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Abstract The minerals carrying the magnetic remanence in geological samples are commonly a solid solution series of iron‐titanium spinels known as titanomagnetites. Despite the range of possible compositions within this series, micromagnetic studies that characterize the magnetic domain structures present in these minerals have typically focused on magnetite. No studies systematically comparing the domain‐states present in titanomagnetites have been undertaken since the discovery of the single vortex (SV) structure and the advent of modern micromagnetism. The magnetic properties of the titanomagnetite series are known to vary strongly with composition, which may influence the domain states present in these minerals, and therefore the magnetic stability of the samples bearing them. We present results from micromagnetic simulations of titanomagnetite ellipsoids of varying shape and composition to find the size ranges of the single domain (SD) and SV structures. These size ranges overlap, allowing for regions where the SD and SV structures are both available. These regions are of interest as they may lead to magnetic instability and “partial thermal remanent magnetization (pTRM) tails” in paleointensity experiments. We find that although this SD + SV zone occupies a narrow range of sizes for equidimensional magnetite, it is widest for intermediate (TM30‐40) titanomagnetite compositions, and increases for both oblate and prolate particles, with some compositions and sizes having an SD + SV zone up to 100s of nm wide. Our results help to explain the prevalence of pTRM tail‐like behavior in paleointensity experiments. They also highlight regions of particles with unusual domain states to target for further investigation into the definitive mechanism behind paleointensity failure.
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From Nano to Micro: Evolution of Magnetic Domain Structures in Multidomain Magnetite
Abstract Reliability of magnetic recordings of the ancient magnetic field is strongly dependent on the magnetic mineralogy of natural samples. Theoretical estimates of long‐term stability of remanence were restricted to single‐domain (SD) states, but micromagnetic models have recently demonstrated that the so‐called single‐vortex (SV) domain structure can have even higher stability that SD grains. In larger grains (10 μm in magnetite) the multidomain (MD) state dominates, so that large uniform magnetic domains are separated by narrow domain walls. In this paper we use a parallelized micromagnetic finite element model to provide resolutions of many millions of elements allowing us, for the first time, to examine the evolution of magnetic structure from a uniform state, through the SV state up to the development of the domain walls indicative of MD states. For a cuboctahedral grain of magnetite, we identify clear domain walls in grains as small as ∼3 μm with domain wall widths equal to that expected in large MD grains; we therefore put the SV to MD transition at ∼3 μm for magnetite and expect well‐defined, and stable, SV structures to be present until at least ∼1 μm when reducing the grain size. Reducing the size further shows critical dependence on the history of domain structures, particularly with SV states that transition through a so‐called “unstable zone” leading to the recently observed hard‐aligned SV states that proceed to unwind to SD yet remain hard aligned.
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- PAR ID:
- 10456563
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Geochemistry, Geophysics, Geosystems
- Volume:
- 20
- Issue:
- 6
- ISSN:
- 1525-2027
- Page Range / eLocation ID:
- p. 2907-2918
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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