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1. Structure, Magnetism, and Multi-electron Reduction Reactivity of the Inverse Sandwich Reduced Arene La 2+ Complex [{[C 5 H 3 (SiMe 3 ) 2 ] 2 La} 2 (μ-η 6 :η 6 -C 6 H 6 )] 1–

   https://doi.org/10.1021/acs.organomet.8b00523  

   Palumbo, Chad T. ; Darago, Lucy E. ; Dumas, Megan T. ; Ziller, Joseph W. ; Long, Jeffrey R. ; Evans, William J. ( September 2018 , Organometallics)
2. Al(OR F ) 3 (R F = C(CF 3 ) 3 ) activated silica: a well-defined weakly coordinating surface anion

   https://doi.org/10.1039/C9SC05904K  

   Culver, Damien B. ; Venkatesh, Amrit ; Huynh, Winn ; Rossini, Aaron J. ; Conley, Matthew P. ( February 2020 , Chemical Science)

   Weakly Coordinating Anions (WCAs) containing electron deficient delocalized anionic fragments that are reasonably inert allow for the isolation of strong electrophiles. Perfluorinated borates, perfluorinated aluminum alkoxides, and halogenated carborane anions are a few families of WCAs that are commonly used in synthesis. Application of similar design strategies to oxide surfaces is challenging. This paper describes the reaction of Al(OR F ) 3 *PhF (R F = C(CF 3 ) 3 ) with silica partially dehydroxylated at 700 °C (SiO 2-700 ) to form the bridging silanol Si–OH⋯Al(OR F ) 3 ( 1 ). DFT calculations using small clusters to model 1 show that the gas phase acidity (GPA) of the bridging silanol is 43.2 kcal mol −1 lower than the GPA of H 2 SO 4 , but higher than the strongest carborane acids, suggesting that deprotonated 1 would be a WCA. Reactions of 1 with NOct 3 show that 1 forms weaker ion-pairs than classical WCAs, but stronger ion-pairs than carborane or borate anions. Though 1 forms stronger ion-pairs than these state-of-the-art WCAs, 1 reacts with alkylsilanes to form silylium type surface species. To the best of our knowledge, this is the first example of a silylium supported on derivatized silica. 

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3. Synthesis and Oxidation of Dirhenium C 4 , C 6 , and C 8 Complexes of the Formula (η 5 -C 5 Me 5 )Re(NO)(PR 3 )(C⋮C) n (R 3 P)(ON)Re(η 5 -C 5 Me 5 ) (R = 4-C 6 H 4 R‘, c-C 6 H 11 ):  In Search of Dications and Radical Cations with Enhanced Stabilities †

   https://doi.org/10.1021/om000961m  

   Meyer, Wayne E. ; Amoroso, Angelo J. ; Horn, Clemens R. ; Jaeger, Monika ; Gladysz, J. A. ( March 2001 , Organometallics)
4. The first potential energy surfaces for the C 6 H − –H 2 and C 6 H − –He collisional systems and their corresponding inelastic cross sections

   https://doi.org/10.1063/1.4955200  

   Walker, Kyle M. ; Dumouchel, Fabien ; Lique, François ; Dawes, Richard ( July 2016 , The Journal of Chemical Physics)
5. Isomer-Dependent Electron Affinities of Fluorophenyl Radicals, • C 6 H 5–x F x (2 ≤ x ≤ 4)

   https://doi.org/10.1021/jacs.4c00556  

   McGinnis, Kristen Rose ; McGee, Conor J. ; Jarrold, Caroline Chick ( March 2024 , Journal of the American Chemical Society)