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1. Viscosity of Dry and Hydrous Diopside Melts at High Pressures: Implications for Upper Mantle Magma Dynamics

   https://doi.org/10.1029/2025JB032842  

   Chen, Qi; Zhao, Bin; Yu, Tony; Ashley, Aaron Wolfgang; Wang, Yanbin (December 2025, Journal of Geophysical Research: Solid Earth)

   Abstract Viscosity of silicate melts governs magma transport and influences mantle dynamics, yet effects of pressure and water on melt viscosity remain poorly understood. Here, we report in situ falling‐sphere viscosity measurements on diopside (Di) melts with 0–3 wt.% H₂O along the liquidus up to 7 GPa and 2103 K using synchrotron X‐ray radiography. By incorporating our hydrous melt data into a previously validated model for the dry system, the effects of pressure, temperature, and H₂O contents on Di melt viscosity can be satisfactorily captured by the function: whereT*is the homologous temperature,x_H2Ois the molar % H₂O,η₀ = 8.90 (1.50) × 10⁻⁸ Pa s,b₀ = 3.02 (0.10), andH*(P) = 15.72 (0.03)−0.35 (0.01)·P + 1.07 (0.07) × 10⁻²·P²−1.19 (0.14) × 10⁻⁴ P³, ×10⁻³ GPa⁻¹. Adding 3 wt.% H₂O systematically reduces viscosity by ∼0.7 log units. For both dry and hydrous melts, viscosity along the liquidus decreases monotonically with increasing pressure, suggesting that moderate hydration may not significantly alter the compressional behavior of Di melts. Combining the Di viscosity model with models for feldspar and olivine, we simulated the viscosity of analog basaltic magmas under mantle conditions. Increasing H₂O content from 0 to 3wt.% raises mobility of basaltic magma increases by >1 order of magnitude. In hot plume settings, the mobility further increases by a factor of 30 relative to typical ambient mantle. Assuming a simple percolation model, the increased mobility corresponds to faster melt ascent in mantle plumes that could, in part, explain the voluminous magmatism of large igneous provinces. 

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2. Properties of Hydrous Aluminosilicate Melts at High Pressures

   https://doi.org/https://pubs.acs.org/doi/10.1021/acsearthspacechem.8b00157  

   Bajgain, Suraj K.; Peng, Ye; Mookherjee, Mainak; Jing, Zhicheng; Solomon, Matthew. (January 2019, ACS earth and space chemistry)

   In this study, we use f irst-principles molecular dynamics simulations to explore the behavior of anhydrous aluminosilicate melt with a stoichiometry of NaAlSi2O6 up to pressures of ∼30 GPa and temperatures between 2500 and 4000 K. We also examine the effect of water (∼4 wt % H2O) on the equation of state and transport properties of the aluminosilicate melt and relate them to atomistic scale changes in the melt structure. Our results show that water reduces the density and bulk modulus of the anhydrous melt. However, the pressure derivative of the bulk modulus of the hydrous melt is larger than that of the anhydrous melt. The pressure dependence of the transport property exhibits an anomalous behavior. At a pressure of ∼12 GPa, anhydrous aluminosilicate melts exhibit maxima in diffusion and minima in viscosity. Dissolved water in melts also affects both diffusion and viscosity. In hydrous aluminosilicate melts, the maxima in diffusion and the minima in viscosity occur at ∼14 GPa. The anomalous behavior of transport properties is related to the pressure-induced changes in the melt structure. At shallower depths, i.e., up to 100 km, relevant for subduction zone settings, the lower density compounded by the lower viscosity of hydrous aluminosilicate melts is likely to provide buoyancy for upward migration. At greater depths of ∼180−200 km, greater compressibility of the hydrous aluminosilicate melts together with the minimum viscosity could hinder magma migration and may explain the presence of a partial melt layer at the lithosphere−asthenosphere boundary. 

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3. The Viscosity of Albitic Melt at High Pressures and Implications for the Mobility of Crust‐Forming Magmas

   https://doi.org/10.1029/2024JB030527  

   Ashley, Aaron Wolfgang; Mookherjee, Mainak; Xu, Man; Yu, Tony; Manthilake, Geeth; Wang, Yanbin (May 2025, Journal of Geophysical Research: Solid Earth)

   Abstract The earliest form of continental crust was produced by tonalite‐trondhjemite‐granodiorite (TTG) magmas. Molten albite (NaAlSi₃O₈) is representative of TTGs and also a major component of modern crust‐forming magma. The viscosity of the melt controls the magma ascent rate and hence influences the production of new continental crust. It is well known that the viscosity (η) of albitic melt exhibits an anomalous pressure (P) dependence. However, prior results on the meltηat high‐Pdiffer significantly which limits our ability to predict the movement of crust‐forming magma at depth. In this study, we more tightly constrained theP‐effect onηin anhydrous albitic melt via high‐Pand high‐temperature (T) falling sphere experiments. We limited undesirable drag effects by using small sphere‐to‐capsule diameter ratios (d/D) such thatd/D ≤ 0.12, and evaluated uncertainties due to such drag using a Monte Carlo approach. Our results show that meltηfirst decreases withP(i.e., ∂η/∂P < 0) and then increases with continued compression (∂η/∂P > 0) with a well‐definedηminimum (η_min) at ∼6 GPa along a ∼2,000 K isotherm. We find that the viscosity of the melt can be described by an Arrhenius formalism with an activation volume that varies withPandT. The results indicate thatηof aluminosilicate magmas decrease with depth and temperature in the crust, thereby mobilizing the magmas to promote rapid volcanic eruptions. The results also suggest that TTG magmas relevant for the early Earth could pond during ascent due to the anomalousP‐effect onη. 

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4. The Viscosity and Atomic Structure of Volatile-Bearing Melilititic Melts at High Pressure and Temperature and the Transport of Deep Carbon

   https://doi.org/10.3390/min10030267  

   Stagno, Vincenzo; Stopponi, Veronica; Kono, Yoshio; D’Arco, Annalisa; Lupi, Stefano; Romano, Claudia; Poe, Brent T.; Foustoukos, Dionysis I.; Scarlato, Piergiorgio; Manning, Craig E. (March 2020, Minerals)

   Understanding the viscosity of mantle-derived magmas is needed to model their migration mechanisms and ascent rate from the source rock to the surface. High pressure–temperature experimental data are now available on the viscosity of synthetic melts, pure carbonatitic to carbonate–silicate compositions, anhydrous basalts, dacites and rhyolites. However, the viscosity of volatile-bearing melilititic melts, among the most plausible carriers of deep carbon, has not been investigated. In this study, we experimentally determined the viscosity of synthetic liquids with ~31 and ~39 wt% SiO2, 1.60 and 1.42 wt% CO2 and 5.7 and 1 wt% H2O, respectively, at pressures from 1 to 4.7 GPa and temperatures between 1265 and 1755 °C, using the falling-sphere technique combined with in situ X-ray radiography. Our results show viscosities between 0.1044 and 2.1221 Pa·s, with a clear dependence on temperature and SiO2 content. The atomic structure of both melt compositions was also determined at high pressure and temperature, using in situ multi-angle energy-dispersive X-ray diffraction supported by ex situ microFTIR and microRaman spectroscopic measurements. Our results yield evidence that the T–T and T–O (T = Si,Al) interatomic distances of ultrabasic melts are higher than those for basaltic melts known from similar recent studies. Based on our experimental data, melilititic melts are expected to migrate at a rate ~from 2 to 57 km·yr−1 in the present-day or the Archaean mantle, respectively. 

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5. Behavior and properties of water in silicate melts under deep mantle conditions

   https://doi.org/https://doi.org/10.1038/s41598-021-90124-7  

   Karki, Bijaya B; Ghosh, Dipta B; Karato, Shun-ichiro (May 2021, Scientific reports)

   null (Ed.)

   Water (H2O) as one of the most abundant fluids present in Earth plays crucial role in the generation and transport of magmas in the interior. Though hydrous silicate melts have been studied extensively, the experimental data are confined to relatively low pressures and the computational results are still rare. Moreover, these studies imply large differences in the way water influences the physical properties of silicate magmas, such as density and electrical conductivity. Here, we investigate the equation of state, speciation, and transport properties of water dissolved in Mg1-xFexSiO3 and Mg2(1-x)Fe2xSiO4 melts (for x = 0 and 0.25) as well as in its bulk (pure) fluid state over the entire mantle pressure regime at 2000 to 4000 K using first-principles molecular dynamics. The simulation results allow us to constrain the partial molar volume of the water component in melts along with the molar volume of pure water. The predicted volume of silicate melt+water solution is negative at low pressures and becomes zero above 15 GPa. Consequently, the hydrous component tends to lower the melt density to similar extent over much of the mantle pressure regime irrespective of composition. Our results also show that hydrogen diffuses fast in silicate melts and enhances the melt electrical conductivity in a way that differs from electrical conduction in the bulk water. The speciation of the water component varies considerably from the bulk water structure as well. Water is dissolved in melts mostly as hydroxyls at low pressure and as -O-H-O-, -O-H-O-H- and other extended species with increasing pressure. On the other hand, the pure water behaves as a molecular fluid below 15 GPa, gradually becoming a dissociated fluid with further compression. On the basis of modeled density and conductivity results, we suggest that partial melts containing a few percent of water may be gravitationally trapped both above and below the upper mantle-transition region. Moreover, such hydrous melts can give rise to detectable electrical conductance by means of electromagnetic sounding observations. 

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