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Recent Advances in Dual Triplet Ketone/Transition-Metal Catalysis
Abstract Dual light-excited ketone/transition-metal catalysis is a rapidly developing field of photochemistry. It allows for versatile functionalizations of C–H or C–X bonds enabled by triplet ketone acting as a hydrogen-atom-abstracting agent, a single-electron acceptor, or a photosensitizer. This review summarizes recent developments of synthetically useful transformations promoted by the synergy between triplet ketone and transition-metal catalysis. 1 Introduction 2 Triplet Ketone Catalysis via Hydrogen Atom Transfer 2.1 Triplet Ketones with Nickel Catalysis 2.2 Triplet Ketones with Copper Catalysis 2.3 Triplet Ketones with Other Transition-Metal Catalysis 3 Triplet Ketone Catalysis via Single-Electron Transfer 4 Triplet Ketone Catalysis via Energy Transfer 5 Conclusions
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- Award ID(s):
- 1955663
- PAR ID:
- 10473949
- Publisher / Repository:
- Thieme
- Date Published:
- Journal Name:
- Synlett
- Volume:
- 34
- Issue:
- 12
- ISSN:
- 0936-5214
- Page Range / eLocation ID:
- 1289 to 1308
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1055/s-0042-1751444
