skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Utilizing Environmental Tracers to Reduce Groundwater Flow and Transport Model Parameter Uncertainties
Abstract Non‐uniqueness in groundwater model calibration is a primary source of uncertainty in groundwater flow and transport predictions. In this study, we investigate the ability of environmental tracer information to constrain groundwater model parameters. We utilize a pilot point calibration procedure conditioned to subsets of observed data including: liquid pressures, tritium (3H), chlorofluorocarbon‐12 (CFC‐12), and sulfur hexafluoride (SF6) concentrations; and groundwater apparent ages inferred from these environmental tracers, to quantify uncertainties in the heterogeneous permeability fields and infiltration rates of a steady‐state 2‐D synthetic aquifer and a transient 3‐D model of a field site located near Riverton, Wyoming (USA). To identify the relative data worth of each observation data type, the post‐calibration uncertainties of the optimal parameters for a given observation subset are compared to that from the full observation data set. Our results suggest that the calibration‐constrained permeability field uncertainties are largest when liquid pressures are used as the sole calibration data set. We find significant reduction in permeability uncertainty and increased predictive accuracy when the environmental tracer concentrations, rather than apparent groundwater ages, are used as calibration targets in the synthetic model. Calibration of the Riverton field site model using environmental tracer concentrations directly produces infiltration rate estimates with the lowest uncertainties, however; permeability field uncertainties remain similar between the environmental tracer concentration and apparent groundwater age calibration scenarios. This work provides insight on the data worth of environmental tracer information to calibrate groundwater models and highlights potential benefits of directly assimilating environmental tracer concentrations into model parameter estimation procedures.  more » « less
Award ID(s):
1633831
PAR ID:
10446509
Author(s) / Creator(s):
 ;  ;  
Publisher / Repository:
DOI PREFIX: 10.1029
Date Published:
Journal Name:
Water Resources Research
Volume:
57
Issue:
7
ISSN:
0043-1397
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. null (Ed.)
    Abstract. The acceleration of urbanization requires sustainable, adaptive management strategies for land and water use in cities. Although the effects of buildings and sealed surfaces on urban runoff generation and local climate are well known, much less is known about the role of water partitioning in urban green spaces. In particular, little is quantitatively known about how different vegetation types of urban green spaces (lawns, parks, woodland, etc.) regulate partitioning of precipitation into evaporation, transpiration and groundwater recharge and how this partitioning is affected by sealed surfaces. Here, we integrated field observations with advanced, isotope-based ecohydrological modelling at a plot-scale site in Berlin, Germany. Soil moisture and sap flow, together with stable isotopes in precipitation, soil water and groundwater recharge, were measured over the course of one growing season under three generic types of urban green space: trees, shrub and grass. Additionally, an eddy flux tower at the site continuously collected hydroclimate data. These data have been used as input and for calibration of the process-based ecohydrological model EcH2O-iso. The model tracks stable isotope ratios and water ages in various stores (e.g. soils and groundwater) and fluxes (evaporation, transpiration and recharge). Green water fluxes in evapotranspiration increased in the order shrub (381±1mm) 
    more » « less
  2. null (Ed.)
    Abstract. Quantifying how vegetation mediates water partitioning at different spatialand temporal scales in complex, managed catchments is fundamental forlong-term sustainable land and water management. Estimations fromecohydrological models conceptualising how vegetation regulates theinterrelationships between evapotranspiration losses, catchment water storage dynamics, and recharge and runoff fluxes are needed to assess water availability for a range of ecosystem services and evaluate how these might change under increasing extreme events, such as droughts. Currently, the feedback mechanisms between water and mosaics of different vegetation and land cover are not well understood across spatial scales, and the effects of different scaleson the skill of ecohydrological models needs to be clarified. We used thetracer-aided ecohydrological model EcH2O-iso in an intensively monitored 66 km2 mixed land use catchment in northeastern Germany to quantify water flux–storage–age interactions at four model grid resolutions (250, 500, 750, and 1000 m). This used a fusion of field (including precipitation, soil water, groundwater, and stream isotopes) and remote sensing data in the calibration. Multicriteria calibration across the catchment at each resolution revealed some differences in the estimation of fluxes, storages, and water ages. In general, model sensitivity decreased and uncertainty increased with coarser model resolutions. Larger grids were unable to replicate observed streamflow and distributed isotope dynamics in the way smaller pixels could. However, using isotope data in the calibration still helped constrain the estimation of fluxes, storage, and water ages at coarserresolutions. Despite using the same data and parameterisation for calibration at different grid resolutions, the modelled proportion of fluxes differed slightly at each resolution, with coarse models simulating higher evapotranspiration, lower relative transpiration, increased overland flow, and slower groundwater movement. Although the coarser resolutions also revealed higher uncertainty and lower overall model performance, the overall results were broadly similar. The study shows that tracers provide effective calibration constraints on larger resolution ecohydrological modelling and help us understand the influence of grid resolution on the simulation of vegetation–soil interactions. This is essential in interpreting associated uncertainty in estimating land use influence on large-scale “blue” (ground and surface water) and “green” (vegetation and evaporated water) fluxes, particularly for future environmental change. 
