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  • Crystal structure of a (carboxymethyl)triethylazanium bromide–2-(triethylazaniumyl)acetate (1/1) hydrogen-bonded dimer
Title: Crystal structure of a (carboxymethyl)triethylazanium bromide–2-(triethylazaniumyl)acetate (1/1) hydrogen-bonded dimer
The title compound, C8H18NO2+·Br−·C8H17NO2, crystallizes as the bromide salt of a 50:50 mixture of (triethylazaniumyl)carboxylic acid and the zwitterionic (triethylazaniumyl)carboxylate. The two organic entities are linked by a half-occupied bridging carboxylic acid hydrogen atom that is hydrogen-bonded to the carboxylate group of the second molecule. The tetralkylammonium group adopts a nearly perfect tetrahedral shape around the nitrogen atom with bond lengths that agree with known values. The carboxylic acid/carboxylate group is orientedantito one of the ethyl groups on the ammonium group, and the carbonyl oxygen atom is engaged in intramolecular C—H...O hydrogen bonds.  more » « less
Award ID(s):
1725699 2102576
PAR ID:
10519941
Author(s) / Creator(s):
; ;
Publisher / Repository:
International Union of Crystallography
Date Published:
Journal Name:
Acta Crystallographica Section E Crystallographic Communications
Volume:
79
Issue:
9
ISSN:
2056-9890
Page Range / eLocation ID:
800 to 803
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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