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Clean and renewable energy development is becoming frontier research for future energy resources, as renewable energy offers sustainable and environmentally friendly alternatives to non-renewable sources such as fossil fuels. Among various renewable energy sources, tremendous progress has been made in converting solar energy to electric energy by developing efficient organic photovoltaics. Organic photovoltaic materials comprising conjugated polymers (CP) with narrow optical energy gaps are promising candidates for developing sustainable sources due to their potentially lower manufacturing costs. Organic semiconductor materials with a high electron affinity are required for many optoelectronic applications. We have designed a series of organic semiconductors comprised of cyclopentadithiophene as a donor and thiadiazoloquinoxaline (TQ) as an acceptor, varying the π-conjugation and TQ-derivatives. We have employed density functional theory (DFT) and time-dependent DFT (TDDFT) to evaluate the designed CP’s optoelectronic properties, such as optical energy gap, dipole moment, and absorption spectra. Our DFT/TDDFT result shows that the energy gap of CPs is lowered and redshifted in the absorption spectra if there is no insertion of conjugation units such as thiophene and selenophene between donor and acceptor. In addition, selenophene shows relatively better redshift behavior compared to thiophene. Our work also provides rational insight into designing donor/acceptor-based CPs for organic solar cells.
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Storage requirements to mitigate intermittent renewable energy sources: analysis for the US Northeast
Moving away from fossil fuels is essential for a sustainable future. Carrying out this transition without reversing the improvements in the quality of life is the ultimate challenge. While minimizing the anticipated impacts of climate change is the primary driver of decarbonization, the inevitable exhaustion of fossil energy sources should provide just as strong or perhaps even stronger incentives. The vast majority of publications outlining the pathways to “net-zero carbon emission” fall short from leading to a truly “fossil fuel-free” future without falling back to some level of dependence on fossil fuels with carbon capture and sequestration. While carbon capture and sequestration might be a necessary step toward decarbonization, such intermediate goals might turn into a dead end without defining the end point. The main obstacle to wider adoption of renewable energy resources is their inherent intermittency. Solar and wind are, by far, the most abundant renewable energy sources that are expected to take the lion share in transitioning to a sustainable future. Intermittency arises at multiple levels. The most recognized are theshort-term(minute-by-minute, hourly, or diurnal) variations that should be the easiest to address. Less frequently realized are theseasonalandinter-annualvariabilities.Seasonalityposes far greater challenges than minute-by-minute or hourly variations because they lead to the absence of energy resources for prolonged periods of time. Our interest is the feasibility of a future where all energy (100%) comes from renewable sources leaving no room for fossil fuels. We carry out rudimentary statistical analyses of solar radiation and wind speed time series records to quantify the degree of their intermittencies seasonally and inter-annually. We employ a simple but robust accounting of the shortfalls when the supplies do not meet demand via a modified cumulative supply/deficit analysis that incorporates energy losses arising from transporting excess energy to storage and retrieving it as needed. The presented analysis provides guidance for choosing between the installation of excess capacity or the deployment of energy storage to guarantee reliable energy services under the assumption that the energy system is powered exclusively by renewable energy sources. This paper examines the seasonal and inter-annual variability of hydropower and biofuel resources to estimate their potential to mitigate the intermittencies of solar and wind resources. The presented analyses are meant to provide crude, bulk part estimates and are not intended for planning or operational purposes of the actual energy infrastructures. The primary focus of this paper is the Northeast region of the United States using the conterminous United States as a reference to assess the viability of reducing the energy storage need in the study region via improved connectivity to the national grid. This paper builds on the modeling exercises carried out as part of the climate-induced extremes on food, energy, water systems studies.
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- Award ID(s):
- 1856012
- PAR ID:
- 10524714
- Publisher / Repository:
- Frontiers in Environmental Science
- Date Published:
- Journal Name:
- Frontiers in Environmental Science
- Volume:
- 11
- ISSN:
- 2296-665X
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.3389/fenvs.2023.1076830
