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1. Investigating the [C ii]-to-H i Conversion Factor and the H i Gas Budget of Galaxies at z ≈ 6 with Hydrodynamic Simulations

   https://doi.org/10.3847/2041-8213/ac982c  

   Vizgan, David; Heintz, Kasper E.; Greve, Thomas R.; Narayanan, Desika; Davé, Romeel; Olsen, Karen P.; Popping, Gergö; Watson, Darach (October 2022, The Astrophysical Journal Letters)

   Abstract One of the most fundamental baryonic matter components of galaxies is the neutral atomic hydrogen (Hi). At low redshifts, this component can be traced directly through the 21 cm transition, but to infer the Higas content of the most distant galaxies, a viable tracer is needed. We here investigate the fidelity of the fine-structure transition of the (²P_3/2−²P_1/3) transition of singly ionized carbon Ciiat 158μm as a proxy for Hiin a set simulated galaxies atz≈ 6, following the work by Heintz et al. We select 11,125 star-forming galaxies from thesimbasimulations, with far-infrared line emissions postprocessed and modeled within the Sigameframework. We find a strong connection between Ciiand Hi, with the relation between this Cii-to-Hirelation (β_[CII]) being anticorrelated with the gas-phase metallicity of the simulated galaxies. We further use these simulations to make predictions for the total baryonic matter content of galaxies atz≈ 6, and specifically the Higas mass fraction. We find mean values ofM_{H I}/M_⋆= 1.4 andM_{H I}/M_bar,tot= 0.45. These results provide strong evidence for Hibeing the dominant baryonic matter component by mass in galaxies atz≈ 6. 

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2. Monovalent lanthanide(I) in borozene complexes

   https://doi.org/10.1038/s41467-021-26785-9  

   Li, Wan-Lu; Chen, Teng-Teng; Chen, Wei-Jia; Li, Jun; Wang, Lai-Sheng (November 2021, Nature Communications)

   Abstract Lanthanide (Ln) elements are generally found in the oxidation state +II or +III, and a few examples of +IV and +V compounds have also been reported. In contrast, monovalent Ln(+I) complexes remain scarce. Here we combine photoelectron spectroscopy and theoretical calculations to study Ln-doped octa-boron clusters (LnB₈⁻, Ln = La, Pr, Tb, Tm, Yb) with the rare +I oxidation state. The global minimum of the LnB₈⁻species changes fromC_stoC_7vsymmetry accompanied by an oxidation-state change from +III to +I from the early to late lanthanides. All theC_7v-LnB₈⁻clusters can be viewed as a monovalent Ln(I) coordinated by a η⁸-B₈²⁻doubly aromatic ligand. The B₇³⁻, B₈²⁻, and B₉⁻series of aromatic boron clusters are analogous to the classical aromatic hydrocarbon molecules, C₅H₅⁻, C₆H₆, and C₇H₇⁺, respectively, with similar trends of size and charge state and they are named collectively as “borozenes”. Lanthanides with variable oxidation states and magnetic properties may be formed with different borozenes. 

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3. Photodriven Elimination of Chlorine From Germanium and Platinum in a Dinuclear Pt ^II →Ge ^IV Complex

   https://doi.org/10.1002/anie.202107485  

   Karimi, Mohammadjavad; Tabei, Elham S.; Fayad, Remi; Saber, Mohamed R.; Danilov, Evgeny O.; Jones, Cameron; Castellano, Felix N.; Gabbaï, François P. (September 2021, Angewandte Chemie International Edition)

   Abstract Searching for a connection between the two‐electron redox behavior of Group‐14 elements and their possible use as platforms for the photoreductive elimination of chlorine, we have studied the photochemistry of [(o‐(Ph₂P)C₆H₄)₂Ge^IVCl₂]Pt^IICl₂and [(o‐(Ph₂P)C₆H₄)₂ClGe^III]Pt^IIICl₃, two newly isolated isomeric complexes. These studies show that, in the presence of a chlorine trap, both isomers convert cleanly into the platinum germyl complex [(o‐(Ph₂P)C₆H₄)₂ClGe^III]Pt^ICl with quantum yields of 1.7 % and 3.2 % for the Ge^IV–Pt^IIand Ge^III–Pt^IIIisomers, respectively. Conversion of the Ge^IV–Pt^IIisomer into the platinum germyl complex is a rare example of a light‐induced transition‐metal/main‐group‐element bond‐forming process. Finally, transient‐absorption‐spectroscopy studies carried out on the Ge^III–Pt^IIIisomer point to a ligand arene–Cl^.charge‐transfer complex as an intermediate. 

