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  • Dynamic mechanochemistry: accelerated self-sorting of two imine-based metal complexes under solvent-free mechanochemical conditions
Title: Dynamic mechanochemistry: accelerated self-sorting of two imine-based metal complexes under solvent-free mechanochemical conditions
Self-sorting of two imine-based Cu(i) and Fe(ii) coordination complexes from a six-component reagent library has been achieved through solvent-free mechanochemistry. The reaction proceeds rapidly, yielding the thermodynamically favored products in less than 24 hours. The results point to the potential of mechanochemistry to achieve increasingly complex multi-metallic systems through one-pot protocols.  more » « less
Award ID(s):
2154061
PAR ID:
10518319
Author(s) / Creator(s):
; ; ; ;
Editor(s):
Friscic; Tomislav
Publisher / Repository:
Royal Society of Chemistry (RSC)
Date Published:
Journal Name:
RSC Mechanochemistry
Volume:
1
Issue:
1
ISSN:
2976-8683
Page Range / eLocation ID:
33 to 37
Subject(s) / Keyword(s):
Organometallic chemistry mechanochemistry dynamic assembly inorganic chemistry inorganic synthesis
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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