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1. Atmospheric Metallicity and C/O of HD 189733 b from High-resolution Spectroscopy

   https://doi.org/10.3847/1538-3881/ad1180  

   Finnerty, Luke; Xuan, Jerry W.; Xin, Yinzi; Liberman, Joshua; Schofield, Tobias; Fitzgerald, Michael P.; Agrawal, Shubh; Baker, Ashley; Bartos, Randall; Blake, Geoffrey A.; et al (January 2024, The Astronomical Journal)

   Abstract We present high-resolutionK-band emission spectra of the quintessential hot Jupiter HD 189733 b from the Keck Planet Imager and Characterizer. Using a Bayesian retrieval framework, we fit the dayside pressure–temperature profile, orbital kinematics, mass-mixing ratios of H₂O, CO, CH₄, NH₃, HCN, and H₂S, and the¹³CO/¹²CO ratio. We measure mass fractions of ${\mathrm{logH}}_2\mathrm{O}=-{2.0}_{-0.4}^{+0.4}$and $\mathrm{logCO}=-{2.2}_{-0.5}^{+0.5}$, and place upper limits on the remaining species. Notably, we find logCH₄< −4.5 at 99% confidence, despite its anticipated presence at the equilibrium temperature of HD 189733 b assuming local thermal equilibrium. We make a tentative (∼3σ) detection of¹³CO, and the retrieved posteriors suggest a¹²C/¹³C ratio similar to or substantially less than the local interstellar value. The possible¹³C enrichment would be consistent with accretion of fractionated material in ices or in the protoplanetary disk midplane. The retrieved abundances correspond to a substantially substellar atmospheric C/O = 0.3 ± 0.1, while the carbon and oxygen abundances are stellar to slightly superstellar, consistent with core-accretion models which predict an inverse correlation between C/O and metallicity. The specific combination of low C/O and high metallicity suggests significant accretion of solid material may have occurred late in the formation process of HD 189733 b. 

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2. The Missing Link of Sulfur Chemistry in TMC-1: The Detection of c -C ₃ H ₂ S from the GOTHAM Survey

   https://doi.org/10.3847/1538-4357/adb84c  

   Remijan, Anthony J; Changala, P Bryan; Xue, Ci; Yuan, Elsa_Q H; Duffy, Miya; Scolati, Haley N; Shingledecker, Christopher N; Speak, Thomas H; Cooke, Ilsa R; Loomis, Ryan; et al (March 2025, The Astrophysical Journal)

   Abstract We present the spectroscopic characterization of cyclopropenethione in the laboratory and detect it in space using the Green Bank Telescope Observations of TMC-1: Hunting Aromatic Molecules survey. The detection of this molecule—the missing link in understanding the C₃H₂S isomeric family in TMC-1—completes the detection of all three low-energy isomers of C₃H₂S, as both CH₂CCS and HCCCHS have been previously detected in this source. The total column density of this molecule (N_Tof $5.72_{-1.61}^{+2.65}\times 10^{10}$cm⁻²at an excitation temperature of $4.7_{-1.1}^{+1.3}$K) is smaller than both CH₂CCS and HCCCHS and follows nicely the relative dipole principle (RDP), a kinetic rule of thumb for predicting isomer abundances that suggests that, all other chemistry among a family of isomers being the same, the member with the smallest dipole (μ) should be the most abundant. The RDP now holds for the astronomical abundance ratios of both the S-bearing and O-bearing counterparts observed in TMC-1; however, CH₂CCO continues to elude detection in any astronomical source. 

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3. Keck Planet Imager and Characterizer Emission Spectroscopy of WASP-33b

   https://doi.org/10.3847/1538-3881/acda91  

   Finnerty, Luke; Schofield, Tobias; Sappey, Ben; Xuan, Jerry W.; Ruffio, Jean-Baptiste; Wang, Jason J.; Delorme, Jacques-Robert; Blake, Geoffrey A.; Buzard, Cam; Fitzgerald, Michael P.; et al (June 2023, The Astronomical Journal)

