in the absence of abraders, the salt crusts were readily ruptured by saltating sand grains resulting in comparable or sometimes even higher particulate matter emissions compared to non‐saline soils. Interestingly, the salinity of the emitted dust is found to be significantly higher (5–10 times more) than that of the parent soil, suggesting that soil salts are preferentially emitted, and airborne dust is enriched of salts. 

   more » « less
4. Freshwater Salinization Syndrome Alters Nitrogen Transport in Urban Watersheds

   https://doi.org/10.3390/w15223956  

   Galella, Joseph G; Kaushal, Sujay S; Mayer, Paul M; Maas, Carly M; Shatkay, Ruth R; Inamdar, Shreeram; Belt, Kenneth T (November 2023, Water)

   Anthropogenic salt inputs have impacted many streams in the U.S. for over a century. Urban stream salinity is often chronically elevated and punctuated by episodic salinization events, which can last hours to days after snowstorms and the application of road salt. Here, we investigated the impacts of freshwater salinization on total dissolved nitrogen (TDN) and NO3−/NO2− concentrations and fluxes across time in urban watersheds in the Baltimore-Washington D.C. metropolitan area of the Chesapeake Bay region. Episodic salinization from road salt applications and snowmelt quickly mobilized TDN in streams likely through soil ion exchange, hydrologic flushing, and other biogeochemical processes. Previous experimental work from other studies has shown that salinization can mobilize nitrogen from sediments, but less work has investigated this phenomenon with high-frequency sensors and targeted monitoring during road salt events. We found that urban streams exhibited elevated concentrations and fluxes of TDN, NO3−/NO2−, and specific conductance that rapidly peaked during and after winter road salt events, and then rapidly declined afterwards. We observed plateaus in TDN concentrations in the ranges of the highest specific conductance values (between 1000 and 2000 μS/cm) caused by road salt events. Plateaus in TDN concentrations beyond a certain threshold of specific conductance values suggested source limitation of TDN in watersheds (at the highest ranges in chloride concentrations and ranges); salts were likely extracting nitrogen from soils and streams through ion exchange in soils and sediments, ion pairing in soils and waters, and sodium dispersion of soils to a certain threshold level. When watershed transport was compared across land use, including a forested reference watershed, there was a positive relationship between Cl− loads and NO3−/NO2− loads. This relationship occurred across all sites regardless of land use, which suggests that the mass transport of Cl− and NO3−/NO2− are likely influenced by similar factors such as soil ion exchange, ion pairing, sodium dispersion of soils, hydrologic flushing, and biogeochemical processes. Freshwater salinization has the potential to alter the magnitude and timing of total dissolved nitrogen delivery to receiving waters during winter months following road salt applications, and further work should investigate the seasonal relationships of N transport with salinization in urban watersheds. 

   more » « less
5. Stormwater best management practices: Experimental evaluation of chemical cocktails mobilized by freshwater salinization syndrome

   https://doi.org/10.3389/fenvs.2023.1020914  

   Galella, Joseph G.; Kaushal, Sujay S.; Mayer, Paul M.; Maas, Carly M.; Shatkay, Ruth R.; Stutzke, Robert A. (April 2023, Frontiers in Environmental Science)

   Freshwater Salinization Syndrome (FSS) refers to the suite of physical, biological, and chemical impacts of salt ions on the degradation of natural, engineered, and social systems. Impacts of FSS on mobilization of chemical cocktails has been documented in streams and groundwater, but little research has focused on the effects of FSS on stormwater best management practices (BMPs) such as: constructed wetlands, bioswales, ponds, and bioretention. However emerging research suggests that stormwater BMPs may be both sources and sinks of contaminants, shifting seasonally with road salt applications. We conducted lab experiments to investigate this premise; replicate water and soil samples were collected from four distinct stormwater feature types (bioretention, bioswale, constructed wetlands and retention ponds) and were used in salt incubation experiments conducted under six different salinities with three different salts (NaCl, CaCl₂, and MgCl₂). Increased salt concentrations had profound effects on major and trace element mobilization, with all three salts showing significant positive relationships across nearly all elements analyzed. Across all sites, mean salt retention was 34%, 28%, and 26% for Na⁺, Mg²⁺and Ca²⁺respectively, and there were significant differences among stormwater BMPs. Salt type showed preferential mobilization of certain elements. NaCl mobilized Cu, a potent toxicant to aquatic biota, at rates over an order of magnitude greater than both CaCl₂and MgCl₂. Stormwater BMP type also had a significant effect on elemental mobilization, with ponds mobilizing significantly more Mn than other sites. However, salt concentration and salt type consistently had significant effects on mean concentrations of elements mobilized across all stormwater BMPs (p< 0.05), suggesting that processes such as ion exchange mobilize metals mobilize metals and salt ions regardless of BMP type. Our results suggest that decisions regarding the amounts and types of salts used as deicers can have significant effects on reducing contaminant mobilization to freshwater ecosystems. 

   more » « less