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1. DID THE BREVARD FAULT ZONE CONTROL NEOACADIAN CHANNEL AND ESCAPE FLOW IN THE SOUTHERN APPALACHIAN INNER PIEDMONT? EVIDENCE FROM MONAZITE U-PB GEOCHRONOLOGY AND REE GEOCHEMISTRY

   https://doi.org/10.1130/abs/2023SE-385449  

   Powell, Nicholas E.; Thigpen, Ryan; Moecher, David P.; Stowell, Harold H.; Spencer, Brandon; Merschat, Arthur; Kylander-Clark, Andrew R.C. (March 2023, Abstracts Geological Society of America)

   In the last two decades, crustal channel and escape flow, wherein long-wavelength ductile flow of lower crustal material transports mass and heat out of the collision zone, have remained among the most impactful ideas proposed to explain shortening accommodation in continental collisions. In the Inner Piedmont (IP), southern Appalachians, channel and escape flow have been previously proposed for the Devonian-Mississippian Neoacadian orogeny, and the deep exhumational level of the IP relative to other orogens in which channel flow has been proposed makes it ideal for testing the channel and escape flow models. In the IP channel flow model, the Brevard fault zone (BFZ) footwall is interpreted to buttress orogen-normal crustal flow of the hot IP in northwestern North Carolina and drive escape flow to the southwest. However, the polymetamorphic and deformational history of the southern Appalachians has made it difficult to isolate the spatial and temporal extent of thermal and deformational events driving flow of the interpreted channel. To address this, we use in situ laser ablation split stream monazite (Mz) U-Pb geochronology and geochemistry coupled with quantitative P-T data to define the extent and conditions of Paleozoic metamorphic events in the southern Appalachians of North Carolina. In this area, northwest of the BFZ, Mz dates indicate mostly Taconic (~462 Ma) and minor Neoacadian metamorphism (~368 Ma) whereas IP data show Neoacadian metamorphism (~363–330 Ma) with no Taconic ages. IP Mz also records a transition over time from HREE-poor to HREE-rich compositions, indicating Mz growth associated with both garnet growth and breakdown, respectively. This, along with diffuse chemical profiles and resorption textures in garnet, suggests that IP Mz records prograde to retrograde metamorphism. Furthermore, P-T estimates from the eastern Blue Ridge of northwestern NC are 5–9 kbar and 565–730 °C, whereas peak Neoacadian metamorphism in the IP core reached 5–8 kbar and 750–850 °C. We interpret this to indicate that the BFZ footwall acted as both a thermal and rheological boundary in northwestern NC during Neoacadian metamorphism, supporting earlier interpretations. Future work will assess the timing and conditions of metamorphism further south into the Blue Ridge and IP of South Carolina, Georgia, and Alabama. 

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2. DEFINING METAMORPHIC TIMING, EXTENT, AND CONDITIONS IN THE SOUTHERN APPALACHIAN BLUE RIDGE AND INNER PIEDMONT—INSIGHTS FROM MONAZITE XENOTIME GEOCHEMISTRY AND GEOCHRONOLOGY

   https://doi.org/10.1130/abs/2021AM-370757  

   Spencer, Brandon; Powell, Nicholas E.; Powell, Nicholas E.; Thigpen, Ryan; Thigpen, Ryan; Moecher, David P.; Moecher, David P.; Stowell, Harold H.; Stowell, Harold H.; Merschat, Arthur J.; et al (October 2021, Abstracts Geological Society of America)

   In the southern Appalachians, questions persist regarding the spatial extent and conditions of metamorphism for the Taconic, Neoacadian, and Alleghanian orogenic events. Ongoing research seeks to investigate the viability of the channel and/or escape flow models as potential mechanisms for lower crustal flow during orogenesis. Thus, metamorphism due to these events must be constrained in the central and eastern Blue Ridge (CBR, EBR) and Inner Piedmont (IP) provinces, which are key components of these models. In this contribution, we present one part of this ongoing research—recent results of monazite-xenotime U-Pb geochronology and rare earth element (REE) geochemistry from western North Carolina. Monazite and xenotime from six metasedimentary and metavolcanic samples collected from the CBR and EBR northwest of the Brevard Fault Zone (BFZ) yield Taconic U-Pb dates (> 400 Ma) and show no evidence of Neoacadian or Alleghanian mineral growth or resetting. Chondrite-normalized REE abundances for the EBR samples show minimal depletion in heavy REE (HREE) relative to light REE (LREE). Two mylonitic samples located adjacent to or within the BFZ yield both Taconic and Neoacadian dates; REE concentrations and petrography suggest that the youngest date, c.339 Ma, records retrograde xenotime and monazite growth during garnet breakdown following peak Neoacadian metamorphism and is not indicative of early Alleghanian prograde influence. In the Brevard and Brindle Creek thrust sheets of the IP, monazite and xenotime U-Pb dates from four metasedimentary samples yield Neoacadian (c. 340-360 Ma) to very early Alleghanian (c. 322-335 Ma) dates; however, the Alleghanian dates are limited to the easternmost portion of the Brindle Creek thrust sheet near the Central Piedmont Suture. Monazites from samples in the IP record varying, but pronounced, depletion in HREE relative to LREE. Combined with petrographic evidence of garnet resorption and monazite-xenotime rim growth and corresponding U-Pb dates, IP rocks likely record prograde Neoacadian metamorphism followed by retrograde monazite-xenotime growth prior to the main Alleghanian pulse. The abovementioned models are supported by these data, but additional geochemical and piezometric analyses are needed to better elucidate their impact during Neoacadian orogenesis. 