   Abstract We present Keck Planet Imager and Characterizer (KPIC) high-resolution (R∼35,000)K-band thermal emission spectroscopy of the ultrahot Jupiter WASP-33b. The use of KPIC’s single-mode fibers greatly improves both blaze and line-spread stabilities relative to slit spectrographs, enhancing the cross-correlation detection strength. We retrieve the dayside emission spectrum with a nested-sampling pipeline, which fits for orbital parameters, the atmospheric pressure–temperature profile, and the molecular abundances. We strongly detect the thermally inverted dayside and measure mass-mixing ratios for CO ( ${\mathrm{logCO}}_{\mathrm{MMR}}=-{1.1}_{-0.6}^{+0.4}$), H₂O ( ${\mathrm{logH}}_2{\mathrm{O}}_{\mathrm{MMR}}=-{4.1}_{-0.9}^{+0.7}$), and OH ( ${\mathrm{logOH}}_{\mathrm{MMR}}=-{2.1}_{-1.1}^{+0.5}$), suggesting near-complete dayside photodissociation of H₂O. The retrieved abundances suggest a carbon- and possibly metal-enriched atmosphere, with a gas-phase C/O ratio of ${0.8}_{-0.2}^{+0.1}$, consistent with the accretion of high-metallicity gas near the CO₂snow line and post-disk migration or with accretion between the soot and H₂O snow lines. We also find tentative evidence for¹²CO/¹³CO ∼ 50, consistent with values expected in protoplanetary disks, as well as tentative evidence for a metal-enriched atmosphere (2–15 × solar). These observations demonstrate KPIC’s ability to characterize close-in planets and the utility of KPIC’s improved instrumental stability for cross-correlation techniques. 

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4. Detection and Bulk Properties of the HR 8799 Planets with High-resolution Spectroscopy

   https://doi.org/10.3847/1538-3881/ac1349  

   Wang 王, Jason J. 劲飞; Ruffio, Jean-Baptiste; Morris, Evan; Delorme, Jacques-Robert; Jovanovic, Nemanja; Pezzato, Jacklyn; Echeverri, Daniel; Finnerty, Luke; Hood, Callie; Zanazzi, J. J.; et al (September 2021, The Astronomical Journal)

   Abstract Using the Keck Planet Imager and Characterizer, we obtained high-resolution (R∼ 35,000)K-band spectra of the four planets orbiting HR 8799. We clearly detected H₂O and CO in the atmospheres of HR 8799 c, d, and e, and tentatively detected a combination of CO and H₂O in b. These are the most challenging directly imaged exoplanets that have been observed at high spectral resolution to date when considering both their angular separations and flux ratios. We developed a forward-modeling framework that allows us to jointly fit the spectra of the planets and the diffracted starlight simultaneously in a likelihood-based approach and obtained posterior probabilities on their effective temperatures, surface gravities, radial velocities, and spins. We measured $v\sin \left(i\right)$values of ${10.1}_{-2.7}^{+2.8}\mathrm{km}{\mathrm{s}}^{-1}$for HR 8799 d and ${15.0}_{-2.6}^{+2.3}\mathrm{km}{\mathrm{s}}^{-1}$for HR 8799 e, and placed an upper limit of <14 km s⁻¹of HR 8799 c. Under two different assumptions of their obliquities, we found tentative evidence that rotation velocity is anticorrelated with companion mass, which could indicate that magnetic braking with a circumplanetary disk at early times is less efficient at spinning down lower-mass planets. 

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5. Gas Sources from the Coma and Nucleus of Comet 46P/Wirtanen Observed Using ALMA

   https://doi.org/10.3847/1538-4357/ace0bc  

   Cordiner, M. A.; Roth, N. X.; Milam, S. N.; Villanueva, G. L.; Bockelée-Morvan, D.; Remijan, A. J.; Charnley, S. B.; Biver, N.; Lis, D. C.; Qi, C.; et al (August 2023, The Astrophysical Journal)

   Abstract Gas-phase molecules in cometary atmospheres (comae) originate primarily from (1) outgassing by the nucleus, (2) sublimation of icy grains in the near-nucleus coma, and (3) coma (photo)chemical processes. However, the majority of cometary gases observed at radio wavelengths have yet to be mapped, so their production/release mechanisms remain uncertain. Here we present observations of six molecular species toward comet 46P/Wirtanen, obtained using the Atacama Large Millimeter/submillimeter Array during the comet’s unusually close (∼0.1 au) approach to Earth in 2018 December. Interferometric maps of HCN, CH₃OH, CH₃CN, H₂CO, CS, and HNC were obtained at an unprecedented sky-projected spatial resolution of up to 25 km, enabling the nucleus and coma sources of these molecules to be accurately quantified. The HCN, CH₃OH, and CH₃CN spatial distributions are consistent with production by direct outgassing from (or very close to) the nucleus, with a significant proportion of the observed CH₃OH originating from sublimation of icy grains in the near-nucleus coma (at a scale lengthL_p= 36 ± 7 km). On the other hand, H₂CO, CS, and HNC originate primarily from distributed coma sources (withL_pvalues in the range 550–16,000 km), the identities of which remain to be established. The HCN, CH₃OH, and HNC abundances in 46P are consistent with the average values previously observed in comets, whereas the H₂CO, CH₃CN, and CS abundances are relatively low. 

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