Fused filament fabrication (FFF) of composites with compliant high-strength fibers could expand opportunities for the design and fabrication of complex flexible structures, but this topic has received limited attention. This study pursued the development of filaments consisting of ultra-high molecular weight polyethylene yarn (UHMWPE) embedded in a matrix of polycaprolactone (UPE/PCL) and successful 3D printing. The physical characteristics and printability of the filament were evaluated in terms of key parameters including spooling speed, temperature, fiber distribution (consolidated vs dispersed), and fiber volume fraction (4≤ Vf ≤30 %). An evaluation of the microstructure and tensile properties of the UPE/PCL was performed after processing and printing. Prior to printing, the filament exhibited an ultimate tensile strength (UTS) of 590±40 MPa with apparent fiber strength of 2.4 GPa. For the printed condition, the UTS reached 470±60 MPa and apparent fiber strength of 1.9 GPa. Fiber dispersion in the filament plays an important role on the printed properties and the potential for fiber degradation. Nevertheless, the strength of the UPE/PCL represents a new performance benchmark for compliant composites printed by FFF. This new material system can support applications where strength and toughness are key performance metrics in addition to flexibility. 
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                            Strength and its variability in 3D printing of polymer composites with continuous fibers
                        
                    
    
            Additive manufacturing (AM) of polymer composites with continuous fibers could play a major role in the future of aerospace and beyond but will require printed materials to achieve new levels of reliability. This study characterized the strength distribution of selected thermoplastic matrix composites as a func- tion of printing via fused filament fabrication (FFF). Experimental and commercial composite filaments of continuous carbon or Kevlar fibers were printed with volume fraction (Vf) ranging from approximately 28 to 56 %. The strength was evaluated under uniaxial tension after specific stages of printing and Weibull statistics were applied to characterize the strength distribution. There was a significant reduction in strength of the printed material with respect to the unprinted condition, regardless of reinforcement type, fiber volume fraction or printer used. Damage introduced by feed extrusion of the filament, and fiber failures induced at material deposition were most detrimental. For carbon fiber filaments, the reduc- tion ranged from approximately 10 % for an experimental material to over 60 % for a commercial filament. There was no correlation in the strength degradation or variability with Vf. The prevention of process-related fiber damage is key to advancing AM for continuous fiber composite and application to designs intended for stress-critical applications. 
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                            - Award ID(s):
- 1833854
- PAR ID:
- 10496148
- Publisher / Repository:
- Elsevier
- Date Published:
- Journal Name:
- Materials design
- ISSN:
- 0264-1275
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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