skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Printing Conductive Nanomaterials for Flexible and Stretchable Electronics: A Review of Materials, Processes, and Applications
Abstract Printed electronics is attracting a great deal of attention in both research and commercialization as it enables fabrication of large‐scale, low‐cost electronic devices on a variety of substrates. Printed electronics plays a critical role in facilitating widespread flexible electronics and more recently stretchable electronics. Conductive nanomaterials, such as metal nanoparticles and nanowires, carbon nanotubes, and graphene, are promising building blocks for printed electronics. Nanomaterial‐based printing technologies, formulation of printable inks, post‐printing treatment, and integration of functional devices have progressed substantially in the recent years. This review summarizes basic principles and recent development of common printing technologies, formulations of printable inks based on conductive nanomaterials, deposition of conductive inks via different printing techniques, and performance enhancement by using various sintering methods. While this review places emphasis on conductive nanomaterials, the printing techniques and ink formulations can be applied to other materials such as semiconducting and insulating nanomaterials. Moreover, some applications of printed flexible and stretchable electronic devices are reviewed to illustrate their potential. Finally, the future challenges and prospects for printing conductive nanomaterials are discussed.  more » « less
Award ID(s):
1728370
PAR ID:
10460955
Author(s) / Creator(s):
 ;  
Publisher / Repository:
Wiley Blackwell (John Wiley & Sons)
Date Published:
Journal Name:
Advanced Materials Technologies
Volume:
4
Issue:
5
ISSN:
2365-709X
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Personalized healthcare (PHC) is a booming sector in the health science domain wherein researchers from diverse technical backgrounds are focusing on the need for remote human health monitoring. PHC employs wearable electronics, viz. group of sensors integrated on a flexible substrate, embedded in the clothes, or attached to the body via adhesive. PHC wearable flexible electronics (FE) offer numerous advantages including being versatile, comfortable, lightweight, flexible, and body conformable. However, finding the appropriate mass manufacturing technologies for these PHC devices is still a challenge. It needs an understanding of the physics, performance, and applications of printing technologies for PHC wearables, ink preparation, and bio-compatible device fabrication. Moreover, the detailed study of the operating principle, ink, and substrate materials of the printing technologies such as inkjet printing will help identify the opportunities and emerging challenges of applying them in manufacturing of PHC wearable devices. In this article, we attempt to bridge this gap by reviewing the printing technologies in the PHC domain, especially inkjet printing in depth. This article presents a brief review of the state-of-the-art wearable devices made by various printing methods and their applications in PHC. It focuses on the evaluation and application of these printing technologies for PHC wearable FE devices, along with advancements in ink preparation and bio-compatible device fabrication. The performance of inkjet, screen, gravure, and flexography printing, as well as the inks and substrates, are comparatively analyzed to aid PHC wearable sensor design, research, fabrication, and mass manufacturing. Moreover, it identifies the application of the emerging mass-customizable printing technologies, such as inkjet printing, in the manufacturing of PHC wearable devices, and reviews the printing principles, drop generation mechanisms, ink formulations, ink-substrate interactions, and matching strategies for printing wearable devices on stretchable substrates. Four surface matching strategies are extracted from literature for the guidance of inkjet printing of PHC stretchable electronics. The electro-mechanical performance of the PHC FE devices printed using four surface matching strategies is comparatively evaluated. Further, the article extends its review by describing the scalable integration of PHC devices and finally presents the future directions of research in printing technologies for PHC wearable devices. 
    more » « less
  2. On‐skin electronics have drawn extensive attention as they revolutionize many aspects of healthcare, motion tracking, rehabilitation, robotics, human–machine interaction, among others. Flexible and stretchable strain sensors represent one of the most explored devices for on‐skin electronics. Many printing techniques have recently emerged showing great promises for manufacturing strain sensors. Herein, it is aimed to provide a timely survey of recent advancements in printed strain sensors for on‐skin electronics. This review starts with an overview of sensing mechanisms for printed strain sensors, followed by a review of various printing techniques employed in fabricating these sensors. The materials, structures, and printing processes of representative strain sensors are discussed in detail for each printing method. Finally, potential applications of printed flexible and stretchable strain sensors are presented focusing on three areas: healthcare, sports performance monitoring, and human–machine interfaces. The review concludes with a discussion of challenges and opportunities for future research. 
