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1. The relationship between topography, bedrock weathering, and water storage across a sequence of ridges and valleys

   Pedrazas, M.A.; Hahm, W.J.; Huang, M.; Dralle, D.; Nelson, M.D.; Breunig, R.E.; Fauria, K.E.; Bryk, A.B.; Dietrich, W.E.; Rempe, D.M. (January 2021, Journal of geophysical research)

   null (Ed.)

   Bedrock weathering regulates nutrient mobilization, water storage, and soil production. Relative to the mobile soil layer, little is known about the relationship between topography and bedrock weathering. Here, we identify a common pattern of weathering and water storage across a sequence of three ridges and valleys in the sedimentary Great Valley Sequence in Northern California that share a tectonic and climate history. Deep drilling, downhole logging, and characterization of chemistry and porosity reveal two weathering fronts. The shallower front is ∼7 m deep at the ridge of all three hillslopes, and marks the extent of pervasive fracturing and oxidation of pyrite and organic carbon. A deeper weathering front marks the extent of open fractures and discoloration. This front is 11 m deep under two ridges of similar ridge-valley spacing, but 17.5 m deep under a ridge with nearly twice the ridge-valley spacing. Hence, at ridge tops, the fraction of the hillslope relief that is weathered scales with hillslope length. In all three hillslopes, below this second weathering front, closed fractures and unweathered bedrock extend about one-half the hilltop elevation above the adjacent channels. Neutron probe surveys reveal that seasonally dynamic moisture is stored to approximately the same depth as the shallow weathering front. Under the channels that bound our study hillslopes, the two weathering fronts coincide and occur within centimeters of the ground surface. Our findings provide evidence for feedbacks between erosion and weathering in mountainous landscapes that result in systematic subsurface structuring and water routing. 

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2. Mapping Variations in Bedrock Weathering With Slope Aspect Under a Sedimentary Ridge‐Valley System Using Near‐Surface Geophysics and Drilling

   https://doi.org/10.1029/2023JF007254  

   Hudson Rasmussen, Berit M.; Huang, Mong‐Han; Hahm, W. Jesse; Rempe, Daniella M.; Dralle, David; Nelson, Mariel D. (July 2023, Journal of Geophysical Research: Earth Surface)

   Abstract Understanding how soil thickness and bedrock weathering vary across ridge and valley topography is needed to constrain the flowpaths of water and sediment production within a landscape. Here, we investigate saprolite and weathered bedrock properties across a ridge‐valley system in the Northern California Coast Ranges, USA, where topography varies with slope aspect such that north‐facing slopes have thicker soils and are more densely vegetated than south‐facing slopes. We use active source seismic refraction surveys to extend observations made in boreholes to the hillslope scale. Seismic velocity models across several ridges capture a high velocity gradient zone (from 1,000 to 2,500 m/s) located ∼4–13 m below ridgetops that coincides with transitions in material strength and chemical depletion observed in boreholes. Comparing this transition depth across multiple north‐ and south‐facing slopes, we find that the thickness of saprolite does not vary with slope aspects. Additionally, seismic survey lines perpendicular and parallel to bedding planes reveal weathering profiles that thicken upslope and taper downslope to channels. Using a rock physics model incorporating seismic velocity, we estimate the total porosity of the saprolite and find that inherited fractures contribute a substantial amount of pore space in the upper 6 m, and the lateral porosity structure varies strongly with hillslope position. The aspect‐independent weathering structure suggests that the contemporary critical zone structure at Rancho Venada is a legacy of past climate and vegetation conditions. 

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3. A numerical investigation of bedrock groundwater recharge and exfiltration on soil mantled hillslopes

   https://doi.org/10.1002/hyp.13799  

   Gardner, W. Payton; Jensco, Kelsey; H. Hoylman, Zachary; Livesay, Robert; P. Maneta, Marco (June 2020, Hydrological Processes)

