Abstract Polyatomic molecules have been identified as sensitive probes of charge-parity violating and parity violating physics beyond the Standard Model (BSM). For example, many linear triatomic molecules are both laser-coolable and have parity doublets in the ground electronic state arising from the bending vibration, both features that can greatly aid BSM searches. Understanding the state is a crucial prerequisite to precision measurements with linear polyatomic molecules. Here, we characterize the fundamental bending vibration of YbOH using high-resolution optical spectroscopy on the nominally forbidden transition at 588 nm. We assign 39 transitions originating from the lowest rotational levels of the state, and accurately model the state’s structure with an effective Hamiltonian using best-fit parameters. Additionally, we perform Stark and Zeeman spectroscopy on the state and fit the molecule-frame dipole moment to Dand the effective electrong-factor to . Further, we use an empirical model to explain observed anomalous line intensities in terms of interference from spin–orbit and vibronic perturbations in the excited state. Our work is an essential step toward searches for BSM physics in YbOH and other linear polyatomic molecules.
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Electronic structure in a transition metal dipnictide TaAs2
Abstract The family of transition-metal dipnictides has been of theoretical and experimental interest because this family hosts topological states and extremely large magnetoresistance (MR). Recently, , a member of this family, has been predicted to support a topological crystalline insulating state. Here, by using high-resolution angle-resolved photoemission spectroscopy (ARPES), we reveal both closed and open pockets in the metallic Fermi surface (FS) and linearly dispersive bands on the ( ) surface, along with the presence of extreme MR observed from magneto-transport measurements. A comparison of the ARPES results with first-principles computations shows that the linearly dispersive bands on the measured surface of are trivial bulk bands. The absence of symmetry-protected surface state on the ( ) surface indicates its topologically dark nature. The presence of open FS features suggests that the open-orbit fermiology could contribute to the extremely large MR of .
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- Award ID(s):
- 1847962
- PAR ID:
- 10484608
- Publisher / Repository:
- IOP publishing
- Date Published:
- Journal Name:
- Journal of Physics: Condensed Matter
- Volume:
- 36
- Issue:
- 7
- ISSN:
- 0953-8984
- Page Range / eLocation ID:
- 075502
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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