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Abstract Understanding photoreaction dynamics in crystals is important for predicting the dynamic property changes accompanying these photoreactions. In this work, we investigate the photoreaction dynamics ofp‐phenylenediacrylic acid dimethyl ester (p‐PDAMe) in single crystals that show reaction front propagation, in which the photoreaction proceeds heterogeneously from the edge to the center of the crystal. Moreover, we find thatp‐PDAMesingle crystals exhibit a distinctive crystal shape change from a parallelogram to a distorted shape resembling a fluttering flag, then to a rectangle as the photoreaction proceeds. Density functional theory calculations predict the crystal structure after the photoreaction, providing a reasonable explanation of the distinctive crystal shape change that results from the spatially heterogeneous photoreaction. These results prove that the spatially heterogeneous photoreaction dynamics have the ability to induce novel crystal shape changes beyond what would be expected based on the equilibrium reactant and product crystal shapes.
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Melting of a macroscale binary Coulombic crystal
Shear of a Coulombic crystal, due to repetitive collisions with its container upon shaking, simultaneously orders and melts the crystal.
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- Award ID(s):
- 2011754
- PAR ID:
- 10500450
- Publisher / Repository:
- Royalty of Chemistry
- Date Published:
- Journal Name:
- Soft Matter
- Volume:
- 19
- Issue:
- 17
- ISSN:
- 1744-683X
- Page Range / eLocation ID:
- 3190 to 3198
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/D2SM01635D
