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1. Textural and geochemical window into the IDDP-1 rhyolitic melt, Krafla, Iceland, and its reaction to drilling

   https://doi.org/10.1130/B35598.1  

   Saubin, E.; Kennedy, B.; Tuffen, H.; Nichols, A.R.L.; Villeneuve, M.; Bindeman, I.; Mortensen, A.; Schipper, C.I.; Wadsworth, F.B.; Watson, T.; et al (January 2021, GSA Bulletin)

   null (Ed.)

   The unexpected intersection of rhyolitic magma and retrieval of quenched glass particles at the Iceland Deep Drilling Project-1 geothermal well in 2009 at Krafla, Iceland, provide unprecedented opportunities to characterize the genesis, storage, and behavior of subsurface silicic magma. In this study, we analyzed the complete time series of glass particles retrieved after magma was intersected, in terms of distribution, chemistry, and vesicle textures. Detailed analysis of the particles revealed them to represent bimodal rhyolitic magma compositions and textures. Early-retrieved clear vesicular glass has higher SiO2, crystal, and vesicle contents than later-retrieved dense brown glass. The vesicle size and distribution of the brown glass also reveal several vesicle populations. The glass particles vary in δD from −120‰ to −80‰ and have dissolved water contents spanning 1.3−2 wt%, although the majority of glass particles exhibit a narrower range. Vesicular textures indicate that volatile overpressure release predominantly occurred prior to late-stage magma ascent, and we infer that vesiculation occurred in response to drilling-induced decompression. The textures and chemistry of the rhyolitic glasses are consistent with variable partial melting of host felsite. The drilling recovery sequence indicates that the clear magma (lower degree partial melt) overlays the brown magma (higher degree partial melt). The isotopes and water species support high temperature hydration of these partial melts by a mixed meteoric and magmatic composition fluid. The textural evidence for partial melting and lack of crystallization imply that magma production is ongoing, and the growing magma body thus has a high potential for geothermal energy extraction. In summary, transfer of heat and fluids into felsite triggered variable degrees of felsite partial melting and produced a hydrated rhyolite magma with chemical and textural heterogeneities that were then enhanced by drilling perturbations. Such partial melting could occur extensively in the crust above magma chambers, where complex intrusive systems can form and supply the heat and fluids required to re-melt the host rock. Our findings emphasize the need for higher resolution geophysical monitoring of restless calderas both for hazard assessment and geothermal prospecting. We also provide insight into how shallow silicic magma reacts to drilling, which could be key to future exploration of the use of magma bodies in geothermal energy. 

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2. Insights for crystal mush storage utilizing mafic enclaves from the 2011–12 Cordón Caulle eruption

   https://doi.org/10.1038/s41598-022-13305-y  

   Winslow, Heather; Ruprecht, Philipp; Gonnermann, Helge M.; Phelps, Patrick R.; Muñoz-Saez, Carolina; Delgado, Francisco; Pritchard, Matthew; Amigo, Alvaro (December 2022, Scientific Reports)

   Abstract Two distinct types of rare crystal-rich mafic enclaves have been identified in the rhyolite lava flow from the 2011–12 Cordón Caulle eruption (Southern Andean Volcanic Zone, SVZ). The majority of mafic enclaves are coarsely crystalline with interlocking olivine-clinopyroxene-plagioclase textures and irregular shaped vesicles filling the crystal framework. These enclaves are interpreted as pieces of crystal-rich magma mush underlying a crystal-poor rhyolitic magma body that has fed recent silicic eruptions at Cordón Caulle. A second type of porphyritic enclaves, with restricted mineral chemistry and spherical vesicles, represents small-volume injections into the rhyolite magma. Both types of enclaves are basaltic end-members (up to 9.3 wt% MgO and 50–53 wt% SiO 2 ) in comparison to enclaves erupted globally. The Cordón Caulle enclaves also have one of the largest compositional gaps on record between the basaltic enclaves and the rhyolite host at 17 wt% SiO 2 . Interstitial melt in the coarsely-crystalline enclaves is compositionally identical to their rhyolitic host, suggesting that the crystal-poor rhyolite magma was derived directly from the underlying basaltic magma mush through efficient melt extraction. We suggest the 2011–12 rhyolitic eruption was generated from a primitive basaltic crystal-rich mush that short-circuited the typical full range of magmatic differentiation in a single step. 

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3. Open-system Evolution of a Crustal-scale Magma Column, Klamath Mountains, California

   https://doi.org/10.1093/petrology/egab065  

   Barnes, Calvin G; Coint, Nolwenn; Barnes, Melanie A; Chamberlain, Kevin R; Cottle, John M; Rämö, O Tapani; Strickland, Ariel; Valley, John W (December 2021, Journal of Petrology)

