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Abstract Photoevaporation is thought to play an important role in early planetary evolution. In this study, we investigate the diffusion limit of X-ray- and ultraviolet-induced photoevaporation in primordial atmospheres. We find that compositional fractionation resulting from mass loss is more significant than currently recognized, because it is controlled by the conditions at the top of the atmosphere, where particle collisions are less frequent. Such fractionation at the top of the atmosphere develops a compositional gradient that extends downward. The mass outflow eventually reaches a steady state in which the hydrogen loss is diffusion-limited. We derive new analytic expressions for the diffusion-limited mass-loss rate and the crossover mass.more » « less
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