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Abstract Prior measurements at bench scale revealed that waterless urinal cartridges containing oily sealant fluids are capable of partitioning pharmaceuticals from urine and therefore reducing their concentration in wastewater. We sought to measure pharmaceutical removal from in‐use waterless urinals. We developed a method to quantify pharmaceuticals in the sealant phase, which resulted in 79 ± 30% and 71 ± 30% recovery of eight pharmaceuticals from two sealant fluids, respectively. The method was applied to sealant samples collected over three weeks from in‐use waterless urinals on a university campus. Six of eight pharmaceuticals were present in the sealant samples from 1.4 µg/L to 241 µg/L. Loads of the six pharmaceuticals detected in the sealants were removed from the receiving wastewater from 0.02 µg/day to 3.4 µg/day across the sampling period. The concentration of the pharmaceuticals were similar over time, indicating rapid saturation and washout of the sealant. We also observed relatively rapid loss of sealant at maintenance intervals consistent with the manufacturer's instructions. These findings indicate that while waterless urinals do remove some pharmaceuticals from the wastewater stream, meaningful changes to wastewater concentrations will only result if the sealant fluid and/or the urinal cartridge are significantly modified. Practitioner pointsWe developed a quantification method for pharmaceuticals in oily waterless urinal sealants.Pharmaceuticals were present at relatively low concentrations in the sealant phase of two in‐use waterless urinals.We identify engineering challenges that must be overcome to meaningfully reduce pharmaceutical loads in wastewater with waterless urinals.
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Baltimore Ecosystem Study: Code for calculations of annual pharmaceutical loads at Gwynns Falls Carroll Park
Code for analyses presented in: Fork, M.L., J. Fick, A.J. Reisinger, and E.J. Rosi. "Dosing the coast: Leaking sewage infrastructure delivers large annual loads and dynamic mixtures of pharmaceuticals to urban rivers." In press at Environmental Science and Technology. Two markdown files contains code to pre-process other data and to analyze grab samples from BES streams collected weekly from 2 Nov 2017 through 15 Nov 2018 and analyzed for 92 target pharmaceuticals. Data and methods are available via EDI at https://doi.org/10.6073/pasta/36453abc14ce8d6a33711231fdee9792. Briefly, the analyses here: A) examine spatial and temporal variability in pharmaceutical detections and concentrations among 7 BES watersheds, and B) combine measured concentrations at the watershed outlet (GFCP) with USGS streamflow data to estimate annual loads of pharmaceuticals by resampling or by interpolating concentrations over the discharge record.
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- Award ID(s):
- 1855277
- PAR ID:
- 10474683
- Publisher / Repository:
- Environmental Data Initiative
- Date Published:
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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