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The Sierra Nevada Batholith is a record of copious magmatism caused by subduction of the Farallon oceanic plate under the western margin of North America during much of the Mesozoic Era, between 256 and 80 Ma. The diversity of rocks produced during these sub-surface interactions depends on several variables, including fluid availability, melt source, and mantle partial melt emplacement geometry (Ducea et al., 2015). The analysis of zircon is particularly appealing because zircon is a robust mineral that endures periods weathering and erosion and commonly lingers as detrital crystals in the rock record. It thus has the potential to add value as a lens into global magmatism and planetary evolution given its use as a thermometer (Watson and Ferry, 2007), and measure of magma source composition (Davies et al. 2021). Several researchers suggest that zircon can be a useful tool for constraining depth of crystallization (Tang et al. 2020). Building on thesis work on the utility of europium anomalies in zircon to model depths and, by proxy, crustal thickness for batholithic granitoids, this project provides additional data and insight to understand spatially and temporally varied trends of the arc’s plutonic record. Magma emplacement occurs in pulses and typically exhibits an eastward younging trend during the Mesozoic (Chen and Moore, 1982). Chinen (2022) found that the arc’s Western Margin exhibits both younging and thickening trends towards the east. Recent research exposed the issues associated with traditional cerium anomaly calculation because of a reliance on lanthanum, a poorly analyzed element (Loader et al., 2022). We incorporate these new methods to calculate zircon metrics for our data; this project further constrains the precision of interpretations about geochemical trends using laboratory analysis and zircon because it draws on a large and prolific database of plutonic trace element geochemistry. Because multiple magmatic and environmental processes affect zircon crystallization compositions, we use broad suites of zircon (e.g. rare earth elements, oxygen isotopes) and whole rock (XRF, trace elements, isotopes, additional minerals) geochemical analyses to elucidate aspects of previous research (Brady and Lackey, 2022; Chinen, 2022) and to build upon noted trends of the plutonic Cordilleran record.
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Europium anomalies in zircon: A signal of crustal depth?
Trace element concentrations and ratios in zircon provide important indicators of the petrological processes that operate in igneous and metamorphic systems. In granitoids, the compositions of zircon have been linked to the behaviour of garnet and plagioclase—pressure-sensitive minerals—in the source during partial melting. This has led to the proposal that Europium anomalies in detrital zircon are linked to the depth of crustal melting or magmatic differentiation and are a proxy for average crustal thickness. In addition to the mineral assemblage present during partial melting, Eu anomalies in zircon are also sensitive to redox conditions as well as magma evolution during extraction, ascent, and emplacement. Here we quantitatively model how rock type, mineral assemblages, redox changes, and reaction sequences influence Eu anomalies of zircon in equilibrium with silicate melt. Partial melting of metasedimentary rocks and metabasites yields felsic to intermediate melts with a large range of Eu anomalies, which do not correlate simply with pressure (i.e. depth) of melting. Europium anomalies of zircon associated with partial melting of metasedimentary rocks are most sensitive to temperature whereas Eu anomalies associated with metabasite melting are controlled by plagioclase proportion—a function of pressure, temperature, and rock composition—as well as changes in oxygen fugacity. Furthermore, magmatic crystallization of granitoids can increase or decrease Eu anomalies in zircon from those of the initial (anatectic) melt. Therefore, Eu anomalies in zircon should not be used as a proxy for the crustal thickness or depth of melting but can be used to track the complex processes of metamorphism, partial melting, and magmatic differentiation in modern and ancient systems. Secular changes of Eu/Eu* from the zircon archive may reflect a change in thermal gradients of crustal melting or an increase in the reworking of sedimentary rocks over time.
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- Award ID(s):
- 2022746
- PAR ID:
- 10536378
- Publisher / Repository:
- Elsevier
- Date Published:
- Journal Name:
- Earth and Planetary Science Letters
- Volume:
- 622
- Issue:
- C
- ISSN:
- 0012-821X
- Page Range / eLocation ID:
- 118405
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1016/j.epsl.2023.118405
