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Title: Exploring sulfur donor atom coordination chemistry with La( ii ), Nd( ii ), and Tm( ii ) using a terphenylthiolate ligand

To expand the range of donor atoms known to stabilize 4fn5d1Ln(ii) ions beyond C, N, and O first row main group donor atoms, the Ln(iii) terphenylthiolate iodides, LnIII(SAriPr6)2I (AriPr6= C6H3-2,6-(C6H2-2,4,6-iPr3)2, Ln = La, Nd) were reduced to LnII(SAriPr6)2complexes.

 
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Award ID(s):
2154255
NSF-PAR ID:
10506406
Author(s) / Creator(s):
; ; ; ; ;
Publisher / Repository:
Royal Society of Chemistry
Date Published:
Journal Name:
Chemical Communications
Volume:
60
Issue:
34
ISSN:
1359-7345
Page Range / eLocation ID:
4601 to 4604
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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