skip to main content


Title: The Effect of Intracrystalline Water on the Mechanical Properties of Olivine at Room Temperature
Abstract

The effect of small concentrations of intracrystalline water on the strength of olivine is significant at asthenospheric temperatures but is poorly constrained at lower temperatures applicable to the shallow lithosphere. We examined the effect of water on the yield stress of olivine during low‐temperature plasticity using room‐temperature Berkovich nanoindentation. The presence of water in olivine (1,600 ppm H/Si) does not affect hardness or yield stress relative to dry olivine (≤40 ppm H/Si) outside of uncertainty but may slightly reduce Young’s modulus. Differences between water‐bearing and dry crystals in similar orientations were minor compared to differences between dry crystals in different orientations. These observations suggest water content does not affect the strength of olivine at low homologous temperatures. Thus, intracrystalline water does not play a role in olivine deformation at these temperatures, implying that water does not lead to weakening in the coldest portions of the mantle.

 
more » « less
Award ID(s):
1255620 1625032
NSF-PAR ID:
10495688
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  ;  ;  ;  ;  
Publisher / Repository:
DOI PREFIX: 10.1029
Date Published:
Journal Name:
Geophysical Research Letters
Volume:
51
Issue:
4
ISSN:
0094-8276
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract

    Plastic deformation of olivine at relatively low temperatures (i.e., low‐temperature plasticity) likely controls the strength of the lithospheric mantle in a variety of geodynamic contexts. Unfortunately, laboratory estimates of the strength of olivine deforming by low‐temperature plasticity vary considerably from study to study, limiting confidence in extrapolation to geological conditions. Here we present the results of deformation experiments on olivine single crystals and aggregates conducted in a deformation‐DIA at confining pressures of 5 to 9 GPa and temperatures of 298 to 1473 K. These results demonstrate that, under conditions in which low‐temperature plasticity is the dominant deformation mechanism, fine‐grained samples are stronger at yield than coarse‐grained samples, and the yield stress decreases with increasing temperature. All samples exhibited significant strain hardening until an approximately constant flow stress was reached. The magnitude of the increase in stress from the yield stress to the flow stress was independent of grain size and temperature. Cyclical loading experiments revealed a Bauschinger effect, wherein the initial yield strength is higher than the yield strength during subsequent cycles. Both strain hardening and the Bauschinger effect are interpreted to result from the development of back stresses associated with long‐range dislocation interactions. We calibrated a constitutive model based on these observations, and extrapolation of the model to geological conditions predicts that the strength of the lithosphere at yield is low compared to previous experimental predictions but increases significantly with increasing strain. Our results resolve apparent discrepancies in recent observational estimates of the strength of the oceanic lithosphere.

     
    more » « less
  2. Abstract

    To constrain the deformation, thermal evolution, and seismic properties of the mantle lithosphere beneath the Hangay Dome, we have analyzed the microstructures, crystal preferred orientations (CPO), and hydrogen concentrations of olivine and pyroxenes of 50 mantle xenoliths carried up by Cenozoic basalts from Zala, Haer, and Shavaryn‐Tsaram from Tariat, Mongolia. Most xenoliths are medium‐ to coarse‐grained spinel‐lherzolites, but four contain garnet + spinel. Coarse granular, highly annealed microstructures predominate. The microstructures are associated with well‐developed CPO, typical of deformation under high temperature, moderate pressure, and dry conditions. The hydrogen concentrations in olivine, orthopyroxene, and clinopyroxene are low and range around 5, 75, and 147 ppm H2O wt, respectively. Together, microstructures and CPO indicate that ductile deformation was followed by static recrystallization, which has annealed the microstructures but preserved the CPO and, hence, the anisotropy of physical properties. Lack of correlation between annealing and equilibrium temperatures suggest that the annealing is due to a long quiescence episode since the last deformation episode. Here, there is not evidence that the formation of Hangay Dome is associated with recent deformation in the lithospheric mantle. Calculated seismic properties show moderate seismic anisotropy, with fast propagation ofPwaves and polarization ofSwaves parallel to the flow direction and low birefringence forSwaves propagating obliquely to the flow plane. The results are consistent with weakPwave anomalies but not with the strong lowSwave velocity anomalies predicted by some tomographic models or with the high conductivity inferred from magnetotelluric data for the lithospheric mantle beneath the Hangay Dome.

