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It is known that the grain size plays a major role in the mechanical properties of magnesium. The aim of the present study is to evaluate its role in long‐term corrosion rate. Samples of pure magnesium with grain sizes in the range of 0.9–82 μm are produced through severe plastic deformation and annealing treatments. The mechanical properties are evaluated using tensile tests and the corrosion behavior is evaluated using immersion tests in Hank's solution. A maximum yield stress of ≈150 MPa is observed in the sample with 1.8 μm of grain size and an elongation larger than 25% is observed in the ultrafine‐grained sample. Ultrafine‐ and fine‐grained magnesium display uniform corrosion with a decreasing corrosion rate while coarse‐grained magnesium displays localized corrosion with an accelerated corrosion rate. A corrosion rate of ≈0.2 mm year−1is observed in the ultrafine‐ and fine‐grained magnesium. The corrosion product layer of the fine‐grained magnesium contains elements absorbed from the media. An analysis of the data in the literature suggests that grain refinement changes the corrosion type from localized to uniform corrosion. The exact relationship between grain size and the corrosion rate remains elusive.
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Effect of grain refinement on high temperature steam oxidation of an FeCrAl alloy
FeCrAl alloys are promising candidates to replace Zr alloys as fuel cladding materials in nuclear light-water reactors. Grain refinement has been indicated to improve irradiation resistance. To enhance corrosion resistance as well, the effects of grain refinement on steam corrosion behavior were investigated in this work. Samples of Kanthal D alloy (Fe-21Cr-5Al) with two different grain sizes (coarse-grained and ultrafine-grained) were exposed to steam at 1200 °C for 2 hrs. Results indicate improved steam corrosion resistance in ultrafine-grained Kanthal D with formation of a thinner protective Al oxide layer and the presence of a thin underlying Cr oxide layer.
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- Award ID(s):
- 2207965
- PAR ID:
- 10519049
- Publisher / Repository:
- Elsevier
- Date Published:
- Journal Name:
- Corrosion Science
- Volume:
- 226
- Issue:
- C
- ISSN:
- 0010-938X
- Page Range / eLocation ID:
- 111688
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1016/j.corsci.2023.111688
