An official website of the United States government
Abstract Owing to high modularity and synthetic tunability, metal–organic frameworks (MOFs) on textiles are poised to contribute to the development of state‐of‐the‐art wearable systems with multifunctional performance. While these composite materials have demonstrated promising functions in sensing, filtration, detoxification, and biomedicine, their applicability in multifunctional systems is only beginning to materialize. This review highlights the multifunctionality and versatility of MOF‐integrated textile systems. It summarizes the operational goals of MOF@textile composites, encompassing sensing, filtration, detoxification, drug delivery, UV protection, and photocatalysis. Building upon these recent advances, this review concludes with an outlook on emerging opportunities for the diverse applications of MOF@textile systems in the realm of smart wearables.
more »
« less
Fluoropolymer ferroelectrics: Multifunctional platform for polar-structured energy conversion
Ferroelectric materials are currently some of the most widely applied material systems and are constantly generating improved functions with higher efficiencies. Advancements in poly(vinylidene fluoride) (PVDF)–based polymer ferroelectrics provide flexural, coupling-efficient, and multifunctional material platforms for applications that demand portable, lightweight, wearable, and durable features. We highlight the recent advances in fluoropolymer ferroelectrics, their energetic cross-coupling effects, and emerging technologies, including wearable, highly efficient electromechanical actuators and sensors, electrocaloric refrigeration, and dielectric devices. These developments reveal that the molecular and nanostructure manipulations of the polarization-field interactions, through facile defect biasing, could introduce enhancements in the physical effects that would enable the realization of multisensory and multifunctional wearables for the emerging immersive virtual world and smart systems for a sustainable future.
more »
« less
- Award ID(s):
- 2103196
- PAR ID:
- 10497801
- Publisher / Repository:
- AAAS
- Date Published:
- Journal Name:
- Science
- Volume:
- 380
- Issue:
- 6645
- ISSN:
- 0036-8075
- Page Range / eLocation ID:
- eadg0902
- Format(s):
- Medium: X Size: 1.6 MB
- Size(s):
- 1.6 MB
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Abstract Rapid advances in the semiconductor industry, driven largely by device scaling, are now approaching fundamental physical limits and face severe power, performance, and cost constraints. Multifunctional materials and devices may lead to a paradigm shift toward new, intelligent, and efficient computing systems, and are being extensively studied. Herein examines how, by controlling the internal ion distribution in a solid‐state film, a material's chemical composition and physical properties can be reversibly reconfigured using an applied electric field, at room temperature and after device fabrication. Reconfigurability is observed in a wide range of materials, including commonly used dielectric films, and has led to the development of new device concepts such as resistive random‐access memory. Physical reconfigurability further allows memory and logic operations to be merged in the same device for efficient in‐memory computing and neuromorphic computing systems. By directly changing the chemical composition of the material, coupled electrical, optical, and magnetic effects can also be obtained. A survey of recent fundamental material and device studies that reveal the dynamic ionic processes is included, along with discussions on systematic modeling efforts, device and material challenges, and future research directions.more » « less
-
Abstract Metamaterials are emerging as an unconventional platform to perform computing abstractions in physical systems by processing environmental stimuli into information. While computation functions have been demonstrated in mechanical systems, they rely on compliant mechanisms to achieve predefined states, which impose inherent design restrictions that limit their miniaturization, deployment, reconfigurability, and functionality. Here, a metamaterial system is described based on responsive magnetoactive Janus particle (MAJP) swarms with multiple programmable functions. MAJPs are designed with tunable structure and properties in mind, that is, encoded swarming behavior and fully reversible switching mechanisms, to enable programmable dynamic display, non‐volatile and semi‐volatile memory, Boolean logic, and information encryption functions in soft, wearable devices. MAJPs and their unique swarming behavior open new functions for the design of multifunctional and reconfigurable display devices, and constitute a promising building block to develop the next generation of soft physical computing devices, with growing applications in security, defense, anti‐counterfeiting, camouflage, soft robotics, and human‐robot interaction.more » « less
-
Photonic technologies continue to drive the quest for new optical materials with unprecedented responses. A major frontier in this field is the exploration of nonlocal (spatially dispersive) materials, going beyond the local, wavevector-independent assumption traditionally adopted in optical material modeling. The growing interest in plasmonic, polaritonic, and quantum materials has revealed naturally occurring nonlocalities, emphasizing the need for more accurate models to predict and design their optical responses. This has major implications also for topological, nonreciprocal, and time-varying systems based on these material platforms. Beyond natural materials, artificially structured materials—metamaterials and metasurfaces—can provide even stronger and engineered nonlocal effects, emerging from long-range interactions or multipolar effects. This is a rapidly expanding area in the field of photonic metamaterials, with open frontiers yet to be explored. In metasurfaces, in particular, nonlocality engineering has emerged as a powerful tool for designing strongly wavevector-dependent responses, enabling enhanced wavefront control, spatial compression, multifunctional devices, and wave-based computing. Furthermore, nonlocality and related concepts play a critical role in defining the ultimate limits of what is possible in optics, photonics, and wave physics. This Roadmap aims to survey the most exciting developments in nonlocal photonic materials and metamaterials, highlight new opportunities and open challenges, and chart new pathways that will drive this emerging field forward—toward new scientific discoveries and technological advancements.more » « less
-
null (Ed.)Human Body Communication has shown great promise to replace wireless communication for information exchange between wearable devices of a body area network. However, there are very few studies in literature, that systematically study the channel loss of capacitive HBC for wearable devices over a wide frequency range with different terminations at the receiver, partly due to the need for miniaturized wearable devices for an accurate study. This paper, for the first time, measures the channel loss of capacitive HBC from 100KHz to 1GHz for both high-impedance and 50Ω terminations using wearable, battery powered devices; which is mandatory for accurate measurement of the HBC channel-loss, due to ground coupling effects. Results show that high impedance termination leads to a significantly lower channel loss (40 dB improvement at 1MHz), as compared to 50Ω termination at low frequencies. This difference steadily decreases with increasing frequency, until they become similar near 80MHz. Beyond 100MHz inter-device coupling dominates, thereby preventing accurate measurements of channel loss of the human body. The measured results provide a consistent wearable, wide-frequency HBC channel loss data and could serve as a backbone for the emerging field of HBC by aiding in the selection of an appropriate operation frequency and termination.more » « less
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1126/science.adg0902