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4. Structural insights into supramolecular interactions in isostructural salts of 2,4,6-triaminopyrimidinium with various heterocyclic carboxylates

   https://doi.org/10.1107/S2053229624008787  

   Mohana, Marimuthu; Gomathi, Sundaramoorthy; Thomas_Muthiah, Packianathan; Butcher, Ray J (November 2024, Acta Crystallographica Section C Structural Chemistry)

   2,4,6-Triaminopyrimidine is an interesting and challenging molecule due to the presence of multiple hydrogen-bond donors and acceptors. Its noncovalent interactions with a variety of carboxylic acids provide several supramolecular aggregates with frequently occurring molecular synthons. The present work focuses on the supramolecular interactions of 2,4,6-triaminopyrimidinium 3-(indol-3-yl)propionate–3-(indol-3-yl)propionic acid (1/1), C₄H₈N₅⁺·C₁₁H₁₀NO₂⁻·C₁₁H₁₁NO₂, (I), 2,4,6-triaminopyrimidinium 2-(indol-3-yl)acetate, C₄H₈N₅⁺·C₁₀H₈NO₂⁻, (II), 2,4,6-triaminopyrimidinium 5-bromothiophene-2-carboxylate, C₄H₈N₅⁺·C₅H₂BrO₂S⁻, (III), and 2,4,6-triaminopyrimidinium 5-chlorothiophene-2-carboxylate, C₄H₈N₅⁺·C₅H₂ClO₂S⁻, (IV). All four salts exhibit robust homomeric and heteromericR₂²(8) ring motifs. Salts (I) and (II) develop sextuple [in (I)] and quadruple [in (I) and (II)] hydrogen-bonded arrays through fused-ring motifs. Salt (II) exhibits a rosette-like architecture. Salt (IV) is isostructural and isomorphous with salt (III), exhibiting an identical crystal structure with a different composition and an identical supramolecular architecture. In salts (III) and (IV), a linear hetero-tetrameric motif is formed and, in addition, both salts exhibit halogen–π interactions which enhance the crystal stability. All four salts develop a supramolecular hydrogen-bonded pattern facilitated by several N—H...O and N—H...N hydrogen bonds with multiple furcated donors and acceptors. 

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5. SN 2024ggi in NGC 3621: Rising Ionization in a Nearby, Circumstellar-material-interacting Type II Supernova

   https://doi.org/10.3847/1538-4357/ad5c64  

   Jacobson-Galán, W V; Davis, K W; Kilpatrick, C D; Dessart, L; Margutti, R; Chornock, R; Foley, R J; Arunachalam, P; Auchettl, K; Bom, C R; et al (September 2024, The Astrophysical Journal)

   Abstract We present UV–optical–near-infrared observations and modeling of supernova (SN) 2024ggi, a type II supernova (SN II) located in NGC 3621 at 7.2 Mpc. Early-time (“flash”) spectroscopy of SN 2024ggi within +0.8 days of discovery shows emission lines of Hi, Hei, Ciii, and Niiiwith a narrow core and broad, symmetric wings (i.e., “IIn-like”) arising from the photoionized, optically thick, unshocked circumstellar material (CSM) that surrounded the progenitor star at shock breakout (SBO). By the next spectral epoch at +1.5 days, SN 2024ggi showed a rise in ionization as emission lines of Heii, Civ, Niv/v, and Ovbecame visible. This phenomenon is temporally consistent with a blueward shift in the UV–optical colors, both likely the result of SBO in an extended, dense CSM. The IIn-like features in SN 2024ggi persist on a timescale oft_IIn= 3.8 ± 1.6 days, at which time a reduction in CSM density allows the detection of Doppler-broadened features from the fastest SN material. SN 2024ggi has peak UV–optical absolute magnitudes ofM_w2= −18.7 mag andM_g= −18.1 mag, respectively, that are consistent with the known population of CSM-interacting SNe II. Comparison of SN 2024ggi with a grid of radiation hydrodynamics and non–local thermodynamic equilibrium radiative-transfer simulations suggests a progenitor mass-loss rate of $\dot{M}={10}^{-2}{M}_{\odot }$yr⁻¹(v_w= 50 km s⁻¹), confined to a distance ofr< 5 × 10¹⁴cm. Assuming a wind velocity ofv_w= 50 km s⁻¹, the progenitor star underwent an enhanced mass-loss episode in the last ∼3 yr before explosion. 

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