Abstract Stabilizing liquid–liquid interfaces, whether between miscible or immiscible liquids, is crucial for a wide range of applications, including energy storage, microreactors, and biomimetic structures. In this study, a versatile approach for stabilizing the water‐oil interface is presented using the morphological transitions that occur during the self‐assembly of anionic, cationic, and nonionic surfactants mixed with fatty acid oils. The morphological transitions underlying this approach are characterized and extensively studied through small‐angle X‐ray scattering (SAXS), rheometry, and microscopy techniques. Dissipative particle dynamics (DPD) as a simulation tool is adopted to investigate these morphological transitions both in the equilibrium ternary system as well as in the dynamic condition of the water‐oil interface. Such a versatile strategy holds promise for enhancing applications such as liquid‐in‐liquid 3D printing. Moreover, it has the potential to revolutionize a wide range of fields where stabilizing liquid–liquid interfaces not only offers unprecedented opportunities for fine‐tuning nanostructural morphologies but also imparts interesting practical features to the resulting liquid shapes. These features include perfusion capabilities, self‐healing, and porosity, which could have significant implications for various industries.
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Nanoelectrochemistry at liquid/liquid interfaces for analytical, biological, and material applications
Herein, we feature our recent efforts toward the development and application of nanoelectrochemistry at liquid/liquid interfaces, which are also known as interfaces between two immiscible electrolyte solutions (ITIES).
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- Award ID(s):
- 2046363
- PAR ID:
- 10495067
- Publisher / Repository:
- Royal society of chemistry
- Date Published:
- Journal Name:
- Chemical Communications
- Volume:
- 59
- Issue:
- 63
- ISSN:
- 1359-7345
- Page Range / eLocation ID:
- 9575 to 9590
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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