Gyroid optical metamaterials consist of triply periodic chiral networks that are attractive photonic structures due to the combination of intriguing optical properties and spontaneous self‐assembly‐based fabrication routes using materials such as block copolymers. A previous experimental investigation found that gyroid metamaterials support strong circular dichroism, beyond what simulations only considering bulk interactions predict. In this work, simulations are used to unravel the contributions of bulk and surface interactions on the circular dichroism spectra of silver‐infilled gyroid metamaterial films. It is found that surface interactions have a significant, often dominating, contribution to circular dichroism. The relative strength of bulk and surface contributions can be tuned by controlling the crystallographic orientation, termination plane of the film, thickness, metal volume fraction, and defect density. Importantly, the dominance of surface interactions allows double gyroids, which are achiral in the bulk, to support strong circular dichroism responses with
Over the past two decades, metamaterials have led to an increasing number of biosensing and nanophotonic applications due to the possibility of a careful control of light propagating through subwavelength features. Chiral nanostructures (characterized by the absence of any mirror symmetry), in particular, give rise to unique chiro‐optical properties such as circular dichroism and optical activity. Here, a gyroid optical metamaterial with a periodicity of 65 nm exhibiting a strong circular dichroism at visible wavelengths is presented. This bottom‐up approach, based on metallic replication of the gyroid morphology in triblock terpolymer films, generates a large area of periodic optical metamaterials. A strong circular dichroism in gold and silver gyroid metamaterials at visible wavelengths is observed. It is shown that the circular dichroism is inherently linked to the handedness of the gyroid nanostructure and its tuneability is demonstrated. The optical effects are discussed and compared to other existing systems, showing the potential of bottom‐up approaches for large‐scale circular filters and chiral sensing.
more » « less- Award ID(s):
- 1707836
- PAR ID:
- 10457585
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Optical Materials
- Volume:
- 8
- Issue:
- 13
- ISSN:
- 2195-1071
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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