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This study aimed to explore lignin as a naturally occurring aromatic precursor for the synthesis of LIG and further fabrication of ultrasensitive strain sensors for the detection of small deformations. One-step direct laser writing (DLW) induced high quality porous graphene, so called laser induced graphene (LIG), from kraft lignin under the conditions optimized for laser power, focus distance, and lignin loading. An electrode based on the resulting LIG was facilely fabricated by transferring LIG onto an elastomeric substrate ( i.e. , Dragon Skin™). The novel LIG transfer was facilitated by spin coating followed by water lifting, leading to the full retention of porous graphene onto the elastomeric substrate. The strain sensor was shown to be highly sensitive to small human body motions and tiny deformations caused by vibrations. It had a working range of up to 14% strain with a gauge factor of 960 and showed high stability as evidenced by repetitive signals over 10 000 cycles at 4% strain. The sensor was also successfully demonstrated for detecting human speaking, breath, seismocardiography (SCG), and movement of pulse and eye. Overall, the lignin-derived LIG can serve as excellent piezoresistive materials for wearable, stretchable, and ultrasensitive strain sensors with applications in human body motion monitoring and sound-related applications.
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Combined Additive and Laser-Induced Processing of Functional Structures for Monitoring under Deformation
This research introduces a readily available and non-chemical combinatorial production approach, known as the laser-induced writing process, to achieve laser-processed conductive graphene traces. The laser-induced graphene (LIG) structure and properties can be improved by adjusting the laser conditions and printing parameters. This method demonstrates the ability of laser-induced graphene (LIG) to overcome the electrothermal issues encountered in electronic devices. To additively process the PEI structures and the laser-induced surface, a high-precision laser nScrypt printer with different power, speed, and printing parameters was used. Raman spectroscopy and scanning electron microscopy analysis revealed similar results for laser-induced graphene morphology and structural chemistry. Significantly, the 3.2 W laser-induced graphene crystalline size (La; 159 nm) is higher than the higher power (4 W; 29 nm) formation due to the surface temperature and oxidation. Under four-point probe electrical property measurements, at a laser power of 3.8 W, the resistivity of the co-processed structure was three orders of magnitude larger. The LIG structure and property improvement are possible by varying the laser conditions and the printing parameters. The lowest gauge factor (GF) found was 17 at 0.5% strain, and the highest GF found was 141.36 at 5%.
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- Award ID(s):
- 1735968
- PAR ID:
- 10525160
- Publisher / Repository:
- Polymers
- Date Published:
- Journal Name:
- Polymers
- Volume:
- 15
- Issue:
- 2
- ISSN:
- 2073-4360
- Page Range / eLocation ID:
- 443
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.3390/polym15020443
