Detrital zircon (DZ) U‐Pb laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) has revolutionised the way geologists approach many Earth science questions. Although recent research has focused on rapid sample throughput, acquisition rates are limited to 100–300 analyses h−1. We present a method to acquire zircon U‐Pb dates at rates of 120, 300, 600 and 1200 analyses h−1(30, 12, 6 and 3 s per analysis) by multi‐collector LA‐ICP‐MS. We demonstrate the efficacy of this method by analysing twelve zircon reference materials with dates from ~ 3465 to ~ 28 Ma. Mean offset from high‐precision dates increases with faster rates from 0.9% to 1.1%; mean random 1
This content will become publicly available on January 9, 2025
Detrital zircon (DZ) U–Pb geochronology has improved the way geologists approach questions of sediment provenance and stratigraphic age. However, there is debate about what constitutes an appropriate sample size (i.e., the number of dates in a DZ sample,
- NSF-PAR ID:
- 10485330
- Publisher / Repository:
- Wiley-Blackwell
- Date Published:
- Journal Name:
- Basin Research
- Volume:
- 36
- Issue:
- 1
- ISSN:
- 0950-091X
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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s uncertainty increases from 0.6% to 1.3%. We tested this new method on a sandstone sample previously characterised by large‐n DZ geochronology. Quantitative comparison shows increased correspondence among age distributions comprising > 300 dates. This new method holds promise for DZ geochronology because (a) it requires no major changes to hardware, but rather modifications to software; (b) it yields robust age distributions well‐suited for quantitative analysis and maximum depositional age calculations; (c) there is only a minor sacrifice of accuracy and measurement uncertainty; and (d) there is less burden to researchers in terms of time investment and analytical cost. -
Ascough, P. ; Dunai, T. ; King, G. ; Lang, A. ; Mezger, K. (Ed.)Detrital zircon geochronology by laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) is a widely used tool for determining maximum depositional ages and sediment provenance, as well as reconstructing sediment routing pathways. Although the accuracy and precision of U–Pb geochronology measurements have improved over the past 2 decades, Pb loss continues to impact the ability to resolve zircon age populations by biasing affected zircon toward younger apparent ages. Chemical abrasion (CA) has been shown to reduce or eliminate the effects of Pb loss in zircon U–Pb geochronology but has yet to be widely applied to large-n detrital zircon analyses. Here, we assess the efficacy of the chemical abrasion treatment on zircon prior to analysis by LA-ICP-MS and discuss the advantages and limitations of this technique in relation to detrital zircon geochronology. We show that (i) CA does not systematically bias LA-ICP-MS U–Pb dates for 13 reference materials that span a wide variety of crystallization dates and U concentrations, (ii) CA-LA-ICP-MS U–Pb zircon geochronology can reduce or eliminate Pb loss in samples that have experienced significant radiation damage, and (iii) bulk CA prior to detrital zircon U–Pb geochronology by LA-ICP-MS improves the resolution of age populations defined by 206Pb/238U dates (Neoproterozoic and younger) and increases the percentage of concordant analyses in age populations defined by 207Pb/206Pb dates (Mesoproterozoic and older). The selective dissolution of zircon that has experienced high degrees of radiation damage suggests that some detrital zircon age populations could be destroyed or have their abundance significantly modified during this process. However, we did not identify this effect in either of the detrital zircon samples that were analyzed as part of this study. We conclude that pre-treatment of detrital zircon by bulk CA may be useful for applications that require increased resolution of detrital zircon populations and increased confidence that 206Pb/238U dates are unaffected by Pb loss.more » « less
