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1. Generalized T _e ([O iii ])– T _e (He i ) Discrepancies in Ionized Nebulae: Possible Evidence of Case B Deviations and Temperature Inhomogeneities

   https://doi.org/10.3847/1538-4357/adc67a  

   Méndez-Delgado, J E; Skillman, E D; Aver, E; Morisset, C; Esteban, C; García-Rojas, J; Kreckel, K; Rogers, N_S J; Rosales-Ortega, F F; Arellano-Córdova, K Z; et al (June 2025, The Astrophysical Journal)

   Abstract The physics of recombination lines in the Heisinglet system is expected to be relatively simple, supported by accurate atomic models. We examine the intensities of Heisingletsλ3614, λ3965, λ5016, λ6678, and λ7281 and the triplet Heiλ5876 in various types of ionized nebulae and compare them with theoretical predictions to test the validity of the “Case B” recombination scenario and the assumption of thermal homogeneity. Our analysis includes 85 spectra from Galactic and extragalactic Hiiregions, 90 from star-forming galaxies, and 218 from planetary nebulae, all compiled by the Deep Spectra of Ionized Regions Database Extended (DESIRED-E) project. By evaluating the ratios Heiλ7281/λ6678 and Heiλ7281/λ5876, we determineT_e(Hei) and compare it with direct measurements ofT_e([Oiii]λ4363/λ5007). We find thatT_e(Hei) is systematically lower thanT_e([Oiii]) across most objects and nebula types. Additionally, we identify a correlation between the abundance discrepancy factor (ADF(O²⁺)) and the differenceT_e([Oiii]) –T_e(Hei) for planetary nebulae. We explore two potential explanations: photon loss fromn¹P → 1¹Stransitions and temperature inhomogeneities. Deviations from “Case B” may indicate photon absorption by Hirather than Heiand/or generalized ionizing photon escape, highlighting the need for detailed consideration of radiative transfer effects. If temperature inhomogeneities are widespread, identifying a common physical phenomenon affecting all ionized nebulae is crucial. Our results suggest that both scenarios can contribute to the observed discrepancies. 

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2. Efficient Ionizers with Low H β + [O iii ] Equivalent Widths: JADES Spectroscopy of a Peculiar High-redshift Population

   https://doi.org/10.3847/1538-4357/adddb5  

   Laseter, Isaac H; Maseda, Michael V; Simmonds, Charlotte; Endsley, Ryan; Stark, Daniel; Bunker, Andrew J; Bhatawdekar, Rachana; Boyett, Kristan; Cameron, Alex J; Carniani, Stefano; et al (July 2025, The Astrophysical Journal)

   Abstract Early JWST photometric studies discovered a population of UV-faint ( $<{\mathit{L}}_{\mathrm{UV}}^{*}$)z ∼ 6.5–8 Lyman break galaxies with spectral energy distributions implying young ages (∼10 Myr) yet relatively weak Hβ+ [Oiii] equivalent widths (EW_{Hβ+ [Oiii]} ≈ 400 Å). These galaxies seemingly contradict the implicit understanding that young star-forming galaxies are ubiquitously strong Hβ+ [Oiii] emitters, i.e., extreme emission line galaxies (EW ≳750 Å). Low metallicities, high Lyman continuum escape fractions, and rapidly declining star formation histories have been proposed as primary drivers behind low Hβ+ [Oiii] EWs, but the blend of Hβ+ [Oiii] in photometric studies makes proving one of these scenarios difficult. We aim to characterize this peculiar population with deep spectroscopy from the JWST Advanced Deep Extragalactic Survey. We find that a significant subset of these galaxies atz ≳ 2 with modest Hβ+ [Oiii] EWs (≈300–600 Å) have high ionization efficiencies ( $\log {\xi }_{\mathrm{ion}}\gtrsim 25.5\mathrm{Hz}{\mathrm{erg}}^{-1}$). Suppressed [Oiii] EW values yet elevated Hαand HβEW values imply that the level of chemical enrichment is the primary culprit, supported by spectroscopic measurements of metallicities below 12 + log(O/H) ≈ 7.70 (0.1Z_⊙). We demonstrate that integrated Hβ+ [Oiii] selections (e.g., Hβ+ [Oiii] EW > 700 Å) exclude the most metal-poor efficient ionizers and favor (1) more chemically enriched systems with comparable extreme radiation fields and (2) older starbursting systems. In contrast, metallicity degeneracies are reduced in Hαspace, enabling the identification of these metal-poor efficient ionizers by their specific star formation rate. 

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3. Oxygen Incorporation in the Molecular Beam Epitaxy Growth of Sc _x Ga _1−x N and Sc _x Al _1−x N

   https://doi.org/10.1002/pssb.201900612  

   Casamento, Joseph; Xing, Huili Grace; Jena, Debdeep (January 2020, physica status solidi (b))

   Secondary‐ion mass spectrometry (SIMS) is used to determine impurity concentrations of carbon and oxygen in two scandium‐containing nitride semiconductor multilayer heterostructures: Sc_xGa_1−xN/GaN and Sc_xAl_1−xN/AlN grown by molecular beam epitaxy (MBE). In the Sc_xGa_1−xN/GaN heterostructure grown in metal‐rich conditions on GaN–SiC template substrates with Sc contents up to 28 at%, the oxygen concentration is found to be below 1 × 10¹⁹ cm⁻³, with an increase directly correlated with the scandium content. In the Sc_xAl_1−xN–AlN heterostructure grown in nitrogen‐rich conditions on AlN–Al₂O₃template substrates with Sc contents up to 26 at%, the oxygen concentration is found to be between 10¹⁹and 10²¹ cm⁻³, again directly correlated with the Sc content. The increase in oxygen and carbon takes place during the deposition of scandium‐alloyed layers. 

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4. Exploring sulfur donor atom coordination chemistry with La( ii ), Nd( ii ), and Tm( ii ) using a terphenylthiolate ligand

   https://doi.org/10.1039/d4cc01037j  

   Gilbert-Bass, Kito; Stennett, Cary R.; Grotjahn, Robin; Ziller, Joseph W.; Furche, Filipp; Evans, William J. (April 2024, Chemical Communications)

   To expand the range of donor atoms known to stabilize 4fⁿ5d¹Ln(ii) ions beyond C, N, and O first row main group donor atoms, the Ln(iii) terphenylthiolate iodides, Ln^III(SAr^iPr6)₂I (Ar^iPr6= C₆H₃-2,6-(C₆H₂-2,4,6-ⁱPr₃)₂, Ln = La, Nd) were reduced to Ln^II(SAr^iPr6)₂complexes. 

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5. Role of curvature in acridone for ¹O₂ oxidation of a natural product homoallylic alcohol: A novel iso ‐hydroperoxide intermediate

   https://doi.org/10.1111/php.13843  

   Lapoot, Lloyd; Jabeen, Shakeela; Durantini, Andrés M.; Greer, Alexander (August 2023, Photochemistry and Photobiology)

   Abstract A density functional theoretical (DFT) study is presented, implicating a¹O₂oxidation process to reach a dihydrobenzofuran from the reaction of the natural homoallylic alcohol, glycocitrine. Our results predict an interconversion between glycocitrine and aniso‐hydroperoxide intermediate [R(H)O⁺–O⁻] that provides a key path in the chemistry which then follows. Formations of allylic hydroperoxides are unlikely from a¹O₂‘ene’ reaction. Instead, the dihydrobenzofuran arises by¹O₂oxidation facilitated by a 16° curvature of the glycocitrine ring imposed by a pyramidalN‐methyl group. This curvature facilitates the formation of theiso‐hydroperoxide, which is analogous to theisospecies CH₂I⁺–I⁻and CHI₂⁺–I⁻formed by UV photolysis of CH₂I₂and CHI₃. Theiso‐hydroperoxide is also structurally reminiscent of carbonyl oxides (R₂C=O⁺–O⁻) formed in the reaction of carbenes and oxygen. Our DFT results point to intermolecular process, in which theiso‐hydroperoxide's fate relates to O‐transfer and H₂O dehydration reactions for new insight into the biosynthesis of dihydrobenzofuran natural products. 

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