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1. Fine-structure Transitions of Ne ⁺ , Ar ⁺ , Ne ²⁺ , and Ar ²⁺ Induced by Collisions with Atomic Hydrogen

   https://doi.org/10.3847/1538-4357/ad0e77  

   Yan, Pei-Gen; Babb, James F (January 2024, The Astrophysical Journal)

   Abstract We calculate cross sections for fine-structure transitions of Ne⁺, Ar⁺, Ne²⁺, and Ar²⁺in collisions with atomic hydrogen by using quantum-mechanical methods. Relaxation rate coefficients are calculated for temperatures up to 10,000 K. The temperature-dependent critical densities for the relaxation of Ne⁺, Ar⁺, Ne²⁺, and Ar²⁺in collisions with H have been determined and compared to the critical densities for collisions with electrons. The present calculations will be useful for studies utilizing the infrared lines [Neii] 12.8, [Neiii] 15.6, [Neiii] 36.0, [Arii] 6.99, [Ariii] 8.99, and [Ariii] 21.8μm as diagnostics of, for example, planetary nebulae and star formation. 

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2. GLIMPSE: An Ultrafaint ≃10 ⁵ M _⊙ Pop III Galaxy Candidate and First Constraints on the Pop III UV Luminosity Function at z  ≃  6–7

   https://doi.org/10.3847/1538-4357/ade9a1  

   Fujimoto, Seiji; Naidu, Rohan P; Chisholm, John; Atek, Hakim; Endsley, Ryan; Kokorev, Vasily; Furtak, Lukas J; Pan, Richard; Liu, Boyuan; Bromm, Volker; et al (August 2025, The Astrophysical Journal)

   Abstract Detecting the first generation of stars, Population III (Pop III), has been a long-standing goal in astrophysics, yet they remain elusive even in the JWST era. Here we present a novel NIRCam-based selection method for Pop III galaxies, and carefully validate it through completeness and contamination simulations. We systematically search ≃ 500 arcmin²across JWST legacy fields for Pop III candidates, including GLIMPSE, which, assisted by gravitational lensing, has produced JWST’s deepest NIRCam imaging thus far. We discover one promising Pop III galaxy candidate (GLIMPSE-16043) at $z=6.50_{-0.24}^{+0.03}$, a moderately lensed galaxy ( $\mu =2.9_{-0.2}^{+0.1}$) with an intrinsic UV magnitude of $M_{\mathrm{UV}}=-15.89_{-0.14}^{+0.12}$. It exhibits key Pop III features: strong Hαemission (rest-frame EW 2810 ± 550 Å); a Balmer jump; no dust (UV slopeβ = −2.34 ± 0.36); and undetectable metal lines (e.g., [Oiii]; [Oiii]/Hβ < 0.44), implying a gas-phase metallicity ofZ_gas/Z_⊙ < 0.5%. These properties indicate the presence of a nascent, metal-deficient young stellar population (<5 Myr) with a stellar mass of ≃10⁵M_⊙. Intriguingly, this source deviates significantly from the extrapolated UV–metallicity relation derived from recent JWST observations atz= 4–10, consistent with UV enhancement by a top-heavy Pop III initial mass function or the presence of an extremely metal-poor active galactic nucleus. We also derive the first observational constraints on the Pop III UV luminosity function atz ≃ 6–7. The volume density of GLIMPSE-16043 (≈10⁻⁴cMpc⁻³) is in excellent agreement with theoretical predictions, independently reinforcing its plausibility. This study demonstrates the power of our novel NIRCam method to finally reveal distant galaxies even more pristine than the Milky Way’s most metal-poor satellites, thereby promising to bring us closer to the first generation of stars than we have ever been before. 

