skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Initial 40 Ar‐ 39 Ar Ages of the Paleocene‐Eocene Boundary Impact Spherules
Abstract We report40Ar‐39Ar step‐heating ages of Paleocene‐Eocene (P‐E) boundary impact spherules from Atlantic Margin coastal plain and open ocean sites. We test the hypothesis that the P‐E spherules are reworked from an earlier event (e.g., K‐Pg impact at ~66 Ma), which predicts a cooling age discordant from their depositional age of 55.93 ± 0.05 Ma at the P‐E boundary. Isochrons from the step‐heating analysis yield40Ar‐36Ar intercepts in excess of the modern in most cases, indicating that the spherules have excess radiogenic Ar (40Ar*), typical of impact glasses incompletely degassed before solidification. The weighted mean of the isochron‐corrected plateau age is 54.2 ± 2.5 Ma (1σ), and their isochron age is 55.4 ± 4.0 Ma, both indistinguishable from their P‐E depositional age, not supporting the K‐Pg reworking hypothesis. This is consistent with all other stratigraphic and geochemical evidence for an impact at the P‐E boundary and ejecta distribution by air fall.  more » « less
Award ID(s):
1737100
PAR ID:
10449072
Author(s) / Creator(s):
 ;  ;  ;  ;  
Publisher / Repository:
DOI PREFIX: 10.1029
Date Published:
Journal Name:
Geophysical Research Letters
Volume:
46
Issue:
15
ISSN:
0094-8276
Format(s):
Medium: X Size: p. 9091-9102
Size(s):
p. 9091-9102
Sponsoring Org:
National Science Foundation
More Like this
  1. Mattoon, C.M.; Vogt, R.; Escher, J.; Thompson, I. (Ed.)
    The cross-section of the thermal neutron capture41Ar(n,γ)42Ar(t1/2=32.9 y) reaction was measured by irradiating a40Ar sample at the high-flux reactor of Institut Laue-Langevin (ILL) Grenoble, France. The signature of the two-neutron capture has been observed by measuring the growth curve and identifying the 1524.6 keV γ-lines of the shorter-lived42K(12.4 h) βdaughter of42Ar. Our preliminary value of the41Ar(n,γ)42Ar thermal cross section is 240(80) mb at 25.3 meV. For the first time, direct counting of42Ar was performed using the ultra-high sensitivity technique of noble gas accelerator mass spectrometry (NOGAMS) at Argonne National Laboratory, USA. 
    more » « less
  2. Abstract Deccan Traps flood basalt volcanism affected ecosystems spanning the end‐Cretaceous mass extinction, with the most significant environmental effects hypothesized to be a consequence of the largest eruptions. The Rajahmundry Traps are the farthest exposures (~1,000 km) of Deccan basalt from the putative eruptive centers in the Western Ghats and hence represent some of the largest volume Deccan eruptions. Although the three subaerial Rajahmundry lava flows have been geochemically correlated to the Wai Subgroup of the Deccan Traps, poor precision associated with previous radioisotopic age constraints has prevented detailed comparison with potential climate effects. In this study, we use new40Ar/39Ar dates, paleomagnetic and volcanological analyses, and biostratigraphic constraints for the Rajahmundry lava flows to ascertain the timing and style of their emplacement. We find that the lower and middle flows (65.92 ± 0.25 and 65.67 ± 0.08 Ma, ±1σsystematic uncertainty) were erupted within magnetochron C29r and were a part of the Ambenali Formation of the Deccan Traps. By contrast, the uppermost flow (65.27 ± 0.08 Ma) was erupted in C29n as part of the Mahabaleshwar Formation. Given these age constraints, the Rajahmundry flows were not involved in the end‐Cretaceous extinction as previously hypothesized. To determine whether the emplacement of the Rajahmundry flows could have affected global climate, we estimated their eruptive CO2release and corresponding climate change using scalings from the LOSCAR carbon cycle model. We find that the eruptive gas emissions of these flows were insufficient to directly cause multi‐degree warming; hence, a causal relationship with significant climate warming requires additional Earth system feedbacks. 
    more » « less
  3. Abstract 39Ar with its 269‐year half‐life has great potential for constraining ocean ventilation and transport. Here we estimate the distribution of39Ar using a steady ocean circulation inverse model. Our estimates match available39Ar measurements to within an absolute error of ∼9% modern argon without major biases. We find that39Ar traces out the world ocean's ventilation pathways and that the39Ar age ΓArand the ideal mean age have broadly similar large‐scale patterns. At the surface,39Ar is close to saturated except at high latitudes. Undersaturation imparts a finite39Ar age to surface waters relative to the atmosphere, with peak values exceeding 100 years in Antarctic waters. This reservoir age is propagated into the interior with Antarctic Bottom Water, elevating ΓArby ∼50 years in the deep Pacific and Indian oceans. Our estimates identify the large‐scale gradients and uncertainty patterns of39Ar, thus providing guidance for future measurements. 
    more » « less
  4. Abstract The bulk of Uranus consists of a rock–ice core, but the relative proportions of rock and ice are unknown. Radioactive decay of potassium in the silicates produces40Ar. If transport of argon from the core to the gaseous envelope is efficient, a measurement of40Ar in the envelope will provide a direct constraint on the rock mass present (assuming a chondritic rock composition). The expected40Ar concentrations in this case would be readily detectable by a mass spectrometer carried by a future atmospheric probe. For a given envelope concentration there is a trade-off between the rock mass present and the transport efficiency; this degeneracy could be overcome by making independent determinations of the rock mass (e.g., by gravity and seismology). Primordial40Ar is a potential confounding factor, especially if Ar/H2is significantly enhanced above solar or if degassing of radiogenic40Ar were inefficient. Unfortunately, the primordial40Ar/36Ar ratio is very uncertain; better constraints on this ratio through measurement or theory would be very helpful. Pollution of the envelope by silicates is another confounding factor but can be overcome by a measurement of the alkali metals in the envelope. 
    more » « less
  5. Abstract We calculate cross sections for fine-structure transitions of Ne+, Ar+, Ne2+, and Ar2+in collisions with atomic hydrogen by using quantum-mechanical methods. Relaxation rate coefficients are calculated for temperatures up to 10,000 K. The temperature-dependent critical densities for the relaxation of Ne+, Ar+, Ne2+, and Ar2+in collisions with H have been determined and compared to the critical densities for collisions with electrons. The present calculations will be useful for studies utilizing the infrared lines [Neii] 12.8, [Neiii] 15.6, [Neiii] 36.0, [Arii] 6.99, [Ariii] 8.99, and [Ariii] 21.8μm as diagnostics of, for example, planetary nebulae and star formation. 
    more » « less