     
    more » « less
  3. Hydrogen is a rapidly diffusing monovalent cation in nominally anhydrous minerals (NAMs, such as olivine, orthopyroxene, and clinopyroxene), which is potentially re-equilibrated during silicate melt-rock and aqueous fluid-rock interactions in massif and abyssal peridotites. We apply a 3D numerical diffusion modeling technique to provide first-order timescales of complete hydrogen re-equilibration in olivine, clinopyroxene, and orthopyroxene over the temperature range 600-1200°C. Model crystals are 1-3 mm along the c-axis and utilize H+ diffusion coefficients appropriate for Fe-bearing systems. Two sets of models were run with different boundary compositions: 1) “low-H models” are constrained by mineral-melt equilibrium partitioning with a basaltic melt that has 0.75 wt% H2O and 2) “high-H models,” which utilize the upper end of the estimated range of mantle water solubility for each phase. Both sets of models yield re-equilibration timescales that are identical and are fast for all phases at a given temperature. These timescales have strong log-linear trends as a function of temperature (R2 from 0.97 to 0.99) that can be used to calculate expected re-equilibration time at a given temperature and grain size. At the high end of the model temperatures (1000-1200°C), H+ completely re-equilibrates in olivine, orthopyroxene, and clinopyroxene within minutes to hours, consistent with previous studies. These short timescales indicate that xenolith NAM mantle water contents are likely to be overprinted prior to eruption. The models also resolve the decoupled water-trace element relationship in Southwest Indian Ridge peridotites, in which peridotite REE abundances are reproduced by partial melting models whereas the relatively high NAM H2O contents require later re-equilibration with melt. At temperatures of 600-800°C, which correspond to conditions of hydrothermal alteration of pyroxene to amphibole and talc, H+ re-equilibration typically occurs over a range of timescales spanning days to years. These durations are well within existing estimates for the duration of fluid flow in oceanic hydrothermal systems, suggesting that peridotite NAM water contents are susceptible to diffusive overprinting during higher temperature hydrothermal alteration. Thus, diffusion during aqueous fluid-rock interactions may also explain NAM H2O contents that are too high to reflect residues of melting. These relatively short timescales at low temperatures suggest that the origin of water contents measured in peridotite NAMs requires additional constraints on sample petrogenesis, including petrographic and trace element analyses. Our 3D model results also hint that H+ may diffuse appreciably during peridotite serpentinization, but diffusion coefficients at low temperature are unconstrained and additional experimental investigations are needed. 
    more » « less
  4. Abstract

    The constitutive behavior of faults is central to many interconnected aspects of earthquake science, from fault dynamics to induced seismicity, to seismic hazards characterization. Yet, a friction law applicable to the range of temperatures found in the brittle crust and upper mantle is still missing. In particular, rocks often exhibit a transition from steady‐state velocity‐strengthening at room temperature to velocity‐weakening in warmer conditions that is poorly understood. Here, we investigate the effect of competing healing mechanisms on the evolution of frictional resistance in a physical model of rate‐, state‐, and temperature‐dependent friction. The yield strength for fault slip depends on the real area of contact, which is modulated by the competition between the growth and erosion of interfacial micro‐asperities. Incorporating multiple healing mechanisms and rock‐forming minerals with different thermodynamic properties allows a transition of the velocity‐ and temperature‐dependence of friction at steady‐state with varying temperatures. We explain the mechanical data for granite, pyroxene, amphibole, shale, and natural fault gouges with activation energies and stress power exponent for weakening of 10–50 kJ/mol and 55–150, respectively, compatible with subcritical crack growth and inter‐granular flow in the active slip zone. Activation energies for the time‐dependent healing process in the range 90–130 kJ/mol in dry conditions and 20–65 kJ/mol in wet conditions indicate the prominence of viscoelastic collapse of microasperities in the absence of water and of pressure‐solution creep, crack healing, and cementation when assisted by pore fluids.

     
    more » « less
  5. Abstract

    For brittle friction and rock deformation, the coefficientαin the general effective stress relationσe = σ − αPpcan be approximated as unity with sufficient accuracy. However, it is uncertain ifαdeviates from unity for semibrittle flow when both brittle and intracrystalline‐plastic deformation is involved. We conducted triaxial and isostatic compression experiments on synthetic salt‐rocks (∼300 ppm water) at room temperature to test the effective stress relation in the semibrittle regime using silicone oil and argon gas as pore fluids. Confining and pore pressures were cycled while their difference (differential pressure) was kept constant, such that changes in the mechanical behavior would indicate deviation ofαfrom unity. Microstructural observations were used to determine the dependence ofαon true area of grain contact from asperity yielding. In triaxial compression experiments, semibrittle flow involves grain boundary cracking and sliding, and intragranular dislocation glide and cracking. Flow strength remains constant for changes in pore fluid pressure of more than two orders of magnitude. In isostatic compression experiments, samples show combined processes of microcracking, grain boundary sliding, dislocation glide, and fluid‐assisted grain boundary migration recrystallization. Volumetric strain depends directly on the differential pressures (i.e.,αequals one). Analysis of grain‐contact area in both experiments indicates thatαis independent of the true area of contact defined by plastic yielding at grain boundaries. The observation ofαeffectively equals one may be explained by operation of pressure‐independent intracrystalline‐plastic mechanisms and transmission of pore pressure at grain boundaries through thin fluid films.

     
    more » « less