    more » « less
  3. Abstract The development of wireless implantable sensors and integrated systems, enabled by advances in flexible and stretchable electronics technologies, is emerging to advance human health monitoring, diagnosis, and treatment. Progress in material and fabrication strategies allows for implantable electronics for unobtrusive monitoring via seamlessly interfacing with tissues and wirelessly communicating. Combining new nanomaterials and customizable printing processes offers unique possibilities for high‐performance implantable electronics. Here, this report summarizes the recent progress and advances in nanomaterials and printing technologies to develop wireless implantable sensors and electronics. Advances in materials and printing processes are reviewed with a focus on challenges in implantable applications. Demonstrations of wireless implantable electronics and advantages based on these technologies are discussed. Lastly, existing challenges and future directions of nanomaterials and printing are described. 
    more » « less
  4. Abstract Printed electronics have made remarkable progress in recent years and inkjet printing (IJP) has emerged as one of the leading methods for fabricating printed electronic devices. However, challenges such as nozzle clogging, and strict ink formulation constraints have limited their widespread use. To address this issue, a novel nozzle‐free printing technology is explored, which is enabled by laser‐generated focused ultrasound, as a potential alternative printing modality called Shock‐wave Jet Printing (SJP). Specifically, the performance of SJP‐printed and IJP‐printed bottom‐gated carbon nanotube (CNT) thin film transistors (TFTs) is compared. While IJP required ten print passes to achieve fully functional devices with channel dimensions ranging from tens to hundreds of micrometers, SJP achieved comparable performance with just a single pass. For optimized devices, SJP demonstrated six times higher maximum mobility than IJP‐printed devices. Furthermore, the advantages of nozzle‐free printing are evident, as SJP successfully printed stored and unsonicated inks, delivering moderate electrical performance, whereas IJP suffered from nozzle clogging due to CNT agglomeration. Moreover, SJP can print significantly longer CNTs, spanning the entire range of tube lengths of commercially available CNT ink. The findings from this study contribute to the advancement of nanomaterial printing, ink formulation, and the development of cost‐effective printable electronics. 
    more » « less
  5. Abstract Over the past several years, atomically thin two‐dimensional carbides, nitrides, and carbonitrides, otherwise known asMXenes, have been expanded into over fifty material candidates that are experimentally produced, and over one hundred fifty more candidates that have been theoretically predicted. They have demonstrated transformative properties such as metallic‐type electrical conductivities, optical properties such as plasmonics and optical nonlinearity, and key surface properties such as hydrophilicity, and unique surface chemistry. In terms of their applications, they are poised to transform technological areas such as energy storage, electromagnetic shielding, electronics, photonics, optoelectronics, sensing, and bioelectronics. One of the most promising aspects ofMXene'sfuture application in all the above areas of interest, we believe, is reliably developing their flexible and bendable electronics and optoelectronics by printing methods (henceforth, termed asprinted flexible MXetronics). Designing and manipulatingMXeneconductive inks according to the application requirements will therefore be a transformative goal for future printed flexible MXetronics.MXene'scombined property of high electrical conductivity and water‐friendly nature to easily disperse its micro/nano‐flakes in an aqueous medium without any binder paves the way for designing additive‐free highly conductiveMXene ink. However, the chemical and/or structural and hence functional stability of water basedMXeneinks over time is not reliable, opening research avenues for further development of stable and conductiveMXeneinks. Such priorities will enable applications requiring high‐resolution and highly reliable printedMXeneelectronics using state‐of‐the art printing methods. EngineeringMXenestructural and surface functional properties while tuningMXeneink rheology in benign solvents of choice will be a key for ink developments. This review article summarizes the present status and prospects ofMXeneinks and their use in inkjet‐printed (IJP) technology for future flexible and bendableMXetronics. 
    more » « less