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Title: The kinetic energy of PAH dication and trication dissociation determined by recoil-frame covariance map imaging
We investigated the dissociation of dications and trications of three polycyclic aromatic hydrocarbons (PAHs), fluorene, phenanthrene, and pyrene. PAHs are a family of molecules ubiquitous in space and involved in much of the chemistry of the interstellar medium. In our experiments, ions are formed by interaction with 30.3 nm extreme ultraviolet (XUV) photons, and their velocity map images are recorded using a PImMS2 multi-mass imaging sensor. Application of recoil-frame covariance analysis allows the total kinetic energy release (TKER) associated with multiple fragmentation channels to be determined to high precision, ranging 1.94–2.60 eV and 2.95–5.29 eV for the dications and trications, respectively. Experimental measurements are supported by Born–Oppenheimer molecular dynamics (BOMD) simulations.  more » « less
Award ID(s):
1753324
PAR ID:
10438831
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; more » ; ; ; ; ; ; ; ; ; ; ; « less
Date Published:
Journal Name:
Physical Chemistry Chemical Physics
Volume:
24
Issue:
38
ISSN:
1463-9076
Page Range / eLocation ID:
23096 to 23105
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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