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1. Synthesis and crystallographic characterization of diphenylamide rare-earth metal complexes Ln (NPh 2 ) 3 (THF) 2 and [(Ph 2 N) 2 Ln (μ-NPh 2 )] 2

   https://doi.org/10.1107/S2056989020009998  

   Palumbo, Chad T. ; Kotyk, Christopher M. ; Ziller, Joseph W. ; Evans, William J. ( September 2020 , Acta Crystallographica Section E Crystallographic Communications)

   null (Ed.)

   Studies of the coordination chemistry between the diphenylamide ligand, NPh 2 , and the smaller rare-earth Ln III ions, Ln = Y, Dy, and Er, led to the structural characterization by single-crystal X-ray diffraction crystallography of both solvated and unsolvated complexes, namely, tris(diphenylamido-κ N )bis(tetrahydrofuran-κ O )yttrium(III), Y(NPh 2 ) 3 (THF) 2 or [Y(C 12 H 10 N) 3 (C 4 H 8 O) 2 ], 1-Y , and the erbium(III) (Er), 1-Er , analogue, and bis[μ-1κ N :2(η 6 )-diphenylamido]bis[bis(diphenylamido-κ N )yttrium(III)], [(Ph 2 N) 2 Y(μ-NPh 2 )] 2 or [Y 2 (C 12 H 10 N) 6 ], 2-Y , and the dysprosium(III) (Dy), 2-Dy , analogue. The THF ligands of 1-Er are modeled with disorder across two positions with occupancies of 0.627 (12):0.323 (12) and 0.633 (7):0.367 (7). Also structurally characterized was the tetrametallic Er III bridging oxide hydrolysis product, bis(μ-diphenylamido-κ 2 N : N )bis[μ-1κ N :2(η 6 )-diphenylamido]tetrakis(diphenylamido-κ N )di-μ 3 -oxido-tetraerbium(III) benzene disolvate, {[(Ph 2 N)Er(μ-NPh 2 )] 4 (μ-O) 2 }·(C 6 H 6 ) 2 or [Er 4 (C 12 H 10 N) 8 O 2 ]·2C 6 H 6 , 3-Er . The 3-Er structure was refined as a three-component twin with occupancies 0.7375:0.2010:0.0615. 

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2. Crystallographic characterization of rare-earth cyanotriphenylborate complexes and the cyanoborates [NCBPh 3 ] 1− , [NCBPh 2 Me] 1− , and [NCBPh 2 (μ-O)BPh 2 ] 1−

   https://doi.org/10.1107/S2056989021006861  

   Dumas, Megan T. ; White, Jessica R. ; Ziller, Joseph W. ; Evans, William J. ( August 2021 , Acta Crystallographica Section E Crystallographic Communications)

   The investigation of the coordination chemistry of rare-earth metal complexes with cyanide ligands led to the isolation and crystallographic characterization of the Ln III cyanotriphenylborate complexes dichlorido(cyanotriphenylborato-κ N )tetrakis(tetrahydrofuran-κ O )lanthanide(III), [ Ln Cl 2 (C 19 H 15 BN)(C 4 H 8 O) 4 ] [lanthanide ( Ln ) = dysprosium (Dy) and yttrium Y)] from reactions of LnCl 3 , KCN, and NaBPh 4 . Attempts to independently synthesize the tetraethylammonium salt of (NCBPh 3 ) − from BPh 3 and [NEt 4 ][CN] in THF yielded crystals of the phenyl-substituted cyclic borate, tetraethylazanium 2,2,4,6-tetraphenyl-1,3,5,2λ 4 ,4,6-trioxatriborinan-2-ide, C 8 H 20 N + ·C 24 H 20 B 3 O 3 − or [NEt 4 ][B 3 (μ-O) 3 (C 6 H 5 ) 4 ]. The mechanochemical reaction of BPh 3 and [NEt 4 ][CN] without solvent produced crystals of tetraethylazanium cyanodiphenyl-λ 4 -boranyl diphenylborinate, C 8 H 20 N + ·C 25 H 20 B 2 NO − or [NEt 4 ][NCBPh 2 (μ-O)BPh 2 ]. Reaction of BPh 3 and KCN in THF in the presence of 2.2.2-cryptand (crypt) led to a crystal of bis[(2.2.2-cryptand)potassium] 2,2,4,6-tetraphenyl-1,3,5,2λ 4 ,4,6-trioxatriborinan-2-ide cyanomethyldiphenylborate tetrahydrofuran disolvate, 2C 18 H 36 KN 2 O 6 + ·C 24 H 20 B 3 O 3 − ·C 14 H 13 BN − ·2C 4 H 8 O or [K(crypt)] 2 [B 3 (μ-O) 3 (C 6 H 5 ) 4 ][NCBPh 2 Me]·2THF. The [NCBPh 2 (μ-O)BPh 2 ] 1− and (NCBPh 2 Me) 1− anions have not been structurally characterized previously. The structure of 1-Y was refined as a two-component twin with occupancy factors 0.513 (1) and 0.487 (1). In 4 , one solvent molecule was disordered and included using multiple components with partial site-occupancy factors. 