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3. 10 ⁶ -fold faster C–H bond hydroxylation by a Co ^III,IV ₂ (µ-O) ₂ complex [via a Co ^III ₂ (µ-O)(µ-OH) intermediate] versus its Fe ^III Fe ^IV analog

   https://doi.org/10.1073/pnas.2307950120  

   Li, Yan; Abelson, Chase; Que, Lawrence; Wang, Dong (December 2023, Proceedings of the National Academy of Sciences)

   The hydroxylation of C–H bonds can be carried out by the high-valent Co^III,IV₂(µ-O)₂complex2asupported by the tetradentate tris(2-pyridylmethyl)amine ligand via a Co^III₂(µ-O)(µ-OH) intermediate (3a). Complex3acan be independently generated either by H-atom transfer (HAT) in the reaction of2awith phenols as the H-atom donor or protonation of its conjugate base, the Co^III₂(µ-O)₂complex1a. Resonance Raman spectra of these three complexes reveal oxygen-isotope-sensitive vibrations at 560 to 590 cm⁻¹associated with the symmetric Co–O–Co stretching mode of the Co₂O₂diamond core. Together with a Co•••Co distance of 2.78(2) Å previously identified for1aand2aby Extended X-ray Absorption Fine Structure (EXAFS) analysis, these results provide solid evidence for their “diamond core” structural assignments. The independent generation of3aallows us to investigate HAT reactions of2awith phenols in detail, measure the redox potential and pK_aof the system, and calculate the O–H bond strength (D_O–H) of3ato shed light on the C–H bond activation reactivity of2a. Complex3ais found to be able to transfer its hydroxyl ligand onto the trityl radical to form the hydroxylated product, representing a direct experimental observation of such a reaction by a dinuclear cobalt complex. Surprisingly, reactivity comparisons reveal2ato be 10⁶-fold more reactive in oxidizing hydrocarbon C–H bonds than corresponding Fe^III,IV₂(µ-O)₂and Mn^III,IV₂(µ-O)₂analogs, an unexpected outcome that raises the prospects for using Co^III,IV₂(µ-O)₂species to oxidize alkane C–H bonds. 

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4. The Physical Conditions of Emission-line Galaxies at Cosmic Dawn from JWST/NIRSpec Spectroscopy in the SMACS 0723 Early Release Observations

   https://doi.org/10.3847/1538-4357/acba8a  

   Trump, Jonathan_R; Arrabal_Haro, Pablo; Simons, Raymond_C; Backhaus, Bren_E; Amorín, Ricardo_O; Dickinson, Mark; Fernández, Vital; Papovich, Casey; Nicholls, David_C; Kewley, Lisa_J; et al (March 2023, The Astrophysical Journal)

   Abstract We present rest-frame optical emission-line flux ratio measurements for fivez> 5 galaxies observed by the James Webb Space Telescope Near-Infared Spectrograph (NIRSpec) in the SMACS 0723 Early Release Observations. We add several quality-control and post-processing steps to the NIRSpec pipeline reduction products in order to ensure reliablerelativeflux calibration of emission lines that are closely separated in wavelength, despite the uncertainabsolutespectrophotometry of the current version of the reductions. Compared toz∼ 3 galaxies in the literature, thez> 5 galaxies have similar [Oiii]λ5008/Hβratios, similar [Oiii]λ4364/Hγratios, and higher (∼0.5 dex) [NeIII]λ3870/[OII]λ3728 ratios. We compare the observations to MAPPINGS V photoionization models and find that the measured [NeIII]λ3870/[OII]λ3728, [Oiii]λ4364/Hγ, and [Oiii]λ5008/Hβemission-line ratios are consistent with an interstellar medium (ISM) that has very high ionization ( $\log \left(Q\right)\simeq 8-9$, units of cm s⁻¹), low metallicity (Z/Z_⊙≲ 0.2), and very high pressure ( $\log \left(P/k\right)\simeq 8-9$, units of cm⁻³). The combination of [Oiii]λ4364/Hγand [Oiii]λ(4960 + 5008)/Hβline ratios indicate very high electron temperatures of $4.1<\log \left(T_e/\mathrm{K}\right)<4.4$, further implying metallicities ofZ/Z_⊙≲ 0.2 with the application of low-redshift calibrations for “T_e-based” metallicities. These observations represent a tantalizing new view of the physical conditions of the ISM in galaxies at cosmic dawn. 

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5. C(sp ³ )–H oxidation and chlorination catalysed by a bioinspired pincer iron( iii ) complex

   https://doi.org/10.1039/D2DT02005J  

   Han, Jian; Tan, Liming; Wan, Yanjun; Li, Gang; Anderson, Stephen N. (August 2022, Dalton Transactions)

   A pincer iron(iii) catalyst for the oxidation and chlorination of C(sp³)–H bonds was developed. 

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