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Abstract Identifying and locating the geochemical and geophysical heterogeneities in the Earth’s interior is one of the most important and challenging tasks for the deep Earth scientists. Subducted oceanic crust metamorphizes into the dense eclogite in the upper mantle and is considered as a major cause of geochemical and geophysical heterogeneities in the deep Earth. In order to detect eclogitic materials inside the Earth, precise measurements of the high pressure‐temperature single‐crystal elasticity of major minerals in eclogite are thus exceedingly important. Omphacite, a Na,Al‐bearing clinopyroxene, constitutes up to 75 vol% of eclogite. In the present study, we performed the first high pressure‐temperature single‐crystal elasticity measurements of omphacite using Brillouin spectroscopy. Utilizing the finite‐strain approach, we obtained the following thermoelastic parameters for omphacite:KS0’ = 4.5(1),G0’ = 1.53(5), ∂KS0/∂T = −0.029(5) GPa/K, ∂G0/∂T = −0.013(5) GPa/K, withKS0 = 123(3) GPa,G0 = 74(2) GPa, andρ0 = 3.34(1) g/cm3. We found that the seismic velocities of undeformed eclogite are similar to pyrolite at the depths of 200–300 and 410–500 km, thus eclogite is seismically invisible at these depths. Combined with the lattice‐preferred orientations of the omphacite in naturally deformed eclogites, we also modeled seismic anisotropy of eclogite at various pressure‐temperature conditions. A 10 km thick subducted eclogitic crust can result in ∼0.2 s shear wave splitting in the Earth’s upper mantle.
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High‐Pressure Single‐Crystal Elasticity and Thermal Equation of State of Omphacite and Their Implications for the Seismic Properties of Eclogite in the Earth's Interior
Abstract Omphacite is a major mineral phase of eclogite, which provides the main driving force for the slab subduction into the Earth's interior. We have measured the single‐crystal elastic moduli of omphacite at high pressures for the first time up to 18 GPa at ambient temperature using Brillouin spectroscopy. A least squares fit of the velocity‐pressure data to the third‐order finite strain equation of state yieldsKS0′ = 4.5 (3),G0′ = 1.6 (1) withρ0 = 3.34 (1) g/cm3,KS0 = 123 (3) GPa, andG0 = 74 (2) GPa. In addition, the synchrotron single‐crystal X‐ray diffraction data have been collected up to 18 GPa and 700 K. The fitting to Holland‐Powell thermal‐pressure equation of state yieldsKT0′ = 4.6 (5) andα0 = 2.7 (8) × 10−5 K−1. Based on the obtained thermoelastic parameters of omphacite, the anisotropic seismic velocities of eclogite are modeled and compared with pyrolite between 200 and 500 km. The largest contrast between the eclogite and pyrolite in terms of seismic properties is observed between ~310 and 410 km.
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- Award ID(s):
- 1646527
- PAR ID:
- 10454000
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Journal of Geophysical Research: Solid Earth
- Volume:
- 124
- Issue:
- 3
- ISSN:
- 2169-9313
- Page Range / eLocation ID:
- p. 2368-2377
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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