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3. Search for the dark photon in B0 → A′A′, A′ → e+e−, μ+μ−, and π+π− decays at Belle

   https://doi.org/10.1007/JHEP04(2021)191  

   Park, S.-H. ; Kwon, Y.-J. ; Adachi, I. ; Aihara, H. ; Al Said, S. ; Asner, D. M. ; Atmacan, H. ; Aushev, T. ; Ayad, R. ; Babu, V. ; et al ( April 2021 , Journal of High Energy Physics)

   null (Ed.)

   A bstract We present a search for the dark photon A ′ in the B 0 → A ′ A ′ decays, where A ′ subsequently decays to e + e − , μ + μ − , and π + π − . The search is performed by analyzing 772 × 10 6 $$ B\overline{B} $$ B B ¯ events collected by the Belle detector at the KEKB e + e − energy-asymmetric collider at the ϒ(4 S ) resonance. No signal is found in the dark photon mass range 0 . 01 GeV /c 2 ≤ m A ′ ≤ 2 . 62 GeV /c 2 , and we set upper limits of the branching fraction of B 0 → A ′ A ′ at the 90% confidence level. The products of branching fractions, $$ \mathrm{\mathcal{B}}\left({B}^0\to A^{\prime }A^{\prime}\right)\times \mathrm{\mathcal{B}}{\left(A\prime \to {e}^{+}{e}^{-}\right)}^2 $$ ℬ B 0 → A ′ A ′ × ℬ A ′ → e + e − 2 and $$ \mathrm{\mathcal{B}}\left({B}^0\to A^{\prime }A^{\prime}\right)\times \mathrm{\mathcal{B}}{\left(A\prime \to {\mu}^{+}{\mu}^{-}\right)}^2 $$ ℬ B 0 → A ′ A ′ × ℬ A ′ → μ + μ − 2 , have limits of the order of 10 − 8 depending on the A ′ mass. Furthermore, considering A ′ decay rate to each pair of charged particles, the upper limits of $$ \mathrm{\mathcal{B}}\left({B}^0\to A^{\prime }A^{\prime}\right) $$ ℬ B 0 → A ′ A ′ are of the order of 10 − 8 –10 − 5 . From the upper limits of $$ \mathrm{\mathcal{B}}\left({B}^0\to A^{\prime }A^{\prime}\right) $$ ℬ B 0 → A ′ A ′ , we obtain the Higgs portal coupling for each assumed dark photon and dark Higgs mass. The Higgs portal couplings are of the order of 10 − 2 –10 − 1 at $$ {m}_{h\prime}\simeq {m}_{B^0} $$ m h ′ ≃ m B 0 ± 40 MeV /c 2 and 10 − 1 –1 at $$ {m}_{h\prime}\simeq {m}_{B^0} $$ m h ′ ≃ m B 0 ± 3 GeV /c 2 . 

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4. Comparison of two Mn IV Mn IV -bis-μ-oxo complexes {[Mn IV (N 4 (6-Me-DPEN))] 2 (μ-O) 2 } 2+ and {[Mn IV (N 4 (6-Me-DPPN))] 2 (μ-O) 2 } 2+

   https://doi.org/10.1107/S2056989020004557  

   Coggins, Michael K. ; Downing, Alexandra N. ; Kaminsky, Werner ; Kovacs, Julie A. ( July 2020 , Acta Crystallographica Section E Crystallographic Communications)

   null (Ed.)

