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Motivated by microfluidic applications, we investigate drag reduction in laminar pressure-driven flows in channels with streamwise-periodic superhydrophobic surfaces (SHSs) contaminated with soluble surfactant. We develop a model in the long-wave and weak-diffusion limit, where the streamwise SHS period is large compared with the channel height and the Péclet number is large. Using asymptotic and numerical techniques, we determine the influence of surfactant on drag reduction in terms of the relative strength of advection, diffusion, Marangoni effects and bulk–surface exchange. In scenarios with strong exchange, the drag reduction exhibits a complex dependence on the thickness of the bulk-concentration boundary layer and surfactant strength. Strong Marangoni effects immobilise the interface through a linear surfactant distribution, whereas weak Marangoni effects yield a quasi-stagnant cap. The quasi-stagnant cap has an intricate structure with an upstream slip region, followed by intermediate inner regions and a quasi-stagnant region that is mediated by weak bulk diffusion. The quasi-stagnant region differs from the immobile region of a classical stagnant cap, observed for instance in surfactant-laden air bubbles in water, by displaying weak slip. As exchange weakens, the bulk and interface decouple: the surfactant distribution is linear when the surfactant is strong, whilst it forms a classical stagnant cap when the surfactant is weak. The asymptotic solutions offer closed-form predictions of drag reduction across much of the parameter space, providing practical utility and enhancing understanding of surfactant dynamics in flows over SHSs.
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Laminar drag reduction in surfactant-contaminated superhydrophobic channels
Although superhydrophobic surfaces (SHSs) show promise for drag reduction applications, their performance can be compromised by traces of surfactant, which generate Marangoni stresses that increase drag. This question is addressed for soluble surfactant in a three-dimensional laminar channel flow, with periodic SHSs made of long finite-length longitudinal grooves located on both walls. We assume that bulk diffusion is sufficiently strong for cross-channel concentration gradients to be small. Exploiting long-wave theory and accounting for the difference between the rapid transverse and slower longitudinal Marangoni flows, we derive a one-dimensional model for surfactant transport from the full three-dimensional transport equations. Our one-dimensional model allows us to predict the drag reduction and surfactant distribution across the parameter space. The system exhibits multiple regimes, involving competition between Marangoni effects, bulk and interfacial diffusion, bulk and interfacial advection, shear dispersion and surfactant exchange between the bulk and the interface. We map out asymptotic regions in the high-dimensional parameter space, and derive explicit closed-form approximations of the drag reduction, without any fitting or empirical parameters. The physics underpinning the drag reduction effect and the negative effect of surfactant is discussed through analysis of the velocity field and surfactant concentrations, which show both uniform and non-uniform stress distributions. Our theoretical predictions of the drag reduction compare well with results from the literature solving numerically the full three-dimensional transport problem. Our atlas of maps provides a comprehensive analytical guide for designing surfactant-contaminated channels with SHSs, to maximise the drag reduction in applications.
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- Award ID(s):
- 2054894
- PAR ID:
- 10482548
- Publisher / Repository:
- Cambridge University Press
- Date Published:
- Journal Name:
- Journal of Fluid Mechanics
- Volume:
- 963
- ISSN:
- 0022-1120
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1017/jfm.2023.264