   Abstract This study addresses the question of how and where arc magmas obtain their chemical and isotopic characteristics. The Wooley Creek batholith and Slinkard pluton are a tilted, mid- to upper-crustal part of a vertically extensive, late-Jurassic, arc-related magmatic system in the Klamath Mountains, northern California. The main stage of the system is divided into an older lower zone (c. 159 Ma) emplaced as multiple sheet-like bodies, a younger upper zone (c. 158–156 Ma), which is gradationally zoned upward from mafic tonalite to granite, and a complex central zone, which represents the transition between the lower and upper zones. Xenoliths are common and locally abundant in the lower and central zones and preserve a ghost stratigraphy of the three host terranes. Bulk-rock Nd isotope data along with ages and Hf and oxygen isotope data on zircons were used to assess the location and timing of differentiation and assimilation. Xenoliths display a wide range of εNd (whole-rock) and εHf (zircon), ranges that correlate with rocks in the host terranes. Among individual pluton samples, zircon Hf and oxygen isotope data display ranges too large to represent uniform magma compositions, and very few data are consistent with uncontaminated mantle-derived magma. In addition, zoning of Zr and Hf in augite and hornblende indicates that zircon crystallized at temperatures near or below 800 °C; these temperatures are lower than emplacement temperatures. Therefore, the diversity of zircon isotope compositions reflects in situ crystallization from heterogeneous magmas. On the basis of these and published data, the system is interpreted to reflect initial MASH-zone differentiation, which resulted in elevated δ18O and lowered εHf in the magmas prior to zircon crystallization. Further differentiation, and particularly assimilation–fractional crystallization, occurred at the level of emplacement on a piecemeal (local) basis as individual magma batches interacted with partial melts from host-rock xenoliths. This piecemeal assimilation was accompanied by zircon crystallization, resulting in the heterogeneous isotopic signatures. Magmatism ended with late-stage emplacement of isotopically evolved granitic magmas (c. 156 Ma) whose compositions primarily reflect reworking of the deep-crustal MASH environment. 

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4. Continental rift rhyolites at the confluence of the Basin and Range and Colorado Plateau, USA: timescales of activity from the zircon and feldspar record

   Rivera, Tiffany; Jicha, Brian (January 2023, IAVCEI 2023)

   The Colorado Plateau, USA, is bordered by Pleistocene continental rift volcanism in New Mexico, Arizona, and Utah. While most of the eruptions have been basaltic, rhyolitic domes, tuffs, and lavas have been produced. On the western margin, where the Colorado Plateau meets the Basin and Range extensional province, the Black Rock Desert of central Utah hosts Pleistocene-Holocene bimodal basalt-rhyolite volcanic activity. The South Twin Complex consists of six rhyolites within a single basin erupted between 2.45 and 2.40 Ma, and they precede all Pleistocene basalts of the region. In this work, we share a new rhyolite eruptive stratigraphy based on high precision 40Ar/39Ar dates and examine the zircon crystal cargo from each eruptive center. The new eruption ages allow us to examine the spatial and temporal distribution of volcanism in the South Twin Complex, whereas the zircon crystal morphology, geochemistry, and U/Pb dating allow us to assess the conditions and timescales of silicic magma processes in the subvolcanic plumbing system. Our data suggest the plumbing system beneath the region experienced punctuated influxes of magma over a brief period of thousands to tens of thousands of years. Further, the timescales and patterns of silicic magma assembly and evolution of this small anorogenic region are similar to those observed within the voluminous Yellowstone province, suggesting that the volume of magmatic flux does not control magmatic evolution in intercontinental settings. 

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5. Zircon Constraints on the Eruptive Sequence and Magma Evolution of Rhyolites at South Sister Volcano, Oregon

   https://doi.org/10.1029/2024GC011680  

   Dechert, Annika_E; Andersen, Nathan_L; Dufek, Josef; Jilly, Christine_E (August 2024, Geochemistry, Geophysics, Geosystems)

   Abstract We present²³⁰Th‐²³⁸U crystallization ages and trace element compositions for zircons spanning the late Pleistocene to Holocene rhyolite eruptive record at South Sister volcano in the central Oregon Cascade Range. Most zircon ages are between 100 and 20 ka, with very few in secular equilibrium (>350 ka). The weighted mean of zircon ages for the two oldest South Sister rhyolites, 31.5 ± 2.1 and 39.1 ± 2.4 ka, are significantly younger than the associated⁴⁰Ar/³⁹Ar ages, 47.4 ± 9.7 and 51.4 ± 9.7 ka. We propose that these⁴⁰Ar/³⁹Ar dates, performed on plagioclase separates, are compromised by a subtle amount of excess Ar and therefore the younger weighted mean zircon ages yield more reliable eruption ages. These results imply that the interval of rhyolite eruption at South Sister during the late Pleistocene was both shorter and more productive than previously thought and that eruption at South Sister initiated after Middle Sister. Compositionally, zircons from the Pleistocene rhyolites are broadly similar and show down‐temperature zircon and plagioclase crystallization trends. However, we argue that destabilized amphibole and titanite in a common mush also exert leverage on the Pleistocene zircon trace element compositions. Divergence in the Eu/Eu* ratio between the Pleistocene and Holocene lavas implies chemically distinct magma reservoirs originating from the Pleistocene rhyolite eruptive sequence and the Holocene eruptive sequence. This work suggests a higher flux of rhyolite volcanism than previously thought and characterizes magmatic storage distinctions between the Pleistocene and Holocene rhyolites, aiding in the assessment of future eruptive hazards at South Sister volcano. 

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