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Abstract Despite being a prominent continental-scale feature, the late Mesoproterozoic North American Midcontinent Rift did not result in the break-up of Laurentia, and subsequently underwent structural inversion. The timing of inversion is critical for constraining far-field effects of orogenesis and processes associated with the rift's failure. The Keweenaw fault in northern Michigan (USA) is a major thrust structure associated with rift inversion; it places ca. 1093 Ma rift volcanic rocks atop the post-rift Jacobsville Formation, which is folded in its footwall. Previous detrital zircon (DZ) U-Pb geochronology conducted by laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) assigned a ca. 950 Ma maximum age to the Jacobsville Formation and led researchers to interpret its deposition and deformation as postdating the ca. 1090–980 Ma Grenvillian Orogeny. In this study, we reproduced similar DZ dates using LA-ICP-MS and then dated 19 of the youngest DZ grains using high-precision chemical abrasion–isotope dilution–thermal ionization mass spectrometry (CA-ID-TIMS). The youngest DZ dated by CA-ID-TIMS at 992.51 ± 0.64 Ma (2σ) redefines the maximum depositional age of the Jacobsville Formation and overlaps with a U-Pb LA-ICP-MS date of 985.5 ± 35.8 Ma (2σ) for late-kinematic calcite veins within the brecciated Keweenaw fault zone. Collectively, these data are interpreted to constrain deposition of the Jacobsville Formation and final rift inversion to have occurred during the 1010–980 Ma Rigolet Phase of the Grenvillian Orogeny, following an earlier phase of Ottawan inversion. Far-field deformation propagated >500 km into the continental interior during the Ottawan and Rigolet phases of the Grenvillian Orogeny.more » « less
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Abstract The north–south trending, Late Cretaceous to modern Magallanes–Austral foreland basin of southernmost Patagonia lacks a unified, radiometric, age‐controlled stratigraphic framework. By simplifying the sedimentary fill of the basin to deep‐marine, shallow‐marine and terrestrial deposits, and combining 13 new U‐Pb detrital zircon maximum depositional ages (
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The Upper Cretaceous to Paleocene Yakutat Group contains a flysch unit and a mélange unit with an unknown source terrane. The provenance of detrital zircons may be the key to understanding the age of clastic units, their source terrane, and correlative rocks along the margin. Two samples were collected from remote and difficult to access areas in Glacier Bay National Park, and these samples can be compared to samples from Harlequin Lake, Russell Fiord, and Yakutat Bay to the north. We dated detrital zircons using standard LA-ICPMS methodology. A sample of Yakutat Group flysch (YGf) from the Grand Plateau Glacier is from quartzofeldspathic turbidites adjacent to the Grand Plateau pluton. It has an MDA of ~66 Ma (Maastrichtian-Paleocene), and the grain-age distribution is dominated by a broad mid-Cretaceous population with ages from ~91 to ~114 Ma, it also has a Jurassic component at ~166. A unique attribute of this sample is that 23% of the zircons are Precambrian with a bimodal population at ~1397 Ma and ~1702 Ma. A sample of sandstone from the Yakutat Group mélange (YGm) from Lituya Bay, was collected from an assemblage of dark lithic sandstones interbedded with basalt, and dark-gray bedded chert. This sample has an MDA of ~108 (Albian), and its grain-age distribution is dominated (88%)by Jurassic dates ranging from ~156 to ~188 Ma. Both samples can be correlated to similar dated units in the area in and around Yakutat Bay. The YGf sample is correlative to the primary zircon facies common to arkosic rocks in both the Yakutat Group flysch and mélange, which we refer to as the Russell zircon facies, with an MDA range from 61-72 Ma, and distinctive Precambrian populations. The YGm sample is more complicated, but it appears to belong to the Shelter Cove zircon facies, dominated by mid-Cretaceous lithic sandstones that occur only in the mélange. The Yakutat terrane has been translated along the margin of the Cordillera, and candidate correlative rocks are to the south. We are intrigued that similar facies with similar grain-age distributions occur in the Western Mélange Belt in the North Cascades foothills in WA. We evaluate the correlation and connection between the Yakutat and the WMB and post Paleocene translation of part of this once contiguous unit.more » « less
