Non‐conjugated pendant electroactive polymers (NCPEPs) are an emerging class of polymers that offer the potential of combining the desirable optoelectronic properties of conjugated polymers with the superior synthetic methodologies and stability of traditional non‐conjugated polymers. Despite an increasing number of studies focused on NCPEPs, particularly on understanding fundamental structure‐property relationships, no attempts have been made to provide an overview on established relationships to date. This review showcases selected reports on NCPEP homopolymers and copolymers that demonstrate how optical, electronic, and physical properties of the polymers are affected by tuning of key structural variables such as the chemical structure of the polymer backbone, molecular weight, tacticity, spacer length, the nature of the pendant group, and in the case of copolymers the ratios between different comonomers and between individual polymer blocks. Correlation of structural features with improved
- Award ID(s):
- 2103602
- PAR ID:
- 10439037
- Date Published:
- Journal Name:
- Chemical Communications
- Volume:
- 58
- Issue:
- 76
- ISSN:
- 1359-7345
- Page Range / eLocation ID:
- 10596 to 10618
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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