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1. Advances in Selected Heterocyclization Methods

   https://doi.org/10.1055/s-0042-1751429  

   Rivas, Mónica; Gevorgyan, Vladimir (July 2023, Synlett)

   Abstract This Account summarizes efforts in our group toward synthesis of heterocycles in the past decade. Selected examples of transannulative heterocyclizations, intermediate construction of reactive compounds en route to these important motifs, and newer developments of a radical approach are outlined. 1 Introduction 2 Transannulative Heterocyclization 2.1 Rhodium-Catalyzed Transannulative Heterocyclization 2.2 Copper-Catalyzed Transannulative Heterocyclization 3 Synthesis of Heterocycles from Reactive Precursors 3.1 Synthesis of Heterocycles from Diazo Compounds 3.2 Synthesis of Heterocycles from Alkynones 4 Radical Heterocyclization 4.1 Light-Induced Radical Heterocyclization 4.2 Light-Free Radical Heterocyclization 7 Conclusion 

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2. The Genus Paronychia (Caryophyllaceae) in South America: Nomenclatural Review and Taxonomic Notes with the Description of a New Species from North Peru

   https://doi.org/10.3390/plants12051064  

   Iamonico, Duilio; Montesinos_Tubée, Daniel B (March 2023, Plants)

   All the names in Paronychia described from South America are investigated. Five names (P. arbuscula, P. brasiliana subsp. brasiliana var. pubescens, P. coquimbensis, P. hieronymi, and P. mandoniana) are lecto- or neotypified on specimens preserved at GOET, K, LP, and P. The typification of nine names, first proposed by Chaudhri in 1968 as the “holotype” are corrected according to Art. 9.10 of ICN. Three second-step typifications (Art. 9.17 of ICN) are proposed for P. camphorosmoides, P. communis, and P. hartwegiana. The following nomenclatural changes are proposed: P. arequipensis comb. et stat. nov. (basionym: P. microphylla subsp. microphylla var. arequepensis), P. compacta nom. nov. pro P. andina (Philippi non Gray; Art. 53.1 of ICN), P. jujuyensis comb. et stat. nov. (basionym: P. hieronymi subsp. hieronymi var. jujuyensis), P. compacta subsp. boliviana comb. nov. (basionym: P. andina subsp. boliviana), and P. compacta subsp. purpurea comb. nov. (basionym: P. andina subsp. purpurea). A new species (P. glabra sp. nov.) is proposed based on our examination of live plants and herbarium specimens. P. johnstonii subsp. johnstonii var. scabrida is synonymized (syn. nov.) with P. johnstonii. Finally, P. argyrocoma subsp. argyrocoma is excluded from South America since it was based on misidentified specimens (deposited at MO) of P. andina subsp. andina. A total of 30 species (43 taxa including subspecies, varieties, subvarieties, and forms) are recognized, highlighting that for some (Paronychia chilensis, P. communis, P. setigera) we provisionally accept Chaudhri’s infraspecific classification, since the high phenotypic variability of these taxa is quite complicated and further investigations need to solve their taxonomy. 

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3. Exploring FlyBase Data Using QuickSearch

   https://doi.org/10.1002/cpz1.731  

   Marygold, Steven J.; the FlyBase Consortium (April 2023, Current Protocols)