    more » « less
  3. We introduce EcH2O-iso, a new development of the physically-based, fully-distributed ecohydrological model EcH2O where the tracking of water isotopic tracers (2H and 18O) and age has been incorporated. EcH2O-iso is evaluated at a montane, low-energy experimental catchment in eastern Scotland using 16 independent isotope time series from various landscape positions and compartments; encompassing soil water, groundwater, stream water, and plant xylem. We find a good model-observation match in most cases, despite having only calibrated the model using hydrometric data and energy fluxes. These results provide further validation of the physical basis of the model for successfully capturing catchment hydrological functioning, both in terms of the celerity in energy propagation (e.g. runoff generation under prevailing hydraulic gradients) and flow velocities of water molecules (e.g., in consistent tracer concentrations at given locations and times). We also show that the spatially-distributed formulation of EcH2O-iso provides a powerful tool for quantitatively linking water stores and fluxes with spatio-temporal patterns of isotopes ratios and water ages. Finally, our study highlights some model development and benchmarking needs, refined using isotope-based calibration, for hypothesis testing and improved simulations of catchment dynamics that is transferable beyond the catchment landscape studied here. 
    more » « less
  4. Abstract Groundwater discharge zones connect aquifers to surface water, generating baseflow and serving as ecosystem control points across aquatic ecosystems. The influence of groundwater discharge on surface flow connectivity, fate and transport of contaminants and nutrients, and thermal habitat depends strongly on hydrologic characteristics such as the spatial distribution, age, and depth of source groundwater flow paths. Groundwater models have the potential to predict spatial discharge characteristics within river networks, but models are often not evaluated against these critical characteristics and model equifinality with respect to discharge processes is a known challenge. We quantify discharge characteristics across a suite of groundwater models with commonly used frameworks and calibration data. We developed a base model (MODFLOW‐NWT) for a 1,570‐km2watershed in the northeastern United States and varied the calibration data, control of river‐aquifer exchange directionality, and resolution. Most models (n = 11 of 12) fit similarly to calibration metrics, but patterns in discharge location, flow path depth, and subsurface travel time varied substantially. We found (1) a 15% difference in the percent of discharge going to first‐order streams, (2) threefold variations in flow path depth, and (3) sevenfold variations in the subsurface travel times among the models. We recalibrated three models using a synthetic discharge location data set. Calibration with discharge location data reduced differences in simulated discharge characteristics, suggesting an approach to improved equifinality based on widespread field‐based mapping of discharge zones. Our work quantifying variation across common modeling approaches is an important step toward characterizing and improving predictions of groundwater discharge characteristics. 
    more » « less
  5. Abstract Time‐lapse electrical resistivity tomography (ERT) data are increasingly used to inform the hydrologic dynamics of mountainous environments at the hillslope scale. Despite their popularity and recent advancements in hydrogeophysical inversion methods, few studies have shown how time‐lapse ERT data can be used to determine hydraulic parameters of subsurface water flow models. This study uses synthetic and field‐collected, hillslope‐scale, time‐lapse ERT data to determine subsurface hydraulic properties of a two‐layer, physics‐based, 2‐D vertical flow model with predefined layer and boundary locations. Uncoupled and coupled hydrogeophysical inversion methods are combined with a fine‐earth fraction optimization scheme to reduce the number of parameters needing calibration and interpret the influence of the hydraulic parameters on the hydrologic model predictions. Inversions of synthetic ERT data recover the prescribed fine‐earth fraction bulk density to within 0.1 g cm−3. Field‐collected ERT data from a mountain hillslope result in hydrologic model dynamics that are consistent with previous studies and measured water content data but struggle to capture measured groundwater levels. The uncoupled hydrogeophysical inversion method is more sensitive to changes in hydraulic parameter values of the lower hydrologic model layer than the coupled hydrogeophysical inversion method. Time series of minimum objective function value simulations indicate that periodically collected ERT data may recover hydraulic parameters to a similar level of uncertainty as daily ERT data. Using simple hydrologic model domains within hydrogeophysical inversions shows promise for providing reasonable hydrologic predictions while maintaining relatively simple calibration schemes and should be explored further in future studies. 
    more » « less