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3. Thermodynamic Modeling of the Tso Morari UHP Eclogite, NW Himalaya

   Pan, R; Macris, C.A.; Menold, C.A. (December 2019, AGU Fall Meeting 2020)

   Thermodynamic modeling is an important technique to interpret metamorphic phase relations and calculate model pressure-temperature (P-T) paths for metamorphic rocks. This study uses representative, coesite-bearing eclogites from the Tso Morari UHP terrane of the NW Himalaya to simulate its prograde metamorphism using multiple modeling programs and thermobarometry. Our modeling yields a peak metamorphism P-T of ~32-33 kbar and ~560-570 °C by the THERMOCALC345 and Theriak-Domino programs (Green et al., 2016), which is ~5 kbar higher in pressure and ~15 °C lower in temperature than that determined by using THERMOCALC333 (White et al., 2007) (~27.8 kbar and ~580 °C). The significantly higher pressure obtained using the THERMOCALC345 and Theriak-Domino is likely a result of the upgrade of thermodynamic parameters of minerals (i.e. garnet Wpy-gr and agr) in the newer a-x relations. The modeled effective bulk compositions and mineral stabilities along the calculated P-T path show different patterns under the two modeling techniques. Modeling by the Theriak-Domino programs is preferred in this case because the results are more consistent with the measured mineral compositions of our rocks. Multiple thermobarometers by garnet-omphacite-phengite, garnet-omphacite, garnet-phengite on the garnet rim, high-Si phengite and matrix omphacite yield a peak metamorphism of ~ 28.5-29.0 kbar and ~ 650-728 °C, which is generally consistent with the modeled P-T path. Based on our model calculations, the initial bulk composition measured by XRF does not represent the reactant bulk composition at the time of garnet nucleation, and this compositional discrepancy possibly is caused by the crystallization of pre-garnet minerals (i.e. hematite), reaction overstepping, or partial reequilibration. In summary, by implementing and evaluating multiple modeling strategies and considering the petrography and metamorphic mineralogy of the rocks, this study finds that the eclogite modeling using Theriak-Domino programs in the Tso Morari terrane provide more consistent metamorphic phase relations and more reasonable thermodynamic simulations regarding fractionation of the bulk composition and prograde metamorphism. References: Green et al. J Metamorph Geol 34, 845-869 (2016) White et al. J Metamorph Geol 25, 511-527 (2007) 

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4. Petrochronologic constraints on inverted metamorphism, terrane accretion, thrust stacking, and ductile flow in the Gneiss Dome belt, northern Appalachian orogen

   https://doi.org/10.1111/jmg.12741  

   Hillenbrand, Ian W.; Williams, Michael L.; Peterman, Emily M.; Jercinovic, Michael J.; Dietsch, Craig W. (August 2023, Journal of Metamorphic Geology)