   Abstract Here we use Richards Equation models of variably saturated soil and bedrock groundwater flow to investigate first‐order patterns of the coupling between soil and bedrock flow systems. We utilize a Monte Carlo sensitivity analysis to identify important hillslope parameters controlling bedrock recharge and then model the transient response of bedrock and soil flow to seasonal precipitation. Our results suggest that hillslopes can be divided into three conceptual zones of groundwater interaction, (a) the zone of lateral unsaturated soil moisture accumulation (upper portion of hillslope), (b) the zone of soil saturation and bedrock recharge (middle of hillslope) and (c) the zone of saturated‐soil lateral flow and bedrock groundwater exfiltration (bottom of hillslope). Zones of groundwater interaction expand upslope during periods of precipitation and drain downslope during dry periods. The amount of water partitioned to the bedrock groundwater system a can be predicted by the ratio of bedrock to soil saturated hydraulic conductivity across a variety of hillslope configurations. Our modelled processes are qualitatively consistent with observations of shallow subsurface saturation and groundwater fluctuation on hillslopes studied in our two experimental watersheds and support a conceptual model of tightly coupled shallow and deep subsurface circulation where groundwater recharge and discharge continuously stores and releases water from longer residence time storage. 

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4. A bottom-up control on fresh-bedrock topography under landscapes

   https://doi.org/10.1073/pnas.1404763111  

   Rempe, Daniella M.; Dietrich, William E. (May 2014, Proceedings of the National Academy of Sciences)

   The depth to unweathered bedrock beneath landscapes influences subsurface runoff paths, erosional processes, moisture availability to biota, and water flux to the atmosphere. Here we propose a quantitative model to predict the vertical extent of weathered rock underlying soil-mantled hillslopes. We hypothesize that once fresh bedrock, saturated with nearly stagnant fluid, is advected into the near surface through uplift and erosion, channel incision produces a lateral head gradient within the fresh bedrock inducing drainage toward the channel. Drainage of the fresh bedrock causes weathering through drying and permits the introduction of atmospheric and biotically controlled acids and oxidants such that the boundary between weathered and unweathered bedrock is set by the uppermost elevation of undrained fresh bedrock, Z b . The slow drainage of fresh bedrock exerts a “bottom up” control on the advance of the weathering front. The thickness of the weathered zone is calculated as the difference between the predicted topographic surface profile (driven by erosion) and the predicted groundwater profile (driven by drainage of fresh bedrock). For the steady-state, soil-mantled case, a coupled analytical solution arises in which both profiles are driven by channel incision. The model predicts a thickening of the weathered zone upslope and, consequently, a progressive upslope increase in the residence time of bedrock in the weathered zone. Two nondimensional numbers corresponding to the mean hillslope gradient and mean groundwater-table gradient emerge and their ratio defines the proportion of the hillslope relief that is unweathered. Field data from three field sites are consistent with model predictions. 

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5. A low‐dimensional model of bedrock weathering and lateral flow coevolution in hillslopes: 2. Controls on weathering and permeability profiles, drainage hydraulics, and solute export pathways

   https://doi.org/10.1002/hyp.13385  

   Harman, Ciaran J.; Cosans, Cassandra L. (February 2019, Hydrological Processes)

   Abstract The advance of a chemical weathering front into the bedrock of a hillslope is often limited by the rate weathering products that can be carried away, maintaining chemical disequilibrium. If the weathering front is within the saturated zone, groundwater flow downslope may affect the rate of transport and weathering—however, weathering also modifies the rock permeability and the subsurface potential gradient that drives lateral groundwater flow. This feedback may help explain why there tends to be neither “runaway weathering” to great depth nor exposed bedrock covering much of the earth and may provide a mechanism for weathering front advance to keep pace with incision of adjacent streams into bedrock. This is the second of a two‐part paper exploring the coevolution of bedrock weathering and lateral flow in hillslopes using a simple low‐dimensional model based on hydraulic groundwater theory. Here, we show how a simplified kinetic model of 1‐D rock weathering can be extended to consider lateral flow in a 2‐D hillslope. Exact and approximate analytical solutions for the location and thickness of weathering within the hillslope are obtained for a number of cases. A location for the weathering front can be found such that lateral flow is able to export weathering products at the rate required to keep pace with stream incision at steady state. Three pathways of solute export are identified: “diffusing up,” where solutes diffuse up and away from the weathering front into the laterally flowing aquifer; “draining down,” where solutes are advected primarily downward into the unweathered bedrock; and “draining along,” where solutes travel laterally within the weathering zone. For each pathway, a different subsurface topography and overall relief of unweathered bedrock within the hillslope is needed to remove solutes at steady state. The relief each pathway requires depends on the rate of stream incision raised to a different power, such that at a given incision rate, one pathway requires minimal relief and, therefore, likely determines the steady‐state hillslope profile. 

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