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Title: Germanium(II) Dithiolene Complexes
Abstract The 1 : 2 reaction of the imidazole‐based dithiolate (2) with GeCl2 • dioxane in THF/TMEDA gives3, a TMEDA‐complexed dithiolene‐based germylene. Compound3is converted to monothiolate‐complexed (5) and N‐heterocyclic carbene‐complexed (7) germanium(II) dithiolene complexes via Lewis base ligand exchange. A bis‐dithiolene‐based germylene (8), involving a 3c–4e S‐Ge‐S bond, has also been synthesized through controlled hydrolysis of7. The bonding nature of3,5, and8was investigated by both experimental and theoretical methods.  more » « less
Award ID(s):
2153978
PAR ID:
10494415
Author(s) / Creator(s):
; ; ; ; ; ;
Publisher / Repository:
Chemistry Europe
Date Published:
Journal Name:
Chemistry – A European Journal
Volume:
29
Issue:
65
ISSN:
0947-6539
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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