   Abstract Gneiss domes are an integral element of many orogenic belts and commonly provide tectonic windows into deep crustal levels. Gneiss domes in the New England segment of the Appalachian orogen have been classically associated with diapirism and fold interference, but alternative models involving ductile flow have been proposed. We evaluate these models in the Gneiss Dome belt of western New England with U‐Th‐Pb monazite, xenotime, zircon, and titanite petrochronology and major and trace element thermobarometry. These data constrain distinct pressure–temperature–time (P‐T‐t) paths for each unit in the gneiss dome belt tectono‐stratigraphy. The structurally lowest units, Laurentia‐derived migmatitic gneisses of the Waterbury dome, document two stages of metamorphism (455–435 and 400–370 Ma) with peak Acadian metamorphic conditions of ~1.0–1.2 GPa at 750–780°C at 391 ± 7 to 386 ± 4 Ma. The next structurally higher unit, the Gondwana‐derived Taine Mountain Formation, records Taconic (peak conditions: 0.6 GPa, 600°C at 441 ± 4 Ma) and Acadian (peak: 0.8–1.0 GPa, 650°C at 377 ± 4 Ma) metamorphism. The overlying Collinsville Formation yielded a 473 ± 5 Ma crystallization age and evidence for metamorphic conditions of 650°C at 436 ± 4 Ma and 1.2–1.0 GPa, 750–775°C at 397 ± 4 to 385 ± 6 Ma. The structurally higher Sweetheart Mountain Member of the Collinsville Formation yielded only Acadian zircon, monazite, and xenotime dates and evidence for high‐pressure granulite facies metamorphism (1.8 GPa, 815°C) at circa 380–375 Ma. Cover rocks of the dome‐mantling The Straits Schist records peak conditions of ~1 GPa, 700°C at 386 ± 6 to 380 ± 4 Ma. Garnet breakdown to monazite and/or xenotime occurred in all units at circa 375–360 and 345–330 Ma. Peak Acadian metamorphic pressures increase systematically from the structurally lowest to highest units (from 1.0 to 1.8 GPa). This inverted metamorphic sequence is incompatible with the diapiric and fold interference models, which predict the highest pressures at the structurally lowest levels. Based upon P‐T‐t and structural data, we prefer a model involving, first, circa 380 Ma thrust stacking followed by syn‐collisional orogen parallel extension, ductile flow, and rise of the domes between 380 and 365 Ma. Garnet breakdown at circa 345–330 Ma is interpreted to reflect further exhumation during collapse of the Acadian orogenic plateau. These results highlight the power of integrating petrologic constraints with paired geochemical and geochronologic data from multiple chronometers to test structural and tectonic models and show that syn‐convergent orogen parallel ductile flow dramatically modified earlier accretion‐related structures in New England. Further, the Gneiss Dome belt documents gneiss dome development in a syn‐collisional, thick crust setting, providing an ancient example of middle to lower crustal processes that may be occurring today in the modern Himalaya and Pamir Range. 

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5. Insights from elastic thermobarometry into exhumation of high-pressure metamorphic rocks from Syros, Greece

   https://doi.org/10.5194/se-12-1335-2021  

   Cisneros, Miguel; Barnes, Jaime D.; Behr, Whitney M.; Kotowski, Alissa J.; Stockli, Daniel F.; Soukis, Konstantinos (January 2021, Solid Earth)

   Abstract. Retrograde metamorphic rocks provide key insights into the pressure–temperature (P–T) evolution of exhumed material, and resultant P–T constraints have direct implications for the mechanical and thermal conditions of subduction interfaces. However, constraining P–T conditions of retrograde metamorphic rocks has historically been challenging and has resulted in debate about the conditions experienced by these rocks. In this work, we combine elastic thermobarometry with oxygen isotope thermometry to quantify the P–T evolution of retrograde metamorphic rocks of the Cycladic Blueschist Unit (CBU), an exhumed subduction complex exposed on Syros, Greece. We employ quartz-in-garnet and quartz-in-epidote barometry to constrain pressures of garnet and epidote growth near peak subduction conditions and during exhumation, respectively. Oxygen isotope thermometry of quartz and calcite within boudin necks was used to estimate temperatures during exhumation and to refine pressure estimates. Three distinct pressure groups are related to different metamorphic events and fabrics: high-pressure garnet growth at ∼1.4–1.7 GPa between 500–550 ∘C, retrograde epidote growth at ∼1.3–1.5 GPa between 400–500 ∘C, and a second stage of retrograde epidote growth at ∼1.0 GPa and 400 ∘C. These results are consistent with different stages of deformation inferred from field and microstructural observations, recording prograde subduction to blueschist–eclogite facies and subsequent retrogression under blueschist–greenschist facies conditions. Our new results indicate that the CBU experienced cooling during decompression after reaching maximum high-pressure–low-temperature conditions. These P–T conditions and structural observations are consistent with exhumation and cooling within the subduction channel in proximity to the refrigerating subducting plate, prior to Miocene core-complex formation. This study also illustrates the potential of using elastic thermobarometry in combination with structural and microstructural constraints, to better understand the P–T-deformation conditions of retrograde mineral growth in high-pressure–low-temperature (HP/LT) metamorphic terranes. 

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