Austenitic stainless steels are used in power generation components subjected to elevated temperatures over long service lives. Replacing these components can involve lengthy lead times and deteriorate the robustness of the energy infrastructure. Wire arc directed energy deposition (WA-DED) has the potential to enable rapid manufacturing of replacement parts, but the long-term stability of microstructures and mechanical properties produced by WA-DED is not well understood. In this work, we explore the influence of aging at 650°C for 1000 h on the formation of embrittling phases, such as sigma (σ), in the commercially available austenitic stainless steel wire feedstocks 316L, 316LSi, 316H and 16-8-2. All WA-DED samples formed secondary phases at grain boundaries (likely σ, possibly other phases as well), but these phases caused negligible changes in tensile properties in 316L, 316LSi and 316H. Samples of 16-8-2 formed significant amounts of ferrite and/or martensite after aging, which increased tensile strength but reduced ductility when tested at room temperature. This work demonstrates the need to design feedstock compositions that are stable with respect to ferrite and/or martensite formation, in addition to phases typically associated with embrittlement, to ensure microstructure and mechanical property stability for high-temperature applications with long service lives.
Role of Austenite Stability in Elevated Temperature Mechanical Properties of Gas Metal Arc-Directed Energy Deposition Austenitic Stainless Steels
A gas metal-directed energy deposition process was used to fabricate builds using two commercial weld fillers used in power generation applications, 16-8-2 and 316H. Microstructure stability and mechanical properties were investigated through room-temperature and elevated temperature tensile testing and creep testing at 650°C, 750°C, and 825°C. 16-8-2 exhibited reduced austenite stability which resulted in athermal martensite formation after aging at 650°C for 1000 h and strain-induced martensite formation during room-temperature tensile testing. 316H exhibited relatively higher austenite stability due to increased alloying content, resulting in no athermal martensite or strain-induced martensite. Due to lower austenite stability, ferrite formed during creep at 650°C in 16-8-2, which resulted in reduced creep life and lower creep ductility compared to 316H. At 750°C and 825°C, when ferrite is no longer thermodynamically stable, 16-8-2 exhibited longer creep life and similar creep ductility as 316H. The formation of ferrite in 16-8-2 appears to have a greater impact on creep performance than the formation of embrittling topologically close-packed phases like the σ phase, as 316H exhibited superior creep performance while predicted to form 14 vol.% σ phase at 650°C.
more » « less- NSF-PAR ID:
- 10495243
- Publisher / Repository:
- Springer Science + Business Media
- Date Published:
- Journal Name:
- JOM
- Volume:
- 76
- Issue:
- 5
- ISSN:
- 1047-4838
- Format(s):
- Medium: X Size: p. 2268-2282
- Size(s):
- ["p. 2268-2282"]
- Sponsoring Org:
- National Science Foundation
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