   The addition of tert -butyl hydroperoxide ( t BuOOH) to two structurally related Mn II complexes containing N,N -bis(6-methyl-2-pyridylmethyl)ethane-1,2-diamine (6-Me-DPEN) and N,N -bis(6-methyl-2-pyridylmethyl)propane-1,2-diamine (6-Me-DPPN) results in the formation of high-valent bis-oxo complexes, namely di-μ-oxido-bis{[ N , N -bis(6-methyl-2-pyridylmethyl)ethane-1,2-diamine]manganese(II)}( Mn — Mn ) bis(tetraphenylborate) dihydrate, [Mn(C 16 H 22 N 4 ) 2 O 2 ](C 24 H 20 B) 2 ·2H 2 O or {[Mn IV (N 4 (6-Me-DPEN))] 2 ( μ -O) 2 }(2BPh 4 )(2H 2 O) ( 1 ) and di-μ-oxido-bis{[ N , N -bis(6-methyl-2-pyridylmethyl)propane-1,3-diamine]manganese(II)}( Mn — Mn ) bis(tetraphenylborate) diethyl ether disolvate, [Mn(C 17 H 24 N 4 ) 2 O 2 ](C 24 H 20 B) 2 ·2C 4 H 10 O or {[Mn IV (N 4 (6-MeDPPN))] 2 ( μ -O) 2 }(2BPh 4 )(2Et 2 O) ( 2 ). Complexes 1 and 2 both contain the `diamond core' motif found previously in a number of iron, copper, and manganese high-valent bis-oxo compounds. The flexibility in the propyl linker in the ligand scaffold of 2 , as compared to that of the ethyl linker in 1 , results in more elongated Mn—N bonds, as one would expect. The Mn—Mn distances and Mn—O bond lengths support an Mn IV oxidation state assignment for the Mn ions in both 1 and 2 . The angles around the Mn centers are consistent with the local pseudo-octahedral geometry. 

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5. Close-up view of a luminous star-forming galaxy at z = 2.95

   https://doi.org/10.1051/0004-6361/202039743  

   Berta, S. ; Young, A. J. ; Cox, P. ; Neri, R. ; Jones, B. M. ; Baker, A. J. ; Omont, A. ; Dunne, L. ; Carnero Rosell, A. ; Marchetti, L. ; et al ( February 2021 , Astronomy & Astrophysics)

   Exploiting the sensitivity of the IRAM NOrthern Extended Millimeter Array (NOEMA) and its ability to process large instantaneous bandwidths, we have studied the morphology and other properties of the molecular gas and dust in the star forming galaxy, H-ATLAS J131611.5+281219 (HerBS-89a), at z = 2.95. High angular resolution (0 . ″3) images reveal a partial 1 . ″0 diameter Einstein ring in the dust continuum emission and the molecular emission lines of 12 CO(9−8) and H 2 O(2 02  − 1 11 ). Together with lower angular resolution (0 . ″6) images, we report the detection of a series of molecular lines including the three fundamental transitions of the molecular ion OH + , namely (1 1  − 0 1 ), (1 2  − 0 1 ), and (1 0  − 0 1 ), seen in absorption; the molecular ion CH + (1 − 0) seen in absorption, and tentatively in emission; two transitions of amidogen (NH 2 ), namely (2 02  − 1 11 ) and (2 20  − 2 11 ) seen in emission; and HCN(11 − 10) and/or NH(1 2  − 0 1 ) seen in absorption. The NOEMA data are complemented with Very Large Array data tracing the 12 CO(1 − 0) emission line, which provides a measurement of the total mass of molecular gas and an anchor for a CO excitation analysis. In addition, we present Hubble Space Telescope imaging that reveals the foreground lensing galaxy in the near-infrared (1.15  μ m). Together with photometric data from the Gran Telescopio Canarias, we derive a photometric redshift of z phot = 0.9 −0.5 +0.3 for the foreground lensing galaxy. Modeling the lensing of HerBS-89a, we reconstruct the dust continuum (magnified by a factor μ  ≃ 5.0) and molecular emission lines (magnified by μ  ∼ 4 − 5) in the source plane, which probe scales of ∼0 . ″1 (or 800 pc). The 12 CO(9 − 8) and H 2 O(2 02  − 1 11 ) emission lines have comparable spatial and kinematic distributions; the source-plane reconstructions do not clearly distinguish between a one-component and a two-component scenario, but the latter, which reveals two compact rotating components with sizes of ≈1 kpc that are likely merging, more naturally accounts for the broad line widths observed in HerBS-89a. In the core of HerBS-89a, very dense gas with n H 2  ∼ 10 7 − 9 cm −3 is revealed by the NH 2 emission lines and the possible HCN(11 − 10) absorption line. HerBS-89a is a powerful star forming galaxy with a molecular gas mass of M mol  = (2.1 ± 0.4) × 10 11   M ⊙ , an infrared luminosity of L IR  = (4.6 ± 0.4) × 10 12   L ⊙ , and a dust mass of M dust  = (2.6 ± 0.2) × 10 9   M ⊙ , yielding a dust-to-gas ratio δ GDR  ≈ 80. We derive a star formation rate SFR = 614 ± 59  M ⊙ yr −1 and a depletion timescale τ depl  = (3.4 ± 1.0) × 10 8 years. The OH + and CH + absorption lines, which trace low (∼100 cm −3 ) density molecular gas, all have their main velocity component red-shifted by Δ V  ∼ 100 km s −1 relative to the global CO reservoir. We argue that these absorption lines trace a rare example of gas inflow toward the center of a galaxy, indicating that HerBS-89a is accreting gas from its surroundings. 

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