Ru(II) complexes were synthesized with π‐expanding (phenyl, fluorenyl, phenanthrenyl, naphthalen‐1‐yl, naphthalene‐2‐yl, anthryl and pyrenyl groups) attached at a 1
We investigated the effect of the cation‐π interaction on the susceptibility of a tryptophan model system toward interaction with singlet oxygen, that is, type II photooxidation. The model system consists of two indole units linked to a lariat crown ether to measure the total rate of removal of singlet oxygen by the indole units in the presence of sodium cations (i.e. indole units subject to a cation‐π interaction) and in the absence of this interaction. We found that the cation‐π interaction significantly decreases the total rate of removal of singlet oxygen (
- NSF-PAR ID:
- 10455096
- Publisher / Repository:
- Wiley-Blackwell
- Date Published:
- Journal Name:
- Photochemistry and Photobiology
- Volume:
- 96
- Issue:
- 6
- ISSN:
- 0031-8655
- Page Range / eLocation ID:
- p. 1200-1207
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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