More Like this

1. Homogeneous catalysis of dioxygen reduction by molecular Mn complexes

   https://doi.org/10.1039/D2CC04628H  

   Cook, Emma N.; Machan, Charles W. (October 2022, Chemical Communications)

   Continually increasing global energy demand perpetuates the need for effective alternative energy sources and ‘green’ industrial processes. The oxygen reduction reaction (ORR) is crucial to the development of hydrogen fuel cells, a key device in the development of alternative energy sources. Further, the ORR to hydrogen peroxide by electrochemical means can provide an environmentally friendly alternative to its industrial production, which is capital and energy intensive. While Pt has traditionally been the best electrocatalyst for the ORR, inspiration from active sites in nature that bind and transport O 2 has led to the development of earth-abundant transition metal catalysts. However, despite the prevalence of Mn-based active sites that bind and activate O 2 in biological systems, there remains a lack of developed Mn-centered catalysts for ORR in comparison to Fe and Co. Here, we summarize known Mn-based molecular electrocatalysts for the ORR and describe their activity as well as future directions of the field. 

   more » « less
2. Solid State Reduction Driven Synthesis of Mn Containing Multi-principal Component Alloys

   https://doi.org/10.1007/s11661-024-07490-w  

   Jin, Wookyung; Sharma, Prince; Singh, Prashant; Kundu, Animesh; Balasubramanian, Ganesh; Chan, Helen M (October 2024, Metallurgical and Materials Transactions A)
3. Photoinduced Generation of a Durable Thermal Proton Reduction Catalyst with in Situ Conversion of Mn(bpy)(CO)3Br to Mn(bpy)2Br2

   https://doi.org/10.1021/acs.inorgchem.0c00480  

   Shirley, Hunter; Parkin, Sean; Delcamp, Jared H. (June 2020, Inorganic chemistry)
4. Influence of surface restructuring on the activity of ${\mathrm{SrTiO}}_3$ photoelectrodes for photocatalytic hydrogen reduction

   https://doi.org/10.1103/PhysRevMaterials.3.065801  

   Xiong, Yihuang; Dabo, Ismaila (June 2019, Physical Review Materials)
5. Effective reduction of ${\mathrm{PdCoO}}_2$ thin films via hydrogenation and sign tunable anomalous Hall effect

   https://doi.org/10.1103/PhysRevMaterials.5.L052001  

   Rimal, Gaurab; Schmidt, Caleb; Hijazi, Hussein; Feldman, Leonard C.; Liu, Yiting; Skoropata, Elizabeth; Lapano, Jason; Brahlek, Matthew; Mukherjee, Debangshu; Unocic, Raymond R.; et al (May 2021, Physical Review Materials)

   null (Ed.)