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1. Creating superconductivity in WB2 through pressure-induced metastable planar defects

   Lim, J.; A. C. Hire; Y. Quan; J. S. Kim; S. R. Xie; S. Sinha; R. S. Kumar; D. Popov; C. Park; R. J. Hemley; et al (January 2022, Nature communications)

   - (Ed.)

   High-pressure electrical resistivity measurements reveal that the mechanical deformation of ultra-hard WB2 during compression induces superconductivity above 50 GPa with a maximum super-conducting critical temperature, Tc of 17 K at 91 GPa. Upon further compression up to 187 GPa, the Tc gradually decreases. Theoretical calculations show that electron-phonon mediated super-conductivity originates from the formation of metastable stacking faults and twin boundaries that exhibit a local structure resembling MgB2 (hP3, space group 191, prototype AlB2). Synchrotron x-ray diffraction measurements up to 145 GPa show that the ambient pressure hP12 structure (space group 194, prototype WB2) continues to persist to this pressure, consistent with the formation of the planar defects above 50 GPa. The abrupt appearance of superconductivity under pressure does not coincide with a structural transition but instead with the formation and percolation of mechanically-induced stacking faults and twin boundaries. The results identify an alternate route for designing superconducting materials. 

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2. Pressure-induced superconductivity in a novel germanium allotrope

   https://doi.org/10.1016/j.mtphys.2024.101338  

   Deng, Liangzi; Zhang, Jianbo; Sakai, Yuki; Tang, Zhongjia; Adnani, Moein; Dahal, Rabin; Litvinchuk, Alexander P.; Chelikowsky, James R.; Cohen, Marvin L.; Hemley, Russell J.; et al (February 2024, Materials Today Physics)

   - (Ed.)

   High-pressure studies on elements play an essential role in superconductivity research, with implications for both fundamental science and applications. Here we report the experimental discovery of surprisingly low pressure driving a novel germanium allotrope into a superconducting state in comparison to that for α-Ge. Raman measurements revealed structural phase transitions and possible electronic topological transitions under pressure up to 58 GPa. Based on pressure-dependent resistivity measurements, superconductivity was induced above 2 GPa and the maximum Tc of 6.8 K was observed under 4.6 GPa. Interestingly, a superconductivity enhancement was discovered during decompression, indicating the possibility of maintaining pressure-induced superconductivity at ambient pressure with better superconducting performance. Density functional theory analysis further suggested that the electronic structure of Ge (oP32) is sensitive to its detailed geometry and revealed that disorder in the β-tin structure leads to a higher Tc in comparison to the perfect β-tin Ge. 

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3. Creation, stabilization, and investigation at ambient pressure of pressure-induced superconductivity in Bi _0.5 Sb _1.5 Te ₃

   https://doi.org/10.1073/pnas.2423102122  

   Deng, Liangzi; Wang, Busheng; Halbert, Clayton; Schulze, Daniel J; Gooch, Melissa; Bontke, Trevor; Kuo, Ting-Wei; Shi, Xin; Song, Shaowei; Salke, Nilesh; et al (February 2025, Proceedings of the National Academy of Sciences)

   In light of breakthroughs in superconductivity under high pressure, and considering that record critical temperatures (T_cs) across various systems have been achieved under high pressure, the primary challenge for higher T_cshould no longer solely be to increase T_cunder extreme conditions but also to reduce, or ideally eliminate, the need for applied pressure in retaining pressure-induced or -enhanced superconductivity. The topological semiconductor Bi_0.5Sb_1.5Te₃(BST) was chosen to demonstrate our approach to addressing this challenge and exploring its intriguing physics. Under pressures up to ~50 GPa, three superconducting phases (BST-I, -II, and -III) were observed. A superconducting phase in BST-I appears at ~4 GPa, without a structural transition, suggesting the possible topological nature of this phase. Using the pressure-quench protocol (PQP) recently developed by us, we successfully retained this pressure-induced phase at ambient pressure and revealed the bulk nature of the state. Significantly, this demonstrates recovery of a pressure-quenched sample from a diamond anvil cell at room temperature with the pressure-induced phase retained at ambient pressure. Other superconducting phases were retained in BST-II and -III at ambient pressure and subjected to thermal and temporal stability testing. Superconductivity was also found in BST with T_cup to 10.2 K, the record for this compound series. While PQP maintains superconducting phases in BST at ambient pressure, both depressurization and PQP enhance its T_c, possibly due to microstructures formed during these processes, offering an added avenue to raise T_c. These findings are supported by our density-functional theory calculations. 

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4. Superconductor–insulator transitions in three-dimensional indium-oxide at high pressures

   https://doi.org/10.1088/1361-648X/ac48bf  

   Hen, Bar; Shelukhin, Victor; Greenberg, Eran; Rozenberg, Gregory Kh; Kapitulnik, Aharon; Palevski, Alexander (January 2022, Journal of Physics: Condensed Matter)

   Abstract Experiments investigating magnetic-field-tuned superconductor–insulator transition (HSIT) mostly focus on two-dimensional material systems where the transition and its proximate ground-state phases, often exhibit features that are seemingly at odds with the expected behavior. Here we present a complementary study of a three-dimensional pressure-packed amorphous indium-oxide (InOx) powder where granularity controls the HSIT. Above a low threshold pressure of ∼0.2 GPa, vestiges of superconductivity are detected, although neither a true superconducting transition nor insulating behavior are observed. Instead, a saturation at very high resistivity at low pressure is followed by saturation at very low resistivity at higher pressure. We identify both as different manifestations of anomalous metallic phases dominated by superconducting fluctuations. By analogy with previous identification of the low resistance saturation as a ‘failed superconductor’, our data suggests that the very high resistance saturation is a manifestation of a ‘failed insulator’. Above a threshold pressure of ∼6 GPa, the sample becomes fully packed, and superconductivity is robust, withT_Ctunable with pressure. A quantum critical point atP_C∼ 25 GPa marks the complete suppression of superconductivity. For a finite pressure belowP_C, a magnetic field is shown to induce a HSIT from a true zero-resistance superconducting state to a weakly insulating behavior. Determining the critical field,H_C, we show that similar to the 2D behavior, the insulating-like state maintains a superconducting character, which is quenched at higher field, above which the magnetoresistance decreases to its fermionic normal state value. 

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5. Predicted hot superconductivity in LaSc ₂ H ₂₄ under pressure

   https://doi.org/10.1073/pnas.2401840121  

   He, Xin-Ling; Zhao, Wenbo; Xie, Yu; Hermann, Andreas; Hemley, Russell J; Liu, Hanyu; Ma, Yanming (June 2024, Proceedings of the National Academy of Sciences)

   The recent theory-driven discovery of a class of clathrate hydrides (e.g., CaH₆, YH₆, YH₉, and LaH₁₀) with superconducting critical temperatures (T_c) well above 200 K has opened the prospects for “hot” superconductivity above room temperature under pressure. Recent efforts focus on the search for superconductors among ternary hydrides that accommodate more diverse material types and configurations compared to binary hydrides. Through extensive computational searches, we report the prediction of a unique class of thermodynamically stable clathrate hydrides structures consisting of two previously unreported H₂₄and H₃₀hydrogen clathrate cages at megabar pressures. Among these phases, LaSc₂H₂₄shows potential hot superconductivity at the thermodynamically stable pressure range of 167 to 300 GPa, with calculatedT_cs up to 331 K at 250 GPa and 316 K at 167 GPa when the important effects of anharmonicity are included. The very high critical temperatures are attributed to an unusually large hydrogen-derived density of states at the Fermi level arising from the newly reported peculiar H₃₀as well as H₂₄cages in the structure. Our predicted introduction of Sc in the La–H system is expected to facilitate future design and realization of hot superconductors in ternary clathrate superhydrides. 

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