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Abstract The development of integrated systems that mimic the multi‐stage stiffness change of marine animals such as the sea cucumber requires the design of molecularly tailored structures. Herein, we used an integrated biomimicry design to fabricate a sea cucumber mimic using sidechain polypseudorotaxanes with tunable nano‐to‐macroscale properties. A series of polyethylene glycol (PEG)‐based sidechain copolymers were synthesized to form sidechain polypseudorotaxanes with α‐cyclodextrins (α‐CDs). By tailoring the copolymers’ molecular weights and their PEG grafting densities, we rationally tuned the sizes of the formed polypseudorotaxanes crystalline domain and the physical crosslinking density of the hydrogels, which facilitated 3D printing and the mechanical adaptability to these hydrogels. After 3D printing and photo‐crosslinking, the obtained hydrogels exhibited large tensile strain and broad elastic‐to‐plastic variations upon α‐CD (de)threading. These discoveries enabled a successful fabrication of a sea cucumber mimic, demonstrating multi‐stage stiffness changes.
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Troubling the Waters: Gendered Dispossession, Violence, and Sea Cucumber Aquaculture in Madagascar
Poverty reduction and fisheries management in Madagascar have converged on the marine seascape, directed at an unassuming creature: the sea cucumber. In southwestern Madagascar, the enclosure of what was once a common pool resource has led to violence and new gendered seascapes. This form of blue grabbing, promoted by private companies and NGOs alike as an avenue to achieve conservation and develop coastal economies, has fundamentally restructured property relations and who benefits from marine resources. Sea cucumber pens, established in some areas with the input of a narrow local elite and guarded at times by the police have become high risk environments where fishers report injury and death, pointing to important questions about the metrics and means of sustainable production in the marine realm, and whose interests and access to marine resources are prioritized.
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- Award ID(s):
- 1923707
- PAR ID:
- 10537491
- Publisher / Repository:
- Society and Natural Resources
- Date Published:
- Journal Name:
- Society & Natural Resources
- Volume:
- 37
- Issue:
- 4
- ISSN:
- 0894-1920
- Page Range / eLocation ID:
- 443 to 470
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1080/08941920.2023.2288674
