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Abstract Transparent luminescent solar concentrators (TLSCs) selectively harvest ultraviolet and near‐infrared photons. Due to the absence of electrodes, busbars, and collection grids over the solar harvesting area, the device structure enables these devices to achieve the highest levels of transparency and aesthetics. Recently, COi8DFIC has been developed as a nonfullerene acceptor in organic photovoltaics with unprecedented performance. In this work, nonfullerene acceptors are introduced into TLSCs as the luminophores. The impact of COi8DFIC concentration on power conversion efficiency (PCE), aesthetic quality, and scalability is systematically studied. After device optimization, the COi8DFIC TLSCs are shown to achieve a PCE over 1.2% while the average visible transmittance exceeds 74% and color rendering index exceeds 80. This work reports the highest TLSC device efficiency at the highest visibly transparency and highlights that the photoluminescent properties of these emerging low bandgap organic molecules providing an encouraging path to higher TLSC performance.
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Ultraviolet and Near‐Infrared Dual‐Band Selective‐Harvesting Transparent Luminescent Solar Concentrators
Abstract Visibly transparent luminescent solar concentrators (TLSC) can optimize both power production and visible transparency by selectively harvesting the invisible portion of the solar spectrum. Since the primary applications of TLSCs include building envelopes, greenhouses, automobiles, signage, and mobile electronics, maintaining aesthetics and functionalities is as important as achieving high power conversion efficiencies (PCEs) in practical deployment. In this work, massive‐downshifting phosphorescent nanoclusters and fluorescent organic molecules are combined into a TLSC system as ultraviolet (UV) and near‐infrared (NIR) selective‐harvesting luminophores, respectively, demonstrating UV and NIR dual‐band selective‐harvesting TLSCs with PCE over 3%, average visible transmittance (AVT) exceeding 75% and color metrics suitable for the window industry. With distinct wavelength‐selectivity and effective utilization of the invisible portion of the solar spectrum, this work reports the highest light utilization efficiency (PCE × AVT) of 2.6 for a TLSC system, the highest PCE of any transparent photovoltaic (TPV) devices with AVT greater than 70%, and outperforms the practical limit for non‐wavelength‐selective TPV.
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- Award ID(s):
- 1702591
- PAR ID:
- 10452182
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Energy Materials
- Volume:
- 11
- Issue:
- 12
- ISSN:
- 1614-6832
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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