   Abstract FlyBase (www.flybase.org) is the primary online database of genetic, genomic, and functional information aboutDrosophila melanogaster. The long and rich history ofDrosophilaresearch, combined with recent surges in genomic‐scale and high‐throughput technologies, means that FlyBase now houses a huge quantity of data. Researchers need to be able to query these data rapidly and intuitively, and the QuickSearch tool has been designed to meet these needs. This tool is conveniently located on the FlyBase homepage and is organized into a series of simple tabbed interfaces that cover the major data and annotation classes within the database. This article describes the functionality of all aspects of the QuickSearch tool. With this knowledge, FlyBase users will be equipped to take full advantage of all QuickSearch features and thereby gain improved access to data relevant to their research. © 2023 The Authors. Current Protocols published by Wiley Periodicals LLC. Basic Protocol 1: Using the “Search FlyBase” tab of QuickSearch Basic Protocol 2: Using the “Data Class” tab of QuickSearch Basic Protocol 3: Using the “References” tab of QuickSearch Basic Protocol 4: Using the “Gene Groups” tab of QuickSearch Basic Protocol 5: Using the “Pathways” tab of QuickSearch Basic Protocol 6: Using the “GO” tab of QuickSearch Basic Protocol 7: Using the “Protein Domains” tab of QuickSearch Basic Protocol 8: Using the “Expression” tab of QuickSearch Basic Protocol 9: Using the “GAL4 etc” tab of QuickSearch Basic Protocol 10: Using the “Phenotype” tab of QuickSearch Basic Protocol 11: Using the “Human Disease” tab of QuickSearch Basic Protocol 12: Using the “Homologs” tab of QuickSearch Support Protocol 1: Managing FlyBase hit lists 

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4. Recent Advances in Dual Triplet Ketone/Transition-Metal Catalysis

   https://doi.org/10.1055/s-0042-1751444  

   Iziumchenko, Valeriia; Gevorgyan, Vladimir (July 2023, Synlett)

   Abstract Dual light-excited ketone/transition-metal catalysis is a rapidly developing field of photochemistry. It allows for versatile functionalizations of C–H or C–X bonds enabled by triplet ketone acting as a hydrogen-atom-abstracting agent, a single-electron acceptor, or a photosensitizer. This review summarizes recent developments of synthetically useful transformations promoted by the synergy between triplet ketone and transition-metal catalysis. 1 Introduction 2 Triplet Ketone Catalysis via Hydrogen Atom Transfer 2.1 Triplet Ketones with Nickel Catalysis 2.2 Triplet Ketones with Copper Catalysis 2.3 Triplet Ketones with Other Transition-Metal Catalysis 3 Triplet Ketone Catalysis via Single-Electron Transfer 4 Triplet Ketone Catalysis via Energy Transfer 5 Conclusions 

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5. Bacterial Community Structure Modulates Soil Phosphorus Turnover at Early Stages of Primary Succession

   https://doi.org/10.1029/2024GB008174  

   Wang, Yuhan; Bing, Haijian; Moorhead, Daryl L; Hou, Enqing; Wu, Yanhong; Wang, Jipeng; Duan, Chengjiao; Cui, Qingliang; Zhang, Zhiqin; Zhu, He; et al (October 2024, Global Biogeochemical Cycles)

   Abstract Microbes are the drivers of soil phosphorus (P) cycling in terrestrial ecosystems; however, the role of soil microbes in mediating P cycling in P‐rich soils during primary succession remains uncertain. This study examined the impacts of bacterial community structure (diversity and composition) and its functional potential (absolute abundances of P‐cycling functional genes) on soil P cycling along a 130‐year glacial chronosequence on the eastern Tibetan Plateau. Bacterial community structure was a better predictor of soil P fractions than P‐cycling genes along the chronosequence. After glacier retreat, the solubilization of inorganic P and the mineralization of organic P were significantly enhanced by increased bacterial diversity, changed interspecific interactions, and abundant species involved in soil P mineralization, thereby increasing P availability. Although 84% of P‐cycling genes were associated with organic P mineralization, these genes were more closely associated with soil organic carbon than with organic P. Bacterial carbon demand probably determined soil P turnover, indicating the dominant role of organic matter decomposition processes in P‐rich alpine soils. Moreover, the significant decrease in the complexity of the bacterial co‐occurrence network and the taxa‐gene‐P network at the later stage indicates a declining dominance of the bacterial community in driving soil P cycling with succession. Our results reveal that bacteria with a complex community structure have a prominent potential for biogeochemical P cycling in P‐rich soils during the early stages of primary succession. 

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