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Abstract MESSENGER observations suggest a magma ocean formed on proto-Mercury, during which evaporation of metals and outgassing of C- and H-bearing volatiles produced an early atmosphere. Atmospheric escape subsequently occurred by plasma heating, photoevaporation, Jeans escape, and photoionization. To quantify atmospheric loss, we combine constraints on the lifetime of surficial melt, melt composition, and atmospheric composition. Consideration of two initial Mercury sizes and four magma ocean compositions determines the atmospheric speciation at a given surface temperature. A coupled interior–atmosphere model determines the cooling rate and therefore the lifetime of surficial melt. Combining the melt lifetime and escape flux calculations provides estimates for the total mass loss from early Mercury. Loss rates by Jeans escape are negligible. Plasma heating and photoionization are limited by homopause diffusion rates of ∼106kg s−1. Loss by photoevaporation depends on the timing of Mercury formation and assumed heating efficiency and ranges from ∼106.6to ∼109.6kg s−1. The material for photoevaporation is sourced from below the homopause and is therefore energy limited rather than diffusion limited. The timescale for efficient interior–atmosphere chemical exchange is less than 10,000 yr. Therefore, escape processes only account for an equivalent loss of less than 2.3 km of crust (0.3% of Mercury’s mass). Accordingly, ≤0.02% of the total mass of H2O and Na is lost. Therefore, cumulative loss cannot significantly modify Mercury’s bulk mantle composition during the magma ocean stage. Mercury’s high core:mantle ratio and volatile-rich surface may instead reflect chemical variations in its building blocks resulting from its solar-proximal accretion environment.
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The Diffusion Limit of Photoevaporation in Primordial Planetary Atmospheres
Abstract Photoevaporation is thought to play an important role in early planetary evolution. In this study, we investigate the diffusion limit of X-ray- and ultraviolet-induced photoevaporation in primordial atmospheres. We find that compositional fractionation resulting from mass loss is more significant than currently recognized, because it is controlled by the conditions at the top of the atmosphere, where particle collisions are less frequent. Such fractionation at the top of the atmosphere develops a compositional gradient that extends downward. The mass outflow eventually reaches a steady state in which the hydrogen loss is diffusion-limited. We derive new analytic expressions for the diffusion-limited mass-loss rate and the crossover mass.
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- Award ID(s):
- 2224727
- PAR ID:
- 10499846
- Publisher / Repository:
- DOI PREFIX: 10.3847
- Date Published:
- Journal Name:
- The Astrophysical Journal
- Volume:
- 965
- Issue:
- 1
- ISSN:
- 0004-637X
- Format(s):
- Medium: X Size: Article No. 97
- Size(s):
- Article No. 97
- Sponsoring Org:
- National Science Foundation
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