The gas (or plastron) trapped between micro/nano-scale surface textures, such as that on superhydrophobic surfaces, is crucial for many engineering applications, including drag reduction, heat and mass transfer enhancement, anti-biofouling, anti-icing, and self-cleaning. However, the longevity of the plastron is significantly affected by gas diffusion, a process where gas molecules slowly diffuse into the ambient liquid. In this work, we demonstrated that plastron longevity could be extended using a gas-soluble and gas-permeable polydimethylsiloxane (PDMS) surface. We performed experiments for PDMS surfaces consisting of micro-posts and micro-holes. We measured the plastron longevity in undersaturated liquids by an optical method. Our results showed that the plastron longevity increased with increasing the thickness of the PDMS surface, suggesting that gas initially dissolved between polymer chains was transferred to the liquid, delaying the wetting transition. Numerical simulations confirmed that a thicker PDMS material released more gas across the PDMS–liquid interface, resulting in a higher gas concentration near the plastron. Furthermore, we found that plastron longevity increased with increasing pressure differences across the PDMS material, indicating that the plastron was replenished by the gas injected through the PDMS. With increasing pressure, the mass flux caused by gas injection surpassed the mass flux caused by the diffusion of gas from plastron to liquid. Overall, our results provide new solutions for extending plastron longevity and will have significant impacts on engineering applications where a stable plastron is desired.
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Engineering 3D Hierarchical Structures with Bio-Mimetic Solid Fraction Gradient
We present a versatile method to create 3-D surfaces with complex hierarchical microstructures that mimic the patterns found on springtail skin. Our method innovatively merges two fixed-spacing patterns at different scales to create patterns with varying spacing but does not require precise alignment. The key is to utilize localized stretching strain when gradually laminating a thin microstructured elastomer layer onto a wavy substrate. To demonstrate this new fabrication process, we laminated a micro-pillar thin polydimethylsiloxane (PDMS) film on a wavy PDMS substrate with millimeter-scale inverted pyramidal holes. This resulted in hierarchical surface micropillars that display varying spacings along the peaks and the valleys of the wavy substrate. To our best knowledge, this is the first report to generate controllable micro-patterns with a gradient spacing from fixed-spacing patterns. Our new process overcomes one of the major challenges in producing bio-inspired patterns with diverse variations for studies of biomimicry and biomutualism.
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- Award ID(s):
- 2225964
- PAR ID:
- 10533936
- Publisher / Repository:
- IEEE
- Date Published:
- ISBN:
- 979-8-3503-5792-9
- Page Range / eLocation ID:
- 658 to 660
- Format(s):
- Medium: X
- Location:
- Austin, TX, USA
- Sponsoring Org:
- National Science Foundation
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