Coherent Control for Selective Excitation of Combustion Species in a Benchtop Flame Using fs/ps CARS
Hybrid fs/ps coherent anti-Stokes Raman scattering employing coherent control is presented for selective excitation of combustion-relevant species. Femtosecond pulse shaping is accomplished experimentally using a 4-f pulse shaper with a spatial light modulator at the Fourier plane. A feedback-controlled genetic algorithm for adaptive pulse shaping is used to optimize for the selective excitation of CO2 (near 1388 cm−1) and O2 (near 1556 cm−1) rovibrational transitions in a non-reacting flow. 0D fs/ps CARS measurements acquired in a near-adiabatic flame demonstrate the use of coherent control in a combustion environment.
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