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Title: Synthesis of Polymer Nanoweb via a Lipid Template
We report a generalized platform for synthesizing a polymer nanoweb with a high specific surface area via a bicellar template, composed of 1,2-dipalmitoyl phosphocholine (DPPC), 1,2-dihexanoyl phosphocholine (DHPC), and 1,2-dipalmitoyl phosphoglycerol (DPPG). The pristine bicelle (in the absence of monomer or polymer) yields a variety of well-defined structures, including disc, vesicle, and perforated lamella. The addition of styrene monomers in the mixture causes bicelles to transform into lamellae. Monomers are miscible with DPPC and DPPG initially, while polymerization drives polymers to the DHPC-rich domain, resulting in a polymer nanoweb supported by the outcomes of small angle neutron scattering, differential scanning calorimetry, and transmission electron microscopy.  more » « less
Award ID(s):
1930906
PAR ID:
10481570
Author(s) / Creator(s):
; ;
Publisher / Repository:
American Chemical Society
Date Published:
Journal Name:
ACS Macro Letters
Volume:
12
Issue:
7
ISSN:
2161-1653
Page Range / eLocation ID:
